• The Journal of the Petrological Society of Korea
• /
• v.16 no.1 s.47
• /
• pp.27-37
• /
• 2007

Here we discuss a geochemical characterisitc of rare earth element (REE) pattern of a Precambrain leucogranitic gneiss at Imweon, Gangwon Province, Korea. The outcrop includes biotite gneiss xenolith. The leucocratic granite gneiss contacting with biotite gneiss is pegmatitic. However, there is no evidence of contact metamorphism between biotite gneiss and leucocratic-pegmatitic granite gneiss. The leucocratic granite gneiss shows a specific phenomenon of M-type (convex curved) tetrad effect in chondrite-normalized REE patterns with large negative Eu anomaly. The degree of REE tetrad effect in the leucocratic-pegmatitic granitec gneiss is weak and shows partly W-type (concave curved) tetrad effect. The Eu anomaly of leucocratic granite gneiss has close relationship with the degree of tetrad effect as well as Ca/Sr ratio. Our results suggest that the REE tetrad effect from the leucocratic granite gneiss should be formed during differentiation process of granitic magma. We also confirmed that the weathering might affect Eu or Ce anomaly rather than the formation of REE tetrad effect in granitic rock.

• Economic and Environmental Geology
• /
• v.55 no.6
• /
• pp.717-726
• /
• 2022

This study was conducted to assess the geochemical contamination degree of As, Cd, Cu, Pb, Sb, and Zn in the soil and water samples from an abandoned gold mine. Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI) were carried out to assess the geochemical contamination degree of the soil samples. Variations of sulfate and heavy metals concentration in water samples were determined to identify the geochemical distribution with respect to the distance from the mine tailing dam. Geochemical pollution indices indicated significant contaminated with As, Cd, Pb, and Zn in the soil samples that areas close to the mine tailing dam, while, Sb showed similar indices in all soil samples. These results indicated that the As, Cd, Pb, and Zn dispersion has occurred via anthropogenic sources, such as mining activities. In terms of water samples, anomalies in the concentrations of As, Cd, Zn, and SO₄^2- was determined at specific area, in addition, the concentrations of the elements gradually decreased with distance. This result implies the heavy metals distribution in water has carried out by the weathering of sulfide minerals in the mine tailing and soil. The study area has been conducted the remediation of contaminated soil in the past, however, the geochemical dispersion of heavy metals was supposed to be occurred from the potential contamination source. Therefore, continuous monitoring of the soil and water is necessary after the completion of remediation.

• Korean Journal of Soil Science and Fertilizer
• /
• v.25 no.3
• /
• pp.202-212
• /
• 1992

This study reports on the genesis and mineralogical characteristics of the clay minerals in the soils derived from the five major parent rocks of granite, granite-gneiss, limestone, shale, and basalt in Korea. The investigation on the mineralogical aspects of primary and secondary minerals of the rocks and coarse fractions in the soils have been already reported. In this report, the identification of clay minerals in the soil clay fractions was done through the analyses of chemical, X-ray diffraction, and thermal methods. The studies showed clearly that much of the clay minerals was evolved by the weathering of primary minerals and some were further developed by the transformation of secondary minerals. Cation exchange capacity(CEC) of the clay fractions increased with higher amotunts of vermiculite, chlorite, and illite, however, decreased with higher hydroxy octahedral sheet within the interlayer spaces of vermiculite even if dominant clay with vermiculite. Feldspars in the granite and granite-gneiss might be completely transformed to kaolin mineral, Illite, chlolrite, and vermiculite formed by the alteration of micas, amphibole, augite, and primary chlorile seem to be subsequently transformed to the mixed layer minerals such as illite/vermiculite, illite/chlorite, and chlorite/vermiculite. These weathering products may be ultimately transformed into kaolin minerals. The smectite minerals in the clay fractions of the soils developed on the limestone are considerably present and they seem to be formed directly by the precipitation from high Mg solution and/or by the transformation of vermiculite from micas and chlorite in the parent materials. Abundant presence of illite in the soil clays developed on the shale is considered to have inherited from the fine particles and more resistant hydrous muscovite. The weathering sequences of the hydrous muscovite were as follows according to the degree of soil development ; hydrous muscovite ${\rightarrow}$ illite/vermiculite mixed layer(Inceptisols, Daegu series) and hydrous muscovite ${\rightarrow}$ illite/vermiculite mixed layer ${\rightarrow}$ vermiculite ${\rightarrow}$ kaolin mineral(Alfisols, Buyeo series). The plagioclase in the basalt might be mostly weathered to kaolin minerais. The augite in the basalt is likely to be transformed through progressive stage of weathering, augite ${\rightarrow}$ chlorite ${\rightarrow}$ chlorote/vermiculite mixed layer ${\rightarrow}$ vermiculite ${\rightarrow}$ kaolin. Another weathering sequence of augite could be expected, augite ${\rightarrow}$ chlorite ${\rightarrow}$ illite by the presence of illite and illite/vermiculite mixed layer in the clay fractions. Vermiculite and gibbsite were quantified from thermogravimetry(TG) and kaolin minerals, from both TG and differerential thermal analysis (DTA). Vermiculite in Jangseong series from the limestone was the dominant clay mineral of 21.7 percent and had a range in the order of 9.2 percent in Buyeo series to 5.4 percent in Daegu series from the shale. The rest soils ranged from 8.8 to 28.3 percent. Kaolin minerals were the dominant clay mineral of 32.7 percent in Asan series from the granite-gneiss and Gueom series of 32.0 percent from the basalt. The soils from the limestone ranged from 9.4 to 14.9 percent. The rest soils ranged from 8.9 to 28.6 percent. Gibbsite were 3.9 and 2.3 percent for Weoljeong and Chahang series from the granite, respectively. In Asan and Cheongsan series from the giranite-gneiss were 1.4 and 4.5 percent, respectively, and 3.6 percent in Jangpa series from the basalt.

