• Title/Summary/Keyword: water-soluble

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A Study of Emulsion Fuel of Cellulosic Biomass Oil (목본계 바이오매스오일의 에멀젼 연료화 연구)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.836-847
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    • 2016
  • Water soluble oil was obtained by pyrolysis of biomass. The characteristics of emulsified fuel by mixing water soluble oil and MDO(marine diesel oil) and engine emissions were studied with engine dynamometer. Saw dust was used as biomass. Water soluble oil was obtained by condensing of water and carbon content with pyrolysis of saw dust at $500^{\circ}C$. Emulsion fuel was obtained by emulsifying MDO and water soluble oil by the water soluble oil mixing ratio of 10 to 20% of MDO. Exhaust gas detection was performed with engine dynamometer. While combustion, micro-explosion took place in the combustion chamber by water in the emulsion fuel, emulsion fuel scattered to micro particles and it caused to smoke reduction. The heat produced from water vapour reduce the temperature of internal combustion chamber and it caused to inhibition of NOx production. It can be verified by the lower exhaust temperature of each ND-13 mode using emulsion fuel than that of MDO fuel. The NOx and smoke concentration were reduced by increasing water soluble oil content in the emulsion fuel. The power also decreased according to the increment of water soluble oil content of emulsion fuel because emulsion fuel has low calorific value due to high water content than MDO. As a result of ND-13 mode test with 20% bio oil content, it was achieved 25% reduction in NOx production, 60% reduction in smoke density, and 15% reduction in power loss.

Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area (광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사)

  • Park, Seung Shik;Cho, Sung Yong;Kim, Seung Jai
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.20-26
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    • 2010
  • Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

A 4-week Oral Toxicity Study of Water-soluble Chitosan in Sprague-Dawley Rats (수용성 키토산의 SD 랫드에 대한 4 주 반복 경구 투여 독성시험)

  • Jang, Beom-su;Lim, Jong-hwan;Yun, Hyo-in
    • Korean Journal of Veterinary Research
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    • v.43 no.2
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    • pp.195-202
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    • 2003
  • Chitosan is known to have antibacterial, antitumorogenic, hypolipidemic and immunopotentiating activities, hence finding diverse uses as a component in varying functional foodstuffs. However, some investigators reported it caused mineral absoiption inhibition and excess coagulation. From the chemical viewpoint, conventional chitosans are high-molecule polymers lacking water solubility, which could be related with their possible toxicity. A newly developed low- molecule water soluble chitosan is thought to have low toxicity compared to conventional chitosans. But no investigation was carried out to evaluate its toxicity. In this study, a 28-day subacute oral toxicity study of the water-soluble chitosan was performed in Sprague-Dawley rats of both sexes. Each 36 male and female rats were orally administered with 500, 1,000 and 2,000 mg/kg/day for 28 consecutive days, respectively. Clinical parameters (growth rate, feed and water consumption, daily inspection, urine analysis) during the 28 days indicated the water-soluble chitosan did not induce any abnonnal changes. There were no abnormal findings due to the administration of the test substance in gross and microscopic findings. We had not found alteration in absolute and relative organ weight between the control and treated groups, with only exception in the liver but lacking dose-dependency. The results of hematology and serum biochemistry examination revealed that no treatment related changes were between control and all dose groups. In conclusion, it was suggested that subacute toxicity of the water-soluble chitosan was low and the no-observed adverse effect level was considered to be over 2,000 mg/kg in rats.

Change of Physical/Mechanical Property of Human Hair by Treatment using Water Soluble Chitosan (수용성 키토산 처리에 의한 모발의 물리적/역학적 특성 변화)

  • Kim, Kyung-Sun;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.10
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    • pp.1655-1664
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    • 2009
  • Chitosan is an environment-friendly and natural cationic polymer that can be used as a hair cosmetic additive. Healthy hair and damaged hair samples were experimented on according to treatment conditions using a water-soluble chitosan. Chitosan treated hair samples were studied on the physical and mechanical property changes. It is most effective when the water-soluble chitosan treatment was adjusted to the Neutral (pH6.8) or Acid (pH4.5). When the water soluble chitosan was treated at pH4.5, the tensile strength, tensile elongation, and elasticity of decolorized hair all increased. The virgin and damaged hair both changed into elastic and soft hair. The effect of chitosan treatment is more noticeable in the healthy hair than in the damaged hair.

