• Bulletin of the Korean Chemical Society
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• 제5권4호
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• pp.135-140
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• 1984

The reduction of vacuum-dehydrated $Na_xAg_{12-x}-A, 0 {\le} x {\le} 9.2$, and its reoxidation by O$_2$, have been studied by X-ray powder diffraction. Also, the structure of $Na_6Na_6-A$ treated with hydrogen at room temperature has been studied by single crystal methods in the cubic space group Pm3m at $24{\circ}C (a = 12.221(2) {\AA})$. The diffraction pattern of dehydrated Ag$_{12}$-A reduced by H$_2$ contains only the (111) and (200) reflections of silver metal, indicationg that the zeolite structure has been lost, but the zeolite's diffraction pattern and structural integrity can be fully restored by oxidation with O$_2$ at 100 or 200${\circ}C$. In contrast, the structures of $Na_xAg_{12-x}-A$, x = 4.5 and 9.2, were not destroyed by treatment with hydrogen. Dehydrated Na$_6Ag_6$-A treated with 50 Torr of hydrogen gas at 24${\circ}C$ for 30 minutes has $6\; Na^+\;and\;1.27\;Ag^+$ ions at 6-ring sites. These $Ag^+ ions are associated with 2.54 Ag${\circ}$ atoms to form 1.27 $Ag_3^+$ clusters per unit cell. Also found were 0.7 $Ag_3^{2+}$ clusters per unit cell near the 8-rings. The structure was refined to the final error indices R$_1$ = 0.134 and R$_2$ (weighted) = 0.147, using 168 independent reflections for which $I_0 >3{\sigma}(I_0)$.

• Bulletin of the Korean Chemical Society
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• 제13권1호
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• pp.70-74
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• 1992

Two crystal structures of ethylene (a= 12.272(2) ${\AA}$) and acetylene (a = 12.245(2) ${\AA}$) sorption complexes of dehydrated fully $Ca^{2+}$-exchanged zeolite A have been determined by single crystal X-ray diffraction techniques in the cubic space group, Pm3m at $21(1)^{\circ}C$. Their complexes were prepared by dehydration at $360^{\circ}C$ and $2{\times}10^{-6}$ Torr for 2 days, followed by exposure to 200 Torr of ethylene gas and 120 Torr of acetylene gas both at $24^{\circ}C$, respectively. The structures were refined to final R (weighted) indices of 0.062 with 209 reflections and 0.098 with 171 reflections, respectively, for which I > 3${\sigma}$(I). The structures indicate that all six $Ca^{2+}$ ions in the unit cell are associated with 6-oxygen ring of the aluminosilicate framework. Four of these extend somewhat into the large cavity where each is coordinated to three framework oxide ions and an ethylene molecule and/or an acetylene molecule. The carbon to carbon distance in ethylene sorption structure is 1.48(7) ${\AA}$ and that in acetylene sorption structure 1.25(8) ${\AA}$. The distances between $Ca^{2+}$ ion and carbon atom are 2.87(5) ${\AA}$ in ethylene sorption structure and 2.95(7) ${\AA}$ in acetylene sorption structure. These bonds are relatively weak and probably formed by the electrostatic attractions between the bivalent $Ca^{2+}$ ions and the polarizable ${\pi}$-electron density of the ethylene and/or acetylene molecule.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.117-121
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• 1984