• Journal of the Korean Geographical Society
• /
• v.30 no.2
• /
• pp.103-119
• /
• 1995

This Paper aims to compare the lower marine terraces distributed from Muckho to Gangneung in the mid-eastern coast of Korean peninsula by the geomorphic method of using characteristies of terrace features and terrace deposits, paleosol, and fossil cryogenic structures, and to estimate the age of the lower marine terraces on the basis of the comparisons of those with the characteristics of thalassostatic terrace in adjacent rivers. The 1ower marine terraces in this area can be classified into two levels, i.e., lower marine terrace I and II surfaces, in desending order, according to the difference of former shoreline altitude. The former shoreline heights of the lowerm marine terrace I and II surfaces are 18m and 10m, respectiveiy. The width of the I surface is broader and distributed more continuousiy than that of II surface. Daejin I surface in Muckho coast, and Myeongju and Anin terrace in Gangneung coast could be classified into the lower marine terrace I surface, and Daejin II surfaCe into II surface. The Surface of ancient shore platform of the lower marine terrace I and II surfaces were weathered, and the color of the terrace deposit ranges from red to reddish brown. And this terrace deposit is covered with slope deposit of Last Glacial or fossil periglacial structures (platy structure and vecicle) of Last Glacial are formed in terrace deposit. These facts indicate that the lower marine terrace I and II surfaces had been formed before the Last Glacial, and then affected by chemical weathering under warm environment, finally followed by cold period. But the deposit of the lower marine terrace I surface is more weathered than that of II surface. And pseudogleyed red soil, which is developed in I but not in II surface, could be judged to have been formed in the Last Interglacial culmination stage (Oxygen isotope stage 5e). Therefore, in terms of the degree of weathering of the terrace deposit and the existence of pseudogleyed red soil, the age of both terrace is thought to be a little different. And the characteristics of the above mentioned II surface are accord with those of thalassostatic terrace formed in middle or late period of the Last Interglacial (5e or 5a). Thus on the basis of above all points, the lower marine terrace I and II surfaces in this area could be seen to have formed in the Last Interglacial culmination stage and middle or late period of the Last Interglacial, respectively. Because the lower mamine terrace I surface is broadry distributed in the eastern coast of Korea nPeninsula, the surface could be used to be a key surface in studying Quaternary marine terraces.

