• Journal of The Geomorphological Association of Korea
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• 제20권3호
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• pp.55-63
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• 2013

The study deals with the geochemical analyses on the stratigraphy and sedimentation of the paleofluvial outcrop under Jeongok basalt layer in Chugaryeong Rift Valley. The results of field survey and analysis show that the paleofluvial sand and gravel layers had been constructed before the arrival of basaltic lava in Jeongok area of Hantan River valley in central Korea. XRF, for the main elements analysis, results present that JG2-3, a test sample from basalt weathering layer, has different characteristics from 5 other samples in the aspects of chemical weathering levels. ICP-MS, for analysis of the rare earth elements analysis, estimates that gravel layer, in the lowest part of the outcrop, had been originated from pre-lava bedrocks near the upper reach of the Hantan River, so the layer is almost not related to basalt layers. Finally, the OSL dating results in paleofluvial sedimentation had been in process until nearly 40,000 BP, before formation of lava plateau in the Jeongok area.

• Journal of The Geomorphological Association of Korea
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• 제24권3호
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• pp.27-45
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• 2017

At the upper part of terrace deposits at Jeongdongjin area, there is a structure in which reddish brown and grayish white layers laying horizontally. Previous studies have reported the existence of these structures within the deposits and suggested the theoretical background related to the formation process. However, the analysis of physical properties and chemical composition such as particle size, classification, etc. of the materials constituting the reddish brown and grayish white layers is scarcely done. In this study, the physico - chemical properties of gray - white and reddish brown beds are investigated. The mean grain size of the particles was less than $4{\varphi}$ in both layers and the reddish brown layer was more coarse. The results shows that the sorting of the grayish white layer is better. The chemical composition of both layers shows that the average concentration of $SiO_2$, $Al_2O_3$ and $K_2O$ of the grayish white layer was higher than those of the reddish brown layer. The concentration of $Fe_2O_3$ of reddish brown lyaer was 3 times higher than those of the grayish white layer. The degree of chemical weathering (CIA) is 90 or so in both the reddish brown and grayish white layers, indicating a significant level of chemical weathering. In conclusion, reddish brown layers had been formed by the processes related to the migration of iron and the migration of water that induced aggregation after the formation of sediments (psudo-gleization). In this study area, a vertical layer of grayish white which cuts off horizontal reddish brown and grayish white color was found. The vertical layer or wedge similar to a ice-wedge or columnar structure that in a cold environment, and there is a difference in shape and size. The vertical layer appears to have occurred three or more cycles. The vertical layers begin to form at a certain height within the outcrop and descend downwards, which of course is difficult to see as directing certain times.

• The Journal of Engineering Geology
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• 제31권4호
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• pp.731-739
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• 2021

This research aimed to analyze the characteristics of topsoil for soil conservation and promote the process of turning subsoil into topsoil. The physicochemical characteristics of topsoil and subsoil of different types of soil were compared, and their quantitative differences were examined. 204 soil samples were collected from a total of 102 areas according to rock types. These samples were tested to measure grain size, water content, and unit weight, along with XRF and XRD analyses. The topsoil and subsoil of the soil samples were also analyzed. The results of this research showed that the topsoil and subsoil had different physical characteristics, and that the chemical alteration index of the topsoil was higher than that of the subsoil. This would imply that the topsoil was high in clay minerals since it was directly affected by weathering more than the subsoil. In particular, vermiculite, one of the final products generated from weathering, was common in the topsoil.

• Korean Journal of Soil Science and Fertilizer
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• 제27권3호
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• pp.158-167
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• 1994

The various weathering products derived from andesitic rocks in the Guweol mountain area of Pusan have been studied in order to investigate the occurrence, characteristics and evolutional trend of clay minerals in the weathered rock and soil using mainly X-ray powder diffraction method. Kaolinite and halloysite are very abundant in the weathered rocks and soils derived from andesitic rocks of this area. Also, $12{\AA}$- and $14{\AA}$-minerals occur in the considerable amount. $12{\AA}$-minerals have been identified as mica/vermiculite interlayer minerals showing the $25{\AA}$ basal reflection. Their crystal sizes are relatively big showing more than 10 micron in diameter. Two types of $14{\AA}$-mineral, which are vermiculite/smectite interlayer mineral and Al-vermiculite, have been observed. Kaolin minerais consist of kaolinite, $10{\AA}$ and $7{\AA}$ halloysite. Kaolinite relatively dominates in the strongly weathered soil of the area. In contrast with kaolinite. $12{\AA}$- and $14{\AA}$-minerals such as vermiculite/smectite and mica/vermiculite interlayer minerals tend to occur in the weakly to intermediately weathered products. Based on their occurrences, it strongly suggests that they are intermediate products in the course of the weathering process from the parent materials into the kaolin mineral.