The structure of $CS_{7.3}Ag_{4.7}Si_{12}Al_{12}O_{48}$, vacuum dehydrated zeolite A with all Na+ ions replaced by $Cs^+$ and $Ag^+$ as indicated, has been determined by single-crystal x-ray diffraction techniques in the cubic space group, Pm3m (a = 12.282 (1) ${\AA}$). The structure was refined to the final error indices $R_1$$R_2$ (weighted) = 0.099 using 347 independent reflections for whind intlch $I_0\;>\;3{\sigma}(I_0)$. Although deydration occurred at $360^{\circ}C$, no silver atoms or clusters have been observed. The 8-ring sites are occupied only by $Cs^+$ ion, and the 4-ring sites only by a single $Ag^+$ ion. The 6-ring sites contain $Ag^+$ and $Cs^+$ ions with $Ag^+$ nearly in 6-ring planes and $Cs^+$ well off them, one on the sodalite unit side. With regard to the 6-rings, the structure can be represented as a superposition of two types of unit cells: about 70 % have $4Ag^+$ and $4Cs^+$ ions, and the remaining 30 % have $3Ag^+$ and $5Cs^+$. In all unit cells, $3Cs^+$ ions lie at the centers of the 8-rings at sites of D4h symmetry; these ions are approximately 0.3 ${\AA}$ further from their nearest framework-oxygen neighbors than the sum of the appropriate ionic radii would indicate. To minimize electrostatic repulsions, the $Cs^+$ ions at Cs(1) are not likely to occupy adjacent 6-rings in the large cavity; they are likely to be tetrahedrally arranged when there are 4.

• 한국음향학회지
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• 제40권5호
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• pp.496-502
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• 2021

딥러닝 기반의 심층 화자 임베딩 방식은 최근 문장 독립 화자 검증 연구에 널리 사용되고 있으며, 기존의 i-vector 방식에 비해 더 좋은 성능을 보이고 있다. 본 연구에서는 심층 화자 임베딩 방식을 발전시키기 위하여, 화자의 그룹 정보를 도입한 그룹기반 화자 임베딩을 제안한다. 훈련 데이터 내에 존재하는 전체 화자들을 정해진 개수의 그룹으로 비지도 클러스터링 하며, 고정된 길이의 그룹 임베딩 벡터가 각각의 그룹을 대표한다. 그룹 결정 네트워크가 각 그룹에 대응되는 그룹 가중치를 출력하며, 이를 이용한 그룹 임베딩 벡터들의 가중 합을 통해 집합 그룹 임베딩을 추출한다. 최종적으로 집합 그룹 임베딩을 심층 화자 임베딩에 더해주어 그룹기반 화자 임베딩을 생성한다. 이러한 방식을 통해 그룹 정보를 심층 화자 임베딩에 도입함으로써, 화자 임베딩이 나타낼 수 있는 전체 화자의 검색 공간을 줄일 수 있고, 이를 통해 화자 임베딩은 많은 수의 화자를 유연하게 표현할 수 있다. VoxCeleb1 데이터베이스를 이용하여 본 연구에서 제안하는 방식이 기존의 방식을 개선시킨다는 것을 확인하였다.

• 한국지리정보학회지
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• 제21권4호
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• pp.119-131
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• 2018

휴대용 기기와 다양한 위치 기반 서비스의 확산으로 공간데이터의 양적 팽창이 가속화됨에 따라 대용량의 공간데이터를 효율적으로 다룰 수 있는 기술의 중요성이 점차 커지고 있다. 클라우드 컴퓨팅은 인터넷을 통해 스토리지, 메모리, 애플리케이션 등 다양한 전산 자원을 공유할 수 있는 서비스 환경으로, 최근 이를 활용해 대용량의 공간데이터를 처리, 분석하는 방법과 그 필요성에 관한 연구가 활발히 수행되어 왔다. 그러나 아직까지 대용량 공간데이터의 분석에 클라우드 컴퓨팅 플랫폼을 활용했을 때 어느 정도의 성능 향상을 기대할 수 있는지에 대한 실증적 연구는 비교적 많이 이루어지지 않았으며, 본 연구의 목표는 이러한 논의의 공백을 채우는 것이다. 이를 위해 연구에서는 클라우드 컴퓨팅 플랫폼에서 병렬 연산을 사용했을 때 모란지수와 지리가중회귀분석의 연산 속도가 어느 정도 향상되는지 살펴보았으며, 그 결과를 통해 클라우드 컴퓨팅을 활용한 공간분석의 효율성을 평가하였다. 실험 결과, 중앙처리장치의 클록 수가 더 높은 로컬 컴퓨터에 비해 병렬 연산에 적합한 환경을 갖춘 공용 클라우드 컴퓨팅 플랫폼에서 좀 더 효율적인 연산이 가능했으며, 데이터의 규모가 클수록 격차가 더욱 크게 나타났다.