• Economic and Environmental Geology
• /
• v.35 no.6
• /
• pp.491-508
• /
• 2002

While about 80% of Jeju soils are classified as Andisols, the soils derived from volcanic ash in Dangsanbong are not Andisols. There is a significant difference of precipitation in localities of Jeju island. The study area is characterized by the lowest amount of annual rainfall in Jeju Island, and by the layered silicates as dominant solid phase in clay fraction. The purpose of this study was to characterize the mineralogy of the non-Andie soils in detail, especially hydroxy-interlayered silicates. Two major soil horizons are recognized in the soil profile developed in the Dangsanbong area, which can be designated as A and C. The soil pH($H_{2}0$), ranges from 6.6 to 7.3 increasing with depth, is higher than that of typical Andisols(pH<6.0). While the pH(NaF), ranges from 9.49 to 9.81, indicates that significant amount of amorphous phases might be present as exchanging complexes. It is estimated to about 1.542.88 wt% by using chemical selective dissolution. The organic content of surface horizon is about 2 wt%. This soil are composed of quartz, feldspar and olivine as major constituents with minor of silicate clays. Quartz is frequently observed in A and distinctly decreases in its amount with depth, while olivine is dominant phase in C and rarely observed in A. In the <0.2$\mu\textrm{m}$ size fraction, smectite and kaolinite/smectite interstratification are dominant with minor of illite. The amounts of smectite decrease with depth, while the amounts of kaolinite/smecite interstratification increase with depth, which indicates the trend of mineral transformation with increasing the degree of weathering. The proportion of kaolinite in kaolinite/smectite interstratification is about 85%, and is not changed significantly through the profile. In the 2-0.2$\mu\textrm{m}$size fraction, vermiculite, smectite, illite and kaolinite are major components with minor of chlorite. Most of chlorite are interstratified with smectite. Chlorite which is not interstratified with smectite occurs only in surface horizon. The proportion of the chlorite in the chlorite/smectite interstratification is 59-70(%) and increases with depth. Hydroxy-interlayered vermiculite(HIV) with hydroxy-Fe/AI in their interlayers occurs in both A and C horizon. The amounts of hydroxy-Fe/AI decrease with depth. Hydroxy-interlayered smectite(HIS) of which interlayers might be composed of hydroxy-Mg/Al occurs only in C horizon. As the results of mineralogical investigation for the soil profile in the study area, clay minerals might be changed and evolved through the following weathering sequences: 1) Smectite Kaolinite, HIS, Vermiculite, 2) Vermiculite HIV Chlorite.

• Journal of the Korean GEO-environmental Society
• /
• v.15 no.1
• /
• pp.53-62
• /
• 2014

In Korea, in general, separation distance between existing parallel tunnels was set at two to five times as distant as the diameter of the tunnels according to ground conditions. Recently, however, actual applicability of closely spaced parallel tunnels whose distance between tunnel centers was shorter than the diameter has increased due to environmental damages resulting from massive cutting, restriction in purchase of required land, and maintenance of linear continuity. In particular, when the pillar width of tunnel decreases, the safety of pillars affects behaviors of the tunnel and therefore the need for diverse relevant studies has emerged. However, research so far has been largely confined to analysis of behavior characteristics of pillars, or parameters affecting design, and actually applicable and quantitative data have not been presented. Accordingly, in order to present a stability evaluation method which may maximally reflect construction conditions of spots, this study reflected topographical and stratigraphic characteristics of the portal part with the highest closeness between the tunnels, simulated multi-layer conditions with rock mass and complete weathering, and assessed the degree of effect the stability of pillars had on the entire tunnels through numerical analysis according to changes in pillar width by ground strength. This study also presented composite analysis result on ground surface settlement rates, interference volume rates, and average strength to stress and a formula, which may be applicable to actual work, to evaluate safety rates of closely spaced parallel tunnel pillars and minimum pillar width by ground strength based on failure criteria by Hoek-Brown (1980).

• Economic and Environmental Geology
• /
• v.28 no.3
• /
• pp.251-257
• /
• 1995

Three PEA (Pulverised Fuel Ash) samples, which were fresh, 17 and some 40 years weathered, were collected from two major British power plants. Batch leaching tests with these samples using distilled water and simulated industrial leachate showed higher amounts of element liberation from fresh ash, including Ca, Na, K, S (as $SO^{2-}_4$, $Cr_{total}$, Cu, Li Ni, Mo and CI and this seems to indicate their surface association and easier dissolution when contact with water. On the contrary Mg, Al, Ba, Si, V, As and Se do not show such readily leachable concentrations and these elements might be more associated with glass fraction in PFA particle rather than surface. Although element concentrations in the weathered ash are much lower than those in the initial leachate from the fresh ash, elements are still detected as resonable concentrations, with rather constant levels and this seems to demonstrate the element release from unstable glass phase of PFA particle. Fe, Ca, $Cr_{total}$, Cu, Ni, Zn and Hg were removed from the synthetic leachate by PFA and this is also confirmed by gain in solid PFA. The order of element retention is Meaford weathered ash > Drax weathered ash > Drax fresh ash in decreasing order and this conforms with the degree of weathering. Namely, the more wethered, the more wethered, the more effective in metal retention from the synthetic leachate.