• Economic and Environmental Geology
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• 제39권6호
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• pp.629-641
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• 2006

The Standing Buddha Statue in the Gwanchoksa temple consists of medium to coarse grained biotite granodiorite with dark grey color, and it has a week gneissosity along the pegmatite veins. The results of magnetic susceptibility and geochemical patterns of the host rock of Standing Buddha Statue and the basement rock suggest that both values are formed from the co-genetic magma with the same differentiation process. The CIAs of the basement rock and the Standing Buddha Statue are calculated to 51.43 and 50.86, and the WPIs are estimated 4.52 and 8.95, respectively. So the weathering potential from the host rock of Standing Buddha Statue and basement rock prove to be high. The Standing Buddha Statue is terribly damaged with physical weathering from deterioration and exfoliation, and are scattered with secondary pollutant and precipitate. Basement rock is also in danger of ground collapse because of irregularly developed discontinuity system. Most surface of Standing Buddha Statue is seriously discolored into yellowish brown and dark gray, or black precipitates are also formed. Moreover, it is heavily covered with crustose lichen, fungi and algae, or moss are also found. In order to control the influential factors with the complex deterioration of Standing Buddha Statue, it is needed to rearrange a site environments, and conservation scientific management is required to protect it from covering lichens, exfoliations and fractures.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제14권8호
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• pp.4033-4038
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• 2013

Sedimentary rocks from construction waste are discarded through open storage and landfilling, which causes an increase in construction cost and inefficient of execution of works. Some sandstone are selected and utilized as aggregates, but shale is buried as industrial waste. Therefore, in this research, we evaluated weathering properties of shale aggregate that is widely distributed throughout Daegu-Kyeongbuk region and freeze-thaw characteristics of concrete according to the replacement ratio of shale aggregate, in an effort to stabilize aggregate supply-demand in Daegu-Kyeongbuk region and develop alternative aggregates. We used red shale and black shale in the experiment, which were exported from a construction site in Deagu. We verified the usage of shale as a concrete aggregate by comparing andesite, which is broadly used as a thick aggregate for concrete, to hornfels, which is a metamorphic sedimentary rock. As a result of the experiment, we observed no degradation phenomenon for andesite and hornfels. However, a part of country rock containing black shale was found to be exfoliated. Red shale started having cracks in the direction of stratification after 1.5 months of direct exposure, and it broke into smaller pieces after approximately 4 months. After 300 cycles of freeze-thaw process on the concrete manufactured according to the replacement ratio of shale aggregate, the modulus of elasticity was 97% for plain and 95% for hornfels. In the case of RS_100, it was 57% after 210 cycles, and for BS_100, it was 54% after 240 cycles. Therefore, we established that, as the number of repetition increases, the freeze-thaw resistance decreases dramatically.

• Journal of The Geomorphological Association of Korea
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• 제19권3호
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• pp.23-36
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• 2012

This study aims to think about the problem of dolmens: the reasons for the presence of dolmens and how to construct it, at the point of view of geographical and geomorphological. The subjects of this study is the dolmens which locate between at Dogok Hyosanri and Chunyang Daesinri Hwasoon-gun, Jeonlanamdo. The study areas in Hyosanri, Daesinri has been observed as follows. First, the long axis direction of Dolmen upper stone and the slope one are the same. Second, tor, block stream, hockey stick, etc. Third, Composition of the soil silt> sand> clay is distributed in the order. Forth, The soil of high quality silt and the roundness of angular, sub-angular-level and the high frequency, peaks of quarts and illite clay minerals show. Fifth, in the result of $SiO_2/Al_2O_3$, $SiO_2/R_2O_3$, and CIA(Chemical Index of Alteration), Hyosanri, Daesinri areas show mechanical weathering was dominant and chemical weathering environment was not being progressed. The blocks used in construction of dolmens had moved to the bottom of slopes by mass movement such as solifluction then them which had been placed in the position seem to be used by people of Bronze. Based on the above results, the process of construction of dolmens can be estimated as follows. They would dig up the ground under the upper stone of dolmens, put the supporting stone in the place, then dig up earth, place into remains, close the obturating stones, then heal up earth.

