• Title/Summary/Keyword: wet strength

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DETERMINATION OF THE CATIONIC DEMAND OF PAPERMAKING STOCK USING CHROMOPHORIC LABELED CATIONIC POLYMERS

  • Hiroo Tanaka;Hideaki Ichiura;Takuya Kitaoka
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.79-83
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    • 1999
  • A cationic demand(CD) is a very useful indication for determining the optimum dosage rate of retention aids to the papermaking stock at the wet end. Polyelectrolyte titration has been most often used to determine a CD. Highly accurate results can be obtained by this method when the ionic strength of sample is low. But this is accompanied by the serious errors when the ionic strength is higher than that corresponding to 20 milli molar(mM) monovalent, 2 mM divalent or 0.2 mM trivalent ions because of no occurrence of the end point of titration. Therefore, it is very difficult or almost impossible for the conventional method to be applied to the industrial suspensions such as papermaking stock and industrial waste water. Then a novel method using chromophoric labeled cationic polymer which can be applicable to the sample with high ionic strength has been developed.

Effects of Urea-Phenol-Melamine Copolymer Adhesive on the Plywood Qualities (요소(尿素)·멜라민·페놀공축합수지(共縮合樹脂)가 합판(合板)의 재질(材質)에 미치는 영향(影響))

  • Lee, Hwa-Hyoung;Hong, Seung-Do
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.1
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    • pp.38-43
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    • 1984
  • Water soluble urea-melamine-phenol copolymer adhesive manufactured with 80 percent of urea resin contents was manufactured by different molar ratio for a high temperature curing type, and their properties and strengthes were examined through manufactures of plywood with Kapur (Dryobalanops spp.) veneers. The results are summarized as follows: 1. Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.78 to 0.84 and their moisture contents met the KS requirement. 2. In dry and wet shear strength, $U_{80}M_{10}P_{10}$ copolymer resin showed the highest value and urea resin was the lowest, indicating that melamine and phenol were effective for increasing glue shear strength of urea resin. 3. In case of glue shear strength after boiling test, phenolic resin was the nest and melamine was not so effective as phenol on reinforcement of boiling water resistance of urea resin.

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A Design Guide for Composite Laminates by the Compressive after Impact Tests (충격후 잔류압축강도시험에 의한 복합재료 적층판의 설계)

  • 정태은;박경하;류정주
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.9
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    • pp.2105-2113
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    • 1995
  • The compressive tests under impact conditions were performed to establish a design guide for impact damage tolerance. The composition of layup was selected for the real cases of composite aircraft structure. The energy level of visible of visible damage threshold was determined as 7 Joules. It was found that the normalized bending stiffnesses in the direction of closely fixed boundary affected the area of damage. Graphite/epoxy used in the tests exhibited 60% reduction in compression strength at the energy level of visible damage threshold. Wet-conditioned specimens represented 9% reduction in residual compressive strength in comparison with room temperature ambient specimens. In this study, a design factor of 2.1 was proposed for the low velocity impact damage.

A Study on the Properties of Light Weight Foamed Concrete Using Fine Aggregate (잔골재를 활용한 경량기포 콘크리트의 특성에 관한 연구)

  • Han, Min-Cheol;Shin, Jae-Kyung;Jeong, Kwang-Bok;Pei, Chang-Chun;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.781-784
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    • 2006
  • This paper investigates the fundamental properties of light weight foamed concrete with the variances in unit weight of concrete and adding ratio of stability agent(SA). Test showed that concrete adding SA slightly decreased fluidity but secured stable flow appearances without segregation of concrete components. All specimens in a standard condition represented that a sinking depth was not observed, while, in the wet condition, a specimen adding SA decreased the sinking depth $2{\sim}4mm$ more than control concrete. Compressive strength values of control concrete showed $0.03{\sim}0.3MPa$ higher than the concrete adding SA. As for the tensile strength, the specimen adding SA also had lower value, while the ratios of comp. to tens. strength presented $0.43{\sim}0.62$, which is relatively higher than ordinary concrete.

