• Title/Summary/Keyword: wet strength agent

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Effect of Fixation Methods on the Flame Retardant and Performance Properties of MDPPA/HMM treated Cotton (MDPPA/HMM처리 면직물의 고착방법에 따른 방염성과 물성의 변화)

  • 지주원;오경화
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.1
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    • pp.15-23
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    • 2000
  • Effect of fixation methods on the flame retardant(FR) and performance properties of MDPPA/HMM treated cotton fabrics were studied. Combination of three different fixation methods - premercerization, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton with MDPPA/HMM. As a result, an increase in internal volume of cotton fiber by pre-mercerization and addition of swelling agent, and wet fixation increased %add-on of FR agent improving FR efficiency and wash fastness. Tensile strength of MDPPA/HMM treated cotton fabrics by wet fixation and swelling agent were slightly decreased, but that of premercerized cotton was improved. Wet fixated fabric showed lower bending rigidity and better compressional properties which improved fabric hand. Retention of swelling ability of cotton treated with MDPPA/HMM improved moisture absorption properties.

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Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(I) - Effects of Fiber Types, Wet Strength Agents and a Moisture-Proof Chemical on the Physical Properties of Base Papers for Corrugated Board Boxes - (농산물 저온유통용 내수 골판지 상자의 제조 (제1보) -섬유의 종류, 습윤지력증강제 및 방습제 첨가에 따른 골판지 원지의 물리적 특성 -)

  • 조중연;민춘기;신준섭
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.2
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    • pp.26-32
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    • 2003
  • For the purpose of manufacturing water-resistant corrugated board boxes for agricultural products in the cold chain system, the effects of fiber types, wet strength agents and a moisture-proof chemical on the properties of the base papers were investigated first. PAE(polyamide amine epichlorohydrin) showed better performance than MF(melamine formalde-hyde) over broad stock pH ranges, which was prefered as wet strength agent for the paper grade. When short fibers(AOCC, KOCC) were mixed with long fiber(UKP) in certain ratios, some physical properties of the paper made with mixed fibers were similar to those of the paper made with UKP only. Paper containing AOCC showed the biggest increase in water resistance when PAE was added to the stock. Synergistic effects in moisture-proof and some mechanical properties of paper were appeared when PAR was added internally, together with the coating of a moisture proof chemical on the sheets.

Properties of GPAM Emulsion for a Wet Strength Agent (습윤 지력증강제로서 GPAM Emulsion의 특성)

  • Kim, Bong-Yong;Son, Dong-Jin;Kim, Hak-Sang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.3
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    • pp.36-40
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    • 2007
  • It has been problematic to repulp the dry broke treated with permanent wet strength agents like PAE, UF and MF. Solution type GPAM has the benefit of easy repulping but it has problems of cocross-linking and tends to gel. Therefore, the product concentration must be lower than 10% to reduce the gel generation problem. We developed emulsion type GPAM by an inverse emulsion technology to resolve both the repulping problem with permanent wet strength agents and the stability problem of GPAM solution products.

A Study on Physical and Chemical Properties of Vegetation Foundation for Rooftop Greening Using Wood Waste (폐목질 자원을 이용한 옥상녹화용 식생기반재의 물리 및 화학적 특성에 관한 연구)

  • Kim, Dae-Young;Kim, Mi Mi
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.1
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    • pp.79-87
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    • 2008
  • Many researchers have studied on rooftop greening that can be installed in abandoned spaces on a building roof. The most important issue in rooftop greening is the soil weight problem. The light greening materials are needed to solve this problem. Therefore, many alternative materials against the soil were investigated for rooftop greening. In this study, the waste wood chips and the waste paper slurry were evaluated as the lightweight vegetation foundation for rooftop greening. It also has a meaning for recycling of waste materials. The mixture ratio of waste wood chips to waste paper slurry for the board (the foundation of greening) was 60 to 40. The wet strength resin and the sizing agent were additionally added with different amount. After the forming of the board, physical and chemical properties were tested with the variation of wet strength resin and sizing agent. As the result of the test, the board with 15% of wet strength resin in the wet condition showed the highest strength. Futhermore, the moisture evaporation loss from the board surface with sizing agent was much lower than that from the board without sizing agent. Therefore, it was clear that the sizing agent was effective for water retention. The change of thickness in the wet condition was less than 1 mm, and it showed that the board is the predominant material on the dimensional stability. The average pH value of the board was ranged from 7.6 to 8.25.