• Journal of the Mineralogical Society of Korea
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• 제23권2호
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• pp.125-139
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• 2010

Behavior of heavy metals and arsenic in the tailings of Songcheon Au-Ag mine was characterized via both mineralogical and geochemical methods. Mineral composition of the tailings was investigated by X-ray diffractometry, energy-dispersive spectroscopy, and electron probe micro-analyzer (EPMA) and total concentrations of heavy metals and arsenic and their chemical forms were analyzed by total digestion of aqua regia and sequential extraction method, respectively. The results of mineralogical study indicate that the tailings included mineral particles of resinous shape mainly consisting of galena, sphalerite, pyrite, quartz, and scorodite, and specifically socordite was identified in the form of matrix. EPMA quantitative analyses were performed to evaluate the weatherability of each mineral, and the results suggest that it decreased in the sequence of arsenopyrite > galena > sphalerite > pyrite. The weathering pattern of galena was observed to show distinctive zonal structure consisting of secondary minerals such as anglesite and beudantite. In addition, almost all of arsenopyrite has been altered to scorodite existing asmatrix and galena, sphalerite, and pyrite which have lower weatherability than arsenopyrite were identified within the matrix of scorodite. During the process of alteration of arsenopyrite into scorodite, it is likely that a portion of arsenic was lixiviated and caused a great deal of detrimental effects to surrounding environment. The results of EPMA quantitative analyses verify that the stability of scorodite was relatively high and this stable scorodite has restrained the weathering of other primary minerals within tailings as a result of its coating of mineral surfaces. For this reason, Songcheon tailings show the characteristics of the first weathering stage, although they have been exposed to the surface environment for a long time. Based on the overall results of mineralogical and geochemical studies undertaken in this research, if the tailings are kept to be exposed to the surface environment and the weathering process is continuous, not only hazardous heavy metals, such as lead and arsenic seem to be significantly leached out because their larger portions are being partitioned in weakly-bound (highly-mobile) fractions, but the potential of arsenic leaching is likely to be high as the stability of scorodite is gradually decreased. Consequently, it is speculated that the environmental hazard of Songcheon mine is significantly high.

• Journal of the Korea Institute of Building Construction
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• 제23권5호
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• pp.559-570
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• 2023

The corrosion of structural steel used in the construction industry is increasing due to the industrialization where many aggressive ions released in the atmosphere. Therefore, in the present study Al coating was deposited by arc and plasma arc thermal spray process and compared their effectiveness in simulated weathering condition i.e. Society of Automotive Engineers(SAE) J2334 solution which mostly contain Cl^- and CO₃^2- ions. Different analytical techniques have been used to characterize the coating and draw the corrosion mechanism. The Al coating deposited by plasma arc thermal spray process exhibited uniform, dense and layer by layer deposition resulting higher bond adhesion values. The open circuit potential(OCP) of Al coating deposited this process is exhibited more electropositive values than arc thermal spray process in SAE J2334 solution with immersion periods. The total impedance of plasma arc thermal spray process exhibited higher than arc thermal spray process. The corrosion rate of the plasma arc thermal sprayed Al coating is reduced by 20% compared to arc thermal spray process after 23 days of immersion in SAE J2334 solution.

• Journal of Conservation Science
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• 제16권
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• pp.77-88
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• 2004

This study evaluates the occurrences, phyfical weathering and biological deterioration on rock properties during the dissection process an object of stone pagoda in the Mireuksaji temple site. For restoration and conservation, all kinds of rock properties are carried out detailed scientific investigation and diagnosis. Constituting rocks of the pagoda composed mainly of equi-granular medium grained biotite that rock properties presumed to be use about 3,000 materials. Main external properties of the pagoda are total 446 materials, and the rock properties under the concentration load on the each floors occurred with overlapping fracture, weathering and deteriorations. The 84 materials show highly degraded about $18.8\%$ among the external properties. Representative physicochemical deteriorations are fracture, loss, break, exfoliation, degradation, grain shaped dissolution, relief surface, discoloration and hydroxide precipitates, in this study, the deterioration state of each properties give a precisely description and analysis. Coverage of lichen and algae on the rock surface represented about $85\%$. As the some properties, biological contaminants withered up when spray rock surface with diluted cleaning chemicals. Results of the study are utilized an application for restoration system and detailed investigation during the dissection process of stone cultural properties.