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Electron Beam Modification of Dual Phase Filler: Surface Characteristics and its Influence on the Properties of Styrene-Butadiene Rubber Vulcanizates

  • Shanmugharaj A. M.
    • Rubber Technology
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    • v.5 no.2
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    • pp.94-103
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    • 2004
  • The present work describes modification of dual phase filler by electron beam irradiation in presence of multifunctional acrylates like trimethylol propane triacrylate (TMPTA) or silane coupling agent like bis (3-triethoxysilylpropyltetrasulphide) and in-fluence of the modified fillers on the physical properties of styrene-butadiene rubber (SBR) vulcanizates. Modulus at 300 % elongation increases whereas the tensile strength decreases with increase in radiation dose for the dual phase filler loaded styrene-butadiene rubber vulcanizates (SBR). However, modulus and tensile strength significantly increase, which is more, pronounced at higher filler loadings for TMPTA modified dual phase filler loaded SBR. These changes in properties are explained by the equilibrium swelling data and Kraus plot interpreting the polymer-filler interaction. Electron beam modification of the filler results in a reduction of tan ${\delta}$ at $70^{\circ}C$, a parameter for rolling resistance and increase in tan ${\delta}$ at $0^{\circ}C$, a parameter for wet skid resistance of the SBR vulcanizates. Finally, the influence of modified fillers on the properties like abrasion resistance, tear strength and fatigue failure and the improvement in the properties have been explained in terms of polymer-filler interaction.

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Evaluation of the Basic Properties of Materials for Application of Functional Plaster Mortar (기능성 미장 모르타르의 현장 적용을 위한 재료별 기초 물성에 관한 평가)

  • Cho, Do-Young;Kim, Gyu-Yong;Miyauchi, Hiroyuki
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.2
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    • pp.152-160
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    • 2012
  • The development of building must be accompanied with construction technology and performance of materials. In particular, wet processes have a high level of dependence on manpower and a low level of diversification of materials used. This study aimed to determine the applicability of various materials for wet process, mechanized construction and eco-friendly building materials through a comparison with dry premixed mortar. As a result, it was found that resin plaster and gypsum plaster's strength is lower than that of dry cement mortar, but their mechanization application, construction simplification, smoothness and bond strength are higher than that of dry cement mortar. And estimate that is valid as workability, bonding strength, eco-friendly building material in occasion of gypsum plaster.

Effect of Precipitated Calcium Carbonate on Paper Properties and Drying Energy Reduction of Duplex-board (원료 및 건조에너지 절감을 위한 경질탄산칼슘의 백판지 공정 적용성 평가)

  • Lee, Ji-Young;Kim, Young-Hun;Lee, Se-Ran;Kim, Chul-Hwan;Sung, Yong Joo;Lim, Gi-Baek;Kim, Sun-Young;Kim, Jun-Sik;Park, Jong-Hea
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.24-29
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    • 2013
  • In this study, we investigated the applicability of PCC(precipitated calcium carbonate) as a raw material for the manufacture of duplex-board. Papers were made with white-ledger stock collected from the actual duplex-board mill and PCC in a laboratory, and paper properties including bulk, ash content, tensile strength, burst strength, brightness and opacity were measured. The effect of PCC on the drying energy of duplex-board was also determined by measuring the moisture content of wet web and calculating drying energy reduction. PCC increased bulk and ISO brightness significantly, which means PCC can decrease the use of virgin pulp and recycled fibers. PCC decreased the moisture content of wet web, which means PCC can decrease drying energy consumption. However, paper strength decreased as addition levels of PCC addition increased. Therefore, the addition level of PCC must be determined considering the reduction of paper strengths.