Extraction Characteristics of Soluble Solid from Rumex crispus(Curled Dock) Roots (소리쟁이(Rumex crispus) 뿌리로부터 가용성 고형분의 추출특성)

  • Jeong, Kap-Seop
    • Journal of Environmental Science International
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    • v.20 no.10
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    • pp.1265-1272
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    • 2011
  • In this study, the extraction characteristics of soluble solid from Rumex crispus(Curled dock) was studied from the investigation of the effects of experimental conditions on extraction rate; extraction ratio, composition of extractants, extraction time and pH of extractant, etc. The proximate composition of Rumex crispus was 2.58% crude lipid, 5.59% crude protein, 7.39% crude ash, 6.13% moisture and 78.31% carbohydrate, respectively. Turbidity of extract by distilled water was higher and increased with extraction time and extraction temperature, where as the turbidity didn't increase by ethanol and methanol in 20 folds of extraction ratio. Turbidity was inversely proportional to the extraction ratio for the three extractants at 25$^{\circ}C$ and 1 hour extraction. But turbidity of extract was highest by composition of 50% methanol-water extractant than any other compositions of extractants. Eighteen and fifteen free aminoacids were detected in extracts with distilled water, methanol and ethanol extractant, respectively, and it's contents were order of glutamic acid>proline>aminobutyric acid>alanine. The extraction rate of soluble solid from Rumex crispus was order of distilled water>methanol>ethanol within experimental extraction ratio. In extraction with distilled water, the contents of soluble solid was inversely proportional to the pH of extractant.

Evaluation of Total, Water-soluble and Hexavalent Chromium Contents in Construction Materials(Concretes, Cements)

  • Choi, In-Ja;Yoon, Chung-Sik;Choi, Sang-Jun
    • Journal of Environmental Health Sciences
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    • v.33 no.6
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    • pp.497-501
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    • 2007
  • The objective of the study is to determine the contents of total chromium, water-soluble chromium and hexavalent chromium in cements and concretes specimens taken from manufacturing or construction sites. Chromate is an allergen that is widespread in the environment and is richly contained in cements. Metals were extracted with microwave oven and analyzed by atomic absorption spectrometer. Hexavalent chromium was analysed by ion chromatography. The concentrations of total chromium, water-soluble chromium and hexavalent chromium in cements were $36.02{\sim}108.01,\;15.95{\sim}89.01\;and\;26.77{\sim}89.61\;mg/kg$, respectively. The concentrations of hexavalent chromium in cements were higher than 2 mg/kg, a maximum value recommended in Northern European Countries. The concentrations of total chromium, water-soluble chromium and hexavalent chromium in concretes were $17.44{\sim}76.25,\;0.98{\sim}17.71\;and\;ND{\sim}24.13\;mg/kg$, respectively. Especially Hexavalent chromium was detected only from concrete specimens from construction sites. It is oxidized or reduced status by environmental condition or surrounding materials.

Time Resolved Analysis of Water Soluble Organic Carbon by Aerosol-into-Mist System (분진-미스트 시스템을 이용한 실시간 수용성 유기탄소 분석)

  • Cho, In-Hwan;Park, Da-Jeong;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.6
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    • pp.497-507
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    • 2015
  • Real-time and quantitative measurement of the chemical composition in ambient aerosols represents one of the most challenging problems in the field of atmospheric chemistry. In the present study, time resolved application by Aerosol-into-Mist System (AIMS) following by total organic carbon analyzer (TOC) has been developed. The unique aspect of the combination of these two techniques is to provide quantifiable water soluble organic carbon (WSOC) information of particle-phase organic compounds on timescales of minutes. We also demonstrated that the application of the AIMS method is not limited to water-soluble organic carbon but inorganic ion compounds. By correlating the volume concentrations by optical particle sizer (OPS), water soluble organic carbon can be highly related to the secondary organic products. AIMS-TOC method can be potentially applied to probe the formation and evolution mechanism of a variety of SOA behaviors in ambient air.