• Bulletin of the Korean Chemical Society
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• 제7권3호
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• pp.190-193
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• 1986

The structure of partially $Ag^+$-exchanged zeolite 4A, $Ag_{7.6}Na_{4.4}-A$, vacuum dehydrated at $370^{\circ}C$, has been determined by single-crystal x-ray diffraction techniques in the cubic space group, Pm3m (a = 12.311(1)${\AA}$) at $24(1)^{\circ}}C$. The structure was refined to the final error indices $R_1$ = $R_2$ (weighted) = 0.064 using 266 independent reflections for which $I_0$>$3{\sigma}(I_0)$. Three $Na^+$ ions occupy the 3 8-ring sites, and the remaining ions, 1.4 $Na^+$ and 6.6 $Ag^+$, fill the 8 6-ring sites; each $Ag^+$ ion is nearly in the [111] plane of its 3 O(3) ligands, and each $Na^+$ ion is 0.9${\AA}$ from its corresponding plane, on the large-cavity side. One reduced silver atom per unit cell was found inside the sodalite unit. It was presumably formed from the reduction of a $Ag^+$ ion by an oxide ion of a residual water molecule or of the zeolite framework. It may be present as a hexasilver cluster in 1/6 of the sodalite units, or, most attractively among several alternatives, as an isolated Ag atom coordinated to 4 Ag ions in each sodalite unit to give $(Ag_5)^{4+}$, symmetry 4mm.

• Bulletin of the Korean Chemical Society
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• 제6권4호
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• pp.202-206
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• 1985

The crystal structure of The crystal structure of $Ag^+$-Exchanged Zeolite A, $Ag_{4.6}Na_{7.4}-A$, dehydrated, treated with $H_2$, and evacuated, all at $350^{\circ}C$, has been determined by single crystal x-ray diffraction methods in the cubic space group Pm3m at $24(1)^{\circ}C;$ a = $12.208(2)\AA.$ The structure was refined to the final error indices R1 = 0.088 and R2 (weighted) = 0.069 using 194 independent reflections for which II_0$ > $3{\sigma}(I_0)$. On threefold axes near the centers of 6-oxygen rings, $7.4 Na^+$ ions and $0.6 Ag^+$ ions are found. Two non-equivalent 8-ring $Ag^+$ ions are found off the 8-ring planes, each containing about $0.6 Ag^+$ ions. Three non-equivalent Ag atom positions are found in the large cavity, each containing about 0.6 Ag atoms. This crystallographic analysis may be interpreted to indicate that $0.6 (Ag_6)^{3+}$ clusters are present in each large cavity. This cluster may be viewed as a nearly linear trisilver molecule $(Ag_3)^0$ (bond lengths, 2.92 and 2.94 $\AA;$ angle, $153^{\circ})$ stabilized by the coordination of each atom to a Ag^+$ ion at 3.30, 3.33, and 3.43 $\AA$, respectively. In addition, one of the silver atoms approaches all of the 0(1) oxygens of a 4-ring at $2.76\AA.$ Altogether $7.4 Na^+$ ions, $1.8 Ag^+$ ions, and 1.8 Ag atoms are located per unit cell. The remaining $1.0 Ag^+$ ion has been reduced and has migrated out of the zeolite framework to form silver crystallites on the surface of the zeolite single crystal.