THE EFFECTS OF SURFACE CONTAMINATION ON THE SHEAR BOND STRENGTH OF COMPOMER

  • Heo, Jeong-Moo;Lee, Su-Jong;Im, Mi-Kyung
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.577-577
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    • 2001
  • The lastest concepts in bonding are "total etch", in which both enamel and dentin are etched with an acid to remove the smear layers, and "wet dentin" in which the dentin is not blown dry but left moist before application of the bonding primer. Ideally, the application of a bonding agent to tooth structure should be insensitive to minor contamination from oral fluids. Clinically contaminations such as saliva, gingival fluid, blood and handpiece lubricant are often encountered by dentists during preparation of a restoration. The aim of this study was to evaluate the effect of contamination by hem-ostatic agents on shear bond strength of compomer restorations. One hundred and ten extracted human maxillary and mandibular molar teeth were collected. The teeth were cleaned from soft tissue remnant and debris and stored in physiologic solution until they were used. Small flat area on dentin of the buccal surface were wet ground serially with 400, 800 and 1200 abrasive paper on automatic polishing machine. The teeth were randomly divided into 11 groups. Each group was conditioned as follows: Group 1 : Dentin surface was not etched and not contaminated by hemostatic agents. Group2 : Dentin surface was not etched but was contaminated by Astringedent (Ultradent product Inc., Utah, U.S.A.). Group3 : Dentin surface was not etched but was contaminated by Bosmin (Jeil Phann, Korea.). Group4 : Dentin surface was not etched but was contaminated by Epri-dent (Epr Industries, NJ, U.S.A.). Group5: Dentin surface was etched and not contaminated by hemostatic agents. Group 6 : Dentin surface was etched and contaminated by Astringedent. Group7 : Dentin surface was etched and contaminated by Bosmin. Group8 : Dentin surface was etched and contaminated by Epri-dent. Group9 : Dentin surface was contaminated by Astringedent. The contaminated surface was rinsed by water and dried by compressed air. Group10 : Dentin surface was contaminated by Bosmin. The contaminated surface was rinsed by water aud dried by compresfed air. Group 11 : Dentin surface was contaminated by Epri-dent. The contaminated surface was rinsed by water and dried by compresfed air. After surface conditioning, F2000 was applicated on the conditoned dentin surface. The teeth were thermocycled in distilled water at $5^{\circ}C\;and\;55^{\circ}C$ for 1000 cycles. The samples were placed on the binder with the bonded compomer-dentin interface parallel to the lmife-edge shearing rod of the Universal testing machine(Zwick 020, Germany) running at a cross head speed of 1.0mmimin. There were no significant differences in shear bond strength between groups 1 and group 3 and 4, but group 2 showed significant decrease in shear bond strength compared with group 1. There were no significant differences in shear bond strength between group 5 and group 7 and 8, but group 6 showed significant decrease in shear bond strength compared with group 5. There were no significant differences in shear bond strength between group 5 and group 9, 10 and 11.

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EFFECT OF DENTIN SURFACE WETNESS ON TENSILE BOND STRENGTH OF SELF ADHESIVE RESIN CEMENTS (상아질 표면 젖음성이 수종 자가접착레진시멘트의 인장접착강도에 미치는 영향)

  • Yoon, Sung-Young;Park, Se-Hee;Kim, Jin-Woo;Cho, Kyung-Mo
    • Restorative Dentistry and Endodontics
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    • v.34 no.2
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    • pp.113-119
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    • 2009
  • The purpose of this study was to compare the tensile bond strength of several self-adhesive resin cements bonded to dentin surfaces with different wet conditions. Three self-adhesive resin cements: Rely-X Unicem (3M ESPE, St. Paul, MN. USA). Embrace Wetbond (Pulpdent. Oakland. MA. USA). Maxcem (Kerr. Orange. CA. USA) were used. Extracted sixty human molars were used. Each self-adhesive resin cement was adhered to the dentin specimens (two rectangular sticks from each molar) in different wet conditions. Tensile bond strength were measured using universal testing machine (EZ Test. Shimadzu corporation. Kyoto. Japan) at a crosshead speed of 1.0mm/min. After the testing. bonding failures of specimens were observed by Operative microscope (OPMI pro, Carl Zeiss. Oberkochen, Germany). T-test was used to evaluate the effect of dentin surface wetness. One-way ANOVA test was used to evaluate the tensile bond strength of self-adhesive resin cements in the same condition. Scheffe's test was used for statistical analyzing at the 95% level of confidence. The result showed that wetness of dentin surface didn't affect tensile bond strength of self-adhesive resin cements and Maxcem showed the lowest tensile bond strength.

A study for the performance evaluation of concrete block assembly wall without using mortar (무모르타르로 건식조립된 콘크리트블록 벽체의 성능평가 연구)

  • Lee, Joong-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.203-210
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    • 2019
  • A recent earthquake on the Korean Peninsula caused much damage to masonry buildings, and research on performance evaluation has been underway. A masonry building is generally constructed using wet construction and is affected by temperature, which reduces the efficiency of the construction. In this study, we propose a dry construction technique for assembling concrete blocks without using mortar and evaluated its performance through experimental and analytical research. To evaluate the performance, experiments were carried out for the prismatic compressive strength, direct terminal strength, and diagonal tensile strength of the dry construction wall. The adequacy of the cross section shape was also reviewed through FEM analysis. The results show that the compressive strength and diagonal tensile strength could exert a certain intensity or higher. Furthermore, the H-type module of a key block acted as a shear key for the entire concrete block, which resulted in excellent shear strength performance. In addition, the shape and thickness of the main block have a major effect on the strength performance of each block. Therefore, an optimal shape and the proposed dry construction method could be applied to replace the wet method by studying the construction or seismic performance of the proposed method.