• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.387-390
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• 1998

New Ag-deposited graphite anodes were developed using wet chemical reduction methods for depositing Ag metal onto graphite particles. In this paper, we investigated X-ray diffraction pattern and charge-discharge behavior for Ag-deposited graphite anode. The Lithium ion cello using Ag-deposited graphite anode showed a high average discharge voltage of 3.6∼3.W and a excellent cycle ability than that of conventional graphite. Little capacity loss in this battery may be due to the highly durable Ag-deposited graphite anodes.

• 고무기술
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• 제5권2호
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• pp.94-103
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• 2004

The present work describes modification of dual phase filler by electron beam irradiation in presence of multifunctional acrylates like trimethylol propane triacrylate (TMPTA) or silane coupling agent like bis (3-triethoxysilylpropyltetrasulphide) and in-fluence of the modified fillers on the physical properties of styrene-butadiene rubber (SBR) vulcanizates. Modulus at 300 % elongation increases whereas the tensile strength decreases with increase in radiation dose for the dual phase filler loaded styrene-butadiene rubber vulcanizates (SBR). However, modulus and tensile strength significantly increase, which is more, pronounced at higher filler loadings for TMPTA modified dual phase filler loaded SBR. These changes in properties are explained by the equilibrium swelling data and Kraus plot interpreting the polymer-filler interaction. Electron beam modification of the filler results in a reduction of tan ${\delta}$ at $70^{\circ}C$, a parameter for rolling resistance and increase in tan ${\delta}$ at $0^{\circ}C$, a parameter for wet skid resistance of the SBR vulcanizates. Finally, the influence of modified fillers on the properties like abrasion resistance, tear strength and fatigue failure and the improvement in the properties have been explained in terms of polymer-filler interaction.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.267.2-267.2
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• 2016

Semiconductor photo-catalysis offers the potential for complete removal of toxic chemicals through its effective and broad potential applications. Various new compounds and materials for chemical catalysts were synthesized in the past few decades. As one of the most important II-VI group semiconductors, zinc sulfide (ZnS) with a wide direct band gap of 3.8 eV has been extensively investigated and used as a catalyst in photochemistry, environmental protection and in optoelectronic devices. In this work, the ZnS films and nanostructures have been successfully prepared by wet chemical method. We show that the agglomerates with four successive scales are always observed in the case of the homogeneous precipitation of zinc sulfide. Hydrodynamics plays a crucial role to determine the size of the largest agglomerates; however, other factors should be invoked to interpret the complete structure. In addition, studies of the photocatalytic properties by exposure to UV light irradiation demonstrated that ZnS nanocrystals (NCs) are good photo-catalysts as a result of the rapid generation of electron-hole pairs by photo-excitation and the highly negative reduction potentials of excited electrons. A combination of their unique features of high surface-to volume ratios, carrier dynamics and rich photo-catalytic suggests that these ZnS NCs will find many interesting applications in semiconductor photo-catalysis, solar cells, environmental remediation, and nano-devices.

• 한국분말재료학회지
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• 제16권1호
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• pp.43-49
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• 2009

Titanium carbides are widely used for cutting tools and grinding wheels, because of their superior physical properties such as high melting temperature, high hardness, high wear resistance, good thermal conductivity and excellent thermal shock resistance. The common synthesizing method for the titanium carbide powders is carbo-thermal reduction from the mixtures of titanium oxide($TiO_2$) and carbon black. The purpose of the present research is to fabricate nano TiC powders using titanium salt and titanium hydride by the mechanochemical process(MCP). The initial elements used in this experiment are liquid $TiCl_4$(99.9%), $TiH_2$(99.9%) and active carbon(<$32{\mu}m$, 99.9%). Mg powders were added to the $TiCl_4$ solution in order to induce the reaction with Cl-. The weight ratios of the carbon and Mg powders were theoretically calculated. The TiC and $MgCl_2$ powders were milled in the planetary milling jar for 10 hours. The 40 nm TiC powders were fabricated by wet milling for 4 hours from the $TiCl_4$+C+Mg solution, and 300 nm TiC particles were obtained by using titanium hydride.