• 한국임상수의학회지
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• 제38권1호
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• pp.45-48
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• 2021

A 6-year-old, 26 kg spayed female Great Dane presented with back pain and hindlimb paresis. On neurological examination, severe pain was detected on the lumbosacral joint displaying nerve-root signature. The animal presented with lower motor neuron paresis with normal deep pain perception. Radiographic examination revealed narrowing of the lumbosacral joint disc space with endplate destructive lysis. Magnetic resonance imaging of the lumbosacral joint revealed a cauda equina compression, especially on the left. On T2 and T1-weighted images, a mass sized 1 × 1 cm was identified laterally to the left of the lumbosacral joint with hyperintense signal. The lumbosacral joint was stabilized by applying the dorsal distraction fixation-fusion technique and dorsal laminectomy. The soft tissue mass was removed, and a bacterial culture was performed. Coagulase-negative Staphylococcus spp. were detected and discospondylitis was treated with clindamycin for 6 weeks. The patient showed clinical improvement without pain and hindlimb paresis until 6 months follow-up postoperatively.

• Advances in aircraft and spacecraft science
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• 제8권4호
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• pp.345-372
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• 2021

The analysis of nonlinear vibrations, buckling, post-buckling, flutter boundary determination and post-flutter behavior of a homogeneous curved plate assuming cylindrical bending is conducted in this article. Other assumptions include simply-supported boundary conditions, supersonic aerodynamic flow at the top of the plate, constant pressure conditions below the plate, non-viscous flow model (using first- and third-order piston theory), nonlinear structural model with large deformations, and application of mechanical and thermal loads on the curved plate. The analysis is performed with constant environmental indicators (flow density, heat, Reynolds number and Mach number). The material properties (i.e., coefficient of thermal expansion and modulus of elasticity) are temperature-dependent. The equations are derived using the principle of virtual displacement. Furthermore, based on the definitions of virtual work, the potential and kinetic energy of the final relations in the integral form, and the governing nonlinear differential equations are obtained after fractional integration. This problem is solved using two approaches. The frequency analysis and flutter are studied in the first approach by transferring the handle of ordinary differential equations to the state space, calculating the system Jacobin matrix and analyzing the eigenvalue to determine the instability conditions. The second approach discusses the nonlinear frequency analysis and nonlinear flutter using the semi-analytical solution of governing differential equations based on the weighted residual method. The partial differential equations are converted to ordinary differential equations, after which they are solved based on the Runge-Kutta fourth- and fifth-order methods. The comparison between the results of frequency and flutter analysis of curved plate is linearly and nonlinearly performed for the first time. The results show that the plate curvature has a profound impact on the instability boundary of the plate under supersonic aerodynamic loading. The flutter boundary decreases with growing thermal load and increases with growing curvature.

• 감성과학
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• 제26권1호
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• pp.33-42
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• 2023

기존의 연령별 얼굴정서 인식 비교 연구에서는 정서별로 연령 간에 어떤 차이가 있는지 밝혔다. 이에 Kim(2021) 연구에서는 개별 정서가 아닌 정서공간에서 표상된 정서를 연령 간 비교하였다는 점에서 의의가 있으나, 기술적(descriptive) 비교만 시행하였을 뿐, 통계적 유의미 검증을 하지 않았다는 한계가 있다. 본 연구에서는 표상 유사성 분석(representational similarity analysis) 방법을 통해 연령간 실제 데이터 및 정서 모델 유사성행렬을 직접적으로 비교하였다. 또한 개인차 다차원척도법(individual differences multidimensional scaling)을 통해 연령간 정서 차원에 대한 비중을 비교하였다. 그 결과 실제 데이터 비교에서 노년 집단은 청년 및 중년 집단과 가장 유사하지 않았으며, 쾌불쾌 차원이 포함된 정서 모델과의 유사성 비교에서도 가장 유사하지 않았다. 또한 노년 집단은 각성 차원에 대한 비중이 청년 및 중년 집단과 유사하지 않음이 발견되었다. 본 연구는 실제 데이터, 정서 모델, 그리고 정서 차원 비중이라는 세 가지 측정치에 대해 노년 집단과 청년 및 중년 집단과의 차이를 통계적으로 검증하였다는 점에서 의의가 있다.