• Journal of Conservation Science
• /
• v.26 no.1
• /
• pp.1-12
• /
• 2010

The crucibles of Baekje Kingdom from the Ssangbukri Site which were used for glass and metal melting had light brown, grayish blue and grayish brown colored bodies. In thin section, the crucibles contained numerous quartz grains and pottery fragments. The surface was covered with fine grained quartz for thermal resistance. Based on decomposition of mica group minerals and formation of mullite detected by X-ray diffraction analysis, it was inferred that all crucibles have been fired over $1,000^{\circ}C$. It was also found that firing temperature has exceeded $1,100^{\circ}C$ in some crucibles because feldspar was not detected. The maximum temperature was assumed at $1,200^{\circ}C$. The magnetic susceptibility values and geochemical characteristics sorted out the crucibles into two groups that differed from the characteristics of the local soils. This reflected geological setting of the site where the alluvium was formed from two kinds of surrounding rock masses, granite gneiss and biotite granite. However, the local soils had similarities with the crucibles in weathering degree and geochemical behavior of major elements. In consequence, it was considered that the raw clay of the crucibles was supplied from the local area of the site.

• Geophysics and Geophysical Exploration
• /
• v.20 no.3
• /
• pp.163-175
• /
• 2017

In land seismic exploration, irregular surface topography and weathering layer in near surface distorts the reflected signals of data. Therefore, typical land seismic data should be compensated for this distortion by static correction. To perform the static correction, near-surface velocity is required, which can be obtained by seismic refraction survey. However, land seismic data is often acquired in a limited form of geometry depending on the equipment availability, accessibility condition, and permission for the survey site. In this situation, refraction analysis should be performed using reflection data because it is impossible to acquire refraction-oriented data due to limited source and receiver geometry. In this study, we aimed to analyze the reliability of the results obtained by refraction traveltime tomography when using reflection data with a limited number of sources and receivers from irregular surface topography. By comparing the inversion result from irregular topography with that from flat surface, we found that the surface topography affects the reliability of the inversion results to some degree. We also found that the number of sources has little effect on the inversion results unless the number of sources are very small. On the other hand, we observed that velocity distortion occurred in the overlapped part of receiver arrays when using a limited number of receivers, and therefore suggested the size of the least overlapping ratio to avoid the velocity distortion. Finally, we performed numerical tests for the model which simulates the surface topography and acquisition geometry of the survey region and verified the reliability analysis of inversion results. We identified reliable areas and suspicious area of the inverted velocity model by applying the analysis results to field data.

• The Journal of Engineering Geology
• /
• v.30 no.2
• /
• pp.161-173
• /
• 2020

This study is to examine the engineering characteristics of colunmar joints in Mudeugsan National Park, a global geopark. For these purposes, physical and mechanical properties of Mudeungsan Tuff, evaluation for the weathering degree of columnar joints, and crack behavior monitoring in columnar joints were conducted. The physical properties of Mudeungsan tuff were 1.02% for the average porosity, 0.38% for the average absorption, 2.69 g/㎤ for the average specific gravity, and 4,948 m/s for the average elastic wave velocity. Its mechanical properties were 337 MPa for the average uniaxial compressive strength, 68 GPa for the average elastic modulus, 0.29 for the average Poisson's ratio, 41.3 MPa for the average cohesion strength, and 62.8° for the average friction angle. the average rebound Q-value of the silver Schmidt hammer for the three columnar joint blocks at the Ipseok-dae was shown as 49.3. when this value is converted into uniaxial compressive strength, it becomes 70.5 MPa, which is about 21% of the uniaxial compression strength of Mudeungsan tuff. In addition, according to the results of crack monitoring measurements for the three columnar joint blocks at the Ipseok-dae, the crack behavior is less than 1 mm, so it is believed that its behavior in Ipseak-dae columnar joints has hardly occured to date.