• Title/Summary/Keyword: water-ethanol

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Separation of Alcohol/water Mixtures with Surface-modified Alumina Membrane in Vapor Permeation (표면개질 알루미나막의 증기투과에 의한 알코올의 분리)

  • 이상인;오한기;이광래
    • Membrane Journal
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    • v.10 no.3
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    • pp.121-129
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    • 2000
  • The membrane requires both high in selectivity and flux. However, the permselective membrane has low flux. In this study, the porous alumina membrane was coated with silane coupling agent in order to enhance the flux with proper selectivity. The contact angle of water to the surface-modified alumina membrane was greater than 90$^{\circ}$, which indicated the high hydrophobicity. The modified membrane was tested in vapor permeation for the concentration of aqueous ethanol, isopropanol, and n-butanol. With the increase of ethanol, isopropanol, butanol concentration in the feed, permeation flux increased due to the greater affinity of ethanol, isopropanol, butanol with surface-modified alumina membrane than that of water. The experimental results showed that the permeation tate of surface-modified alumina membrane was 20~1000 times greater than that of a polymer membranes.

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Effect of Ginseng on the Lipid Oxidation in Pork and Poultry Meat (돼지고기와 닭고기 지방산화에 대한 인삼의 효과)

  • Jeon, Ki-Hong;Lee, Moo-Ha;Kim, Young-Boong
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.7-10
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    • 1992
  • The antioxidant effect of various concentration of Panax ginseng on pork and chicken breast was investigated in the condition of powder, water extract, ethanol extract and residue. Result showed that the antioxidant effect of each sample increased with increasing concentration of powder but the increment decreased with increasing concentration. Water extract and residue decreased lipid oxidation of pork and chicken breast. However, the effect did not increase proportionally with increasing concentration. Ethanol extract did not show a certain tendency in pork while it had an oxidation-promoting effect in chicken.

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Antioxidant activities of flower, berry and leaf of Panax ginseng C. A. Meyer

  • Ryu, Hee-Jeong;Jung, Chul-Jong;Beik, Gyung-Yun
    • Korean Journal of Food Science and Technology
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    • v.52 no.4
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    • pp.342-349
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    • 2020
  • This study was conducted to investigate the applicability of the ground parts such as flower (GF), berry (GR), and leaf (GL) from Panax ginseng C. A. Meyer. The ground parts were extracted from hot water (WE) and 60% ethanol (EE). Total polyphenol and flavonoid contents were 15.02-32.74 and 21.60-484.05 mg GAE/g, respectively. Hot water extract of ginseng leaf (GLWE) and 60% ethanol extract of ginseng leaf (GLEE) showed higher total polyphenol and total flavonoid contents than other extracts. Crude saponin contents were found in the range of 15.30-37.27%. Antioxidant activity of these extracts from ginseng was also analyzed by DPPH, ABTS, H2O2 scavenging activity, reducing power, and inhibition effect on lipid peroxidation. We confirmed the results that hot water extract of ginseng leaf (GLWE), 60% ethanol extract of ginseng leaf (GLEE) has high anti-oxidative effects. According to the antioxidant activity results of each extract of ginseng flower, ginseng berry, and ginseng leaf, it is judged that their availability is very high, and if proper processing is performed, it can be used as a functional raw material.

Preparation of Composite Membranes of Dense PAA-Poly(BMA-co-MMA) IPN Supported on Porous and Crosslinked Poly(BMA-co-MMA) Sublayer and Their Pervaporation Characteristics

  • Kim, Sung-Chul;Lim, Byung-Yun
    • Macromolecular Research
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    • v.11 no.3
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    • pp.163-171
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    • 2003
  • For the pervaporation of water-ethanol mixtures, new composite membranes having poly(acrylic acid)-poly (butyl methacrylate-co-methyl methacrylate) interpenetrati ng polymer network [PAA-P(BMA-co-MMA) IPN] skin layer supported on porous and crosslinked poly(BMA-co-MMA) were prepared. The morphology of the sub-layer of the composite membrane prepared in the presence of 60 wt% solvent showed cellular structure, on the other hand that of sublayer prepared in the presence of 70 wt% solvent presented very porous interconnected pore structure with macrovoids. Permeation rates of the composite membranes were largely influenced by the morphology of the sublayer. Separation factors increased with the increase of the degree of crosslinking of the PAA network. It was found that permeation rates could be increased by introducing anionic charges on carboxyl groups of the PAA. The permeation rate changes of the PAA-P(BMA-co-MMA) IPN composite membranes according to the feed compositions showed quite similar pattern with the swelling behavior in water-ethanol mixtures.

Determination of Water Content in Ethanol by Miniaturized Near-Infrared (NIR) System

  • Cho, Soo-Hwa;Chung, Hoe-Il;Woo, Young-Ah;Kim, Hyo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.115-118
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    • 2005
  • The miniaturized NIR (Near-infrared) spectrometer has been utilized for the determination of water content (1-19% range) in ethanol that is the most popular organic solvent in pharmaceutical industries. It has many potential capabilities that can replace the conventional analyzers especially for the on-line measurement since it is compact, versatile and cost-effective. By using two dimensional (2D) correlation spectroscopy, it was preliminarily investigated to find any unforeseen spectral distortion among the spectra collected from the miniaturized spectrometer. The 2D study revealed that the spectral variation clearly followed the variation of water concentration without any spectral distortion or abnormality. PLS (Partial Least Squares) was employed to build the calibration model and the resulting prediction performance was acceptable and stable over several days. Even though the miniaturized NIR system was evaluated to fairly simple chemical matrix, the overall study demonstrates the sufficient feasibility for diverse practical and industrial applications.