Determination of the Solubility of Water-Soluble or Alkali-Soluble Pressure Sensitive Adhesives (수용성 및 알칼리 가용성 점착제의 수용성 및 알칼리 가용성 측정)

  • Choi, Jeong Hye;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.14 no.2
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    • pp.88-94
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    • 2013
  • Because of recent requirement for environmentally-friendly adhesive, water and/or alkali soluble pressure sensitive adhesives are being developed and produced. Our research laboratory newly developed the test method for measuring the water and alkali solubility of the adhesives. Also, we made the test method published both in KS and ISO. In this research, the test of measuring the water and/or alkali solubility of the test adhesive samples as a function of time at various temperatures was carried out using the proposed test method. The results showed this proposed test method made stable output data for the change of solubility as a function of time in the proper range of temperature.

The Effect of Water-Soluble Calcium Supplements on Calcium Metabolism and Bone Metabolism of Growing Rats

  • Jang, Se-Young;Jeong, Yong-Jin;Kwon, Teak-Kyu;Seo, Ji-Hyung;Park, Eun-Mi
    • Preventive Nutrition and Food Science
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    • v.12 no.4
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    • pp.217-221
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    • 2007
  • Within the elderly population, the use of calcium supplements and the intake of calcium from food are on the rise in order to maintain health. Calcium is absorbed as an ion in vivo, leading to speculation that absorption efficiency is affected by the solubility of the calcium consumed. In our study, the bioavailability of two types of calcium supplements with different solubilities was evaluated. Experimental animals were fed water-soluble or insoluble calcium supplements for 6 weeks. We found that blood alkali phosphatase activity, osteocalcin content, and urine crosslinks values were not different between the groups. Similarly, the degree of apparent calcium absorption between the two calcium supplements was not significantly different. The bone mineral density and bone mineral content of the femur and the tibia increased in the group that consumed insoluble calcium compared with those of the water-soluble calcium supplemented group. However, when considering body weight, the bone mineral density value for all areas, including the spine, was significantly higher in the group that consumed the water-soluble calcium supplement.

Studies on Dosage Form Design of Anticancer Drug: Release of 5-Fluorouracil from Silicone Devices Containing Water Soluble Additives (항암제(然癌劑) 제형(劑形) 개발(開發)에 관(關)한 연구(硏究) : Silicone Rubber-수용성(水溶性) 첨가제(添加劑)의 Device에서 5-Fluorouracil의 용출(溶出))

  • Kim, Sung-Ho;Choi, Jun-Shik;Back, Chae-Sun;Yu, Young-Jong;Lee, Chi-Young
    • Journal of Pharmaceutical Investigation
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    • v.16 no.1
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    • pp.1-7
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    • 1986
  • The influences of sodium chloride, polyethylene glycol 4000 and 20000 on 5-fluorouracil release from disk type silicone polymer devices were examined in isotonic phosphate buffer. These water soluble cosolvent and sodium chloride caused devices to swell in aqueous media. Sodium chloride exerted the greatest influence on drug release. The addition of water soluble cosolvent or sodium chloride to silicone polymeric devices permitted controlled release of 5-fluorouracil, presumably due to the change of the physical microstructure of silicone network, and the solubility and diffusivity of 5-fluorouracil. It seemed that the water soluble drug was released through the hydrophilic pores or pathways formed in the device by the incorporation of a water soluble cosolvent or sodium chloride.

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