An Experimental Study on the Effect of Concrete Surface Treatment Methods on the Bond Strength of Metal Spray Coating (콘크리트 표면처리 방법이 콘크리트 표면 금속용사 피막의 부착강도에 미치는 영향에 관한 실험적 연구)

  • Park, Jin-Ho;Kim, Sang-Yeol;Lee, Han-Seung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.36 no.1
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    • pp.147-154
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    • 2020
  • The exterior finishing of reinforced concrete buildings is one of the important factors to prevent durability and prevent natural environment or disaster such as temperature, snow, wind, rain from the outside as well as external design of buildings. Finishing methods can be divided into wet and dry methods. The wet method using paint is relatively easy to construct, but it requires repair and reinforcement every 1 to 5 years and requires a lot of LCC for maintenance. Finishing method using panel has good durability, but it is difficult to install and expensive. Therefore, in this paper, we evaluate the bond strength for the application of the metal spray method in order to overcome the problems of existing methods. Experimental results show that the sandblast + surface roughness agent(S-R(Y)) has a roughness of 41.16 ㎛ and the bond strength is about 3.19 MPa, which is the highest bond strength. In addition, the grinding + surface roughness agent(G-R(Y)) application showed roughness of about 36.59 ㎛ and secured the bond strength performance of 2.94 MPa.

Improvement of Paper Bulk and Stiffness by Using Drying Shrinkage Analysis (건조수축 해석을 통한 종이의 벌크 및 강직성 향상)

  • Lee, Jin-Ho;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.49-58
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    • 2011
  • The maximum drying shrinkage velocity was proposed to verify bulk and stiffness improvement mechanism during drying according to papermaking parameters. It was based on the wet-web shrinkage behavior without the restraint of wet-web during drying, so intact drying impact could be measured. Bulking agent reduced the drying shrinkage and the maximum drying shrinkage velocity, so paper bulk increased and paper strength decreased. When adding cationic starch to stock with the bulking agent for strengthening, the bulk was increased further with additional decreasing of the drying shrinkage and the maximum drying shrinkage velocity. Paper strength also increased except tensile stiffness index with decreasing the drying shrinkage and the maximum drying shrinkage velocity. When using additional strength additives for strengthening of fiber interfaces extended by bulking agent and cationic starch, amphoteric strength additive increased paper stiffness without loss of paper bulk. It was considered that the added amphoteric strength additives were cross-linked to the stretched cationic starch and this cross-linking increased elasticity of fiber-polymer-fiber interfaces without changing the drying behavior. Paper bulk could be increased with decreasing the maximum drying shrinkage velocity. The drying shrinkage of paper also could be controlled by fiber-to-fiber bonding interfaces by the bulking agent. In this case, paper strength including stiffness was decreased by reducing fiber-to-fiber bonding but it could be improved by strengthening fiber-to-fiber interfaces with polymer complex without loss of bulk.

Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephthalate and its Sizing Efficiency (Part 2) - Sizing efficiency of modified PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제2보) - 개질 PET의 내수특성 평가 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.95-101
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    • 2010
  • For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

Cure Characteristics, Mechanical Properties and Abrasion Resistance of Silica Filled Natural Rubber Vulcanizate

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • v.50 no.3
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    • pp.159-166
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    • 2015
  • Silica which is used for reinforcing filler in tire industry is widely known as eco-friendly material exerting $CO_2$ reduction effect through decrease of rolling resistance and improvement of wet grip. Generally silica is classified as a highly polar filler because it contains a large number of silanol (Si-OH) group on its surface. And also silica gives a lower reinforcing effect than carbon black due to its poorer rubber-filler interaction. Therefore silica is treated with silane coupling agent or activator, then following the conventional rubber blend method, vulcanized sheets were prepared using a hot press, and cure characteristics, mechanical properties and abrasion resistance of the test specimens were investigated. It was found that with an increase in the silane coupling agent content the tensile strength, 300% modulus and abrasion resistance increased while Mooney viscosity decreased and crosslink density slightly increased with an increase of activator.

An Experimental Study on the Early Prediction of Concrete Strength by Accelerating Agent (급속경화에 의한 콘크리트 강도의 조기 판정에 관한 실험적 연구)

  • 김창교;최창식;이리형
    • Proceedings of the Korea Concrete Institute Conference
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    • 1989.10a
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    • pp.9-13
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    • 1989
  • The purpose of this paper is to propose a method predetermining the 28-days strength of concrete. In this paper, it was predicted by regression analysis of the relation between 7-days and 28-days strength of fresh concrete and the strength of concrete early cured at $70^{\circ}C$ for rour hours after wet screening and addition of accelerating agent. It is concluded that the formula predeterming the 28-days strength of concrete using 25M/M rubbles from Sam-Cheok and sands from Yon-Gok, by the strength of concrete early cured for 4 hours is Y=-11.45 + 3.686X, where the coefficient of determination of regression-expression is r2=0.938, S=17.94(kg/$\textrm{cm}^2$).

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The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent (Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구)

  • 노준석;김진태;박춘근;오복진;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.421-428
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    • 1998
  • The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

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