• 청정기술
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• 제20권3호
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• pp.269-276
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• 2014

본 연구는 수은연속측정시스템의 가장 중요한 구성 요소의 하나인 산화수은을 원소수은으로 환원시킬 수 있는 건식 환원촉매시스템 개발을 목적으로 수행되었다. 산화-환원 표준전위를 기준으로 산화수은의 원소수은으로의 환원반응을 자발적으로 일으킬 수 있는 촉매 대상물질로 Fe, Cu, Ni 및 Co 4종류의 전이금속이 선택되었다. 이들 전이금속 촉매들은 산소가 없는 반응가스 조성에서 산화수은의 원소수은으로의 환원반응에 대해 높은 활성을 보였다. 그러나 산소가 존재하는 경우 환원 활성이 크게 감소하는데 이는 산소에 의해 해당 전이금속이 산화수은 환원 활성이 낮은 전이금속산화물로 변환되기 때문이다. 반응가스에 산소가 존재하여도 수소를 공급하면 산화수은 환원 활성이 크게 증가되는데 이는 산화수은의 환원반응이 진행되는 고온에서 산소와 수소 사이의 연소반응에 의해 산소가 소모되기 때문으로 확인되었다. Fe를 환원촉매로 하고 배기가스에 수소를 공급하는 산화수은 환원촉매시스템은 $SnCl_2$ 수용액을 사용하는 습식화학 환원기술에 필적할 수준의 활성을 나타내기 때문에 상업적으로 적용 가능한 산화수은 환원시스템으로 기대된다.

• 한국잠사곤충학회지
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• 제36권2호
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• pp.110-114
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• 1994

93년 뽕나무 생육기에 내습한 이상저온 현상에 대한 감수정도와 요인을 분석하는 한편, 경감대책을 마련하기 위해 수원 잠업시험장과 충남 공주군에 소재한 충남도 잠업사업소 등 2개 장소에서 방임구를 대조로 요소엽면시비구 (요소 0.7%), 잠시비료 8호구 (요수 0.7%와 미량요소 함유), 그리고 질소질 6kg/10a를 황산암모늄으로 덧거름한 4개처리구를 설치하여 시험결과 다음과 같았다. 1. 여름베기후 뽕나무 생육기간 중인 6월 하순-9월 상순사이에 전국적으로 평년대비 평균기온은 1.4$^{\circ}C$ 낮았으며, 강우량은 83mm나 많았으며, 그 결과 가을뽕 수량은 평년대비 16.4% 감수되었는데, 뽕잎의 감수에 더 크게 영향하는 요인은 기온의 저하보다는 강우량의 과다에서 오는 질소질의 용탈에 원인하는 것으로 판단되었다. 2. 이상저온 내습시 생육부진을 막기 위해 요소 및 잠시비료 8호를 각각 엽면시비한 구보다는, 질소질 6kg/10a를 덧거름으로 시비한 구에서 5% 수준에서 통계적인 유의차가 인정될 정도로 증수되었다. 3. 뽕잎분석 결과 전질소 함량은 요소살포구와 질소질 덧거름구에서 방임구 3.53% 대비 0.53% 높았다.

• 마이크로전자및패키징학회지
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• 제19권4호
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• pp.25-31
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• 2012

Tin(II) acetate 전구체를 사용한 습식 환원 합성법으로 나노입자를 제조하는 공정에서 친환경 환원제(슈거) 및 캡핑제(젤라틴)를 사용하여 합성 조건 및 합성 시간에 따른 주석 나노입자의 합성 특성을 분석하였다. 글루코스 환원제를 사용하여 $70-110^{\circ}C$의 온도에서 합성 시 불규칙한 사슬 형태로 군집체를 이루면서 배열된 환원 나노입자들이 관찰되었다. FFT 패턴 분석으로부터 이러한 나노입자들은 $SnO_2$ 상으로 분석되었다. 수크로오스 환원제로 사용하여 $110^{\circ}C$에서 합성을 실시한 경우에서는 3시간의 합성 시간에서 평균 약 10 nm급의 미세한 구형 나노입자들을 형성시킬 수 있었으나, 합성 시간을 9시간으로 증가시킨 경우에서는 불규칙하게 뭉친 나노입자들 외에도 사슬 형태의 나노입자 군집체들이 국부적으로 형성되는 거동이 관찰되었다. 그러나 $130^{\circ}C$ 합성 시에는 사슬 형태의 나노입자 군집체들만을 관찰할 수 있었다. 그 결과 구형의 나노입자는 순수 Sn 상으로, 사슬 형태 나노입자 군집체들은 $SnO_2$ 상으로 각각 분석되었다.