Physiological Activities of Leaf and Twig Extracts from Lindera obtusiloba Blume (생강나무 잎 및 가지 추출물의 생리활성)

  • Hong, Joo-Heon
    • Korean journal of food and cookery science
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    • v.29 no.5
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    • pp.573-580
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    • 2013
  • We investigated the physiological activities of extracts from Lindera obtusiloba Blume leaf and twig (LLW: water extract from Lindera obtusiloba Blume leaf, LLE: 50% ethanol extract from Lindera obtusiloba Blume leaf, LTW: water extract from Lindera obtusiloba Blume twig, LTE: 50% ethanol extract from Lindera obtusiloba Blume twig). Total polyphenol and total flavonoid contents of LTE were 445.38 mg/g and 302.09 mg/g, respectively. The electron donating ability (95.38%) of LTE was higher than that of the LLE (93.76%), LTW (88.09%), and LLW (82.06%). The oxygen radical absorbance capacity of extracts were improved with 50% ethanol condition, rather than hot water. Superoxide radical scavenging activity and FRAP activity of the extracts were improved with an increase of treatment concentration. All the extracts($1,000{\mu}g/mL$) stimulated a production of nitric oxide (NO) in macrophage RAW264.7 cells. In particular, the NO stimulating activity of LTE was superior to that of LLE, LTW, and LLW. The antitumor activity of LTE ($500{\mu}g/mL$) in A549, HeLa and SNU719 was 55.63%, 83.87% and 68.11%, respectively. The UVB-induced MMP-1 production in HS68 cells was suppressed by the treatment of LTE (88.28%), LLE (83.96%), LTW (80.59%) and LLW (76.08%).

Nucleophilic Displacement at Sulfur Center (VIII). Solvolysis of 1-and 2-Naphthalene Sulfonyl Chlorides in Ethanol-Water Mixture (황의 친핵성 치환반응 (제8보). 물-에탄올 혼합용매 속에서 1-및 2-염화나프탈렌 술포닐의 가용매 분해반응)

  • Uhm, Tae Seop;Lee, Ik Choon;Kim, Jae Rok
    • Journal of the Korean Chemical Society
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    • v.20 no.5
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    • pp.358-363
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    • 1976
  • Kinetic studies on solvolytic reactions of 1-and 2-naphthalene sulfonyl chlorides in ethanol-water mixtures have been carried out by means of conductometry at several temperatures. The rate constant for 2-naphthyl compound was larger than that for 1-naphthyl compound. This was contrary to the prediction of MO theory and could be rationalized as due to the peri-hydrogen effect in the transition state for 1-naphthyl compound. Based on m values of Winstein plots and n values of Kivinen pacolots it was concluded that the solvolytic displacement of the two naphthalene sulfonyl chlorides in ethanol-water mixtures proceed via $S_N2$ process.

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The Effect of Lycii fructus beer intake on serum lipid profiles and antioxidant activity in rats (구기자 맥주의 섭취가 흰쥐의 혈청 지질패턴 및 항산화효소 활성에 미치는 영향)

  • Chung, Hae-Kyung;Choi, Chang-Suk;Yang, Eun-Ju;Kang, Myung-Hwa
    • Journal of the Korean Society of Food Culture
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    • v.19 no.1
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    • pp.52-60
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    • 2004
  • This study was performed to investigate the effect of Lycii fructus beer on serum lipid profiles and antioxidant activity in rat Sprague-Dawley (SD) rats weighting about 190g were divided into the following 5 groups ; distillate water (Control), 5% ethanol in distillate water (Ethanol), commercial beer (CB), Lycii fructus beer (LFB) and 5% alcohol red wine diluted with distillate water (RW). Body weight, total food intake, FER and percent organ (liver, kidney) weight per body weight were not significantly changed by Lycii fructus beer drinking. After 6 weeks, serum total cholesterol, triglyceride and HDL cholesterol level were not significantly different. But, Lycii fructus beer intake tended to decrease serum triglyceride level and atherogenic index. Also, GOT and GPT levels were expressed lower than Ethanol group. There was not significantly different in hepatic glutatiione (GSH) content and glutathione-S-transferase (GST) activities among 5 groups. Lipid peroxidation in the hepatic was decreased by Lycii fructus beer intake. The results demonstrated that Lycii fructus beer was potential and effective antioxidant that can protect the decrease associated with alcohol.

Effect of Non-sterilized Makgeolli Consumption on Blood Glucose Level and Survival Rate in Streptozotocin-induced Type I Diabetic Mice (Streptozotocin으로 유도된 제1형 당뇨 생쥐에서 생막걸리 투여가 혈당 및 생존률에 미치는 영향)

  • Lee, Hyun Sook;Kim, Soon Mi
    • Journal of the Korean Society of Food Culture
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    • v.30 no.6
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    • pp.818-824
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    • 2015
  • Makgeolli is a health beneficial food for diabetes compared to other alcoholic beverages. We examined the effect of Makgeolli on blood glucose level and survival rate in a streptozotocin (STZ)-induced diabetic mouse model. We force fed 30 male STZ-induced diabetic ICR mice Makgeolli consisting of 6% alcohol (DM-MAK), 6% ethanol (DM-EtOH), or distilled water (DM-DW) for 4 weeks. In the DM-MAK group, food intake and water intake were higher than those of other groups after 4 weeks. Body weight, however, was