• 대한금속재료학회지
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• 제49권8호
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• pp.596-600
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• 2011

Thermal degradation behavior of a $WO_3-TiO_2$ monolithic catalyst was investigated in terms of structural, morphological, and physico-chemical analyses. The catalyst with 4 wt.% $WO_3$ contents were prepared by a wet-impregnation method, and a durability test of the catalysts were performed in a temperature range between $400^{\circ}C$ and $800^{\circ}C$ for 3 h. An increase of thermal stress decreased the specific surface area, which was caused by grain growth and agglomeration of the catalyst particles. The phase transition from anatase to rutile occurred at around $800^{\circ}C$ and a decrease in the Brønsted acid sites was confirmed by structural analysis and physico-chemical analysis. A change in Brønsted acidity can affect to the catalytic efficiency; therefore, the thermal degradation behavior of the $WO_3-TiO_2$ catalyst could be explained by the transition to a stable rutile phase of $TiO_2$ and the decrease of specific surface area in the SCR catalyst.

• 현장농수산연구지
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• 제10권1호
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• pp.29-41
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• 2008

This research was conducted to develop a technology transfer and farmer's extension of newly released technology of Bokto seeding method for crop and vegetable production based on the theory of Asian and Pacific Center for Transfer of Technology(APCTT). This technology has recently transferred to not only Korea but also other countries like North Korea, China, Japan, Taiwan, Russia and Africa(Cameroon, Sudan and South Africa) since 2005. It has known as a highly reduction of production cost in terms of labors, chemical fertilizer and pesticides as well as environmental friendly due to a deep and side banded placement of chemical fertilizer at basal application. In addition this technology was proven to a precision farming on sowing depth and mechanism of chemical application method and also highly resistant against disasters like typhoon, flooding, low temperature, drought and lodging due to silicate application. It has improved a constraints such as a poor seedling establishment, weed occurrence, lodging, low yield and poor grain and eating quality in the previous direct seeding methods but still have a problem in occurrence of weedy rice and ununiformed operation of wet or flooded soil condition. Also this technology has a limit in marketing and A/S system. Based on a theory of APCTT evaluation and analysis this technology may be more concentrated on establishment of a special cooperation team among researcher and scientists, extension workers, industry sections and governmental sectors in order to rapidly transfer this technology to farmer's field. Also there will be needed to operate a web site for this newly released technology to inform and exchange an idea, experiences and newly improved information. A feed back system might be operated in this technology as well to improve a technology under way on users' operation. Also user's manual will be internationally released and provided for farmer's instruction and training at field site.

• 펄프종이기술
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• 제43권5호
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• pp.60-67
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• 2011

Hemicelluloses pre-extracted from Korean mixed wood chip were investigated as a wet-end additive. Hemicelluloses dissolved in hot water and alkali solution were isolated by ethyl alcohol precipitation from pre-extractives. They showed molecular weight of 9,000 ~ 27,000 g/mol as revealed by size exclusion chromatography. The reduction of molecular weight through hot water extraction was caused by autohydrolysis. Chemical composition of the hemicelluloses were analyzed with high-performance liquid chromatography and UV-Vis spectroscopy. As the surface charge of isolated hemicelluloses were negative, the adsorption of hemicelluloses onto softwood unbleached kraft pulp fiber was promoted by poly-DADMAC. The physical properties of handsheets increased as the molecular weight of hemicellulose increased. On the other hands, the optical property decreased with hemicellulose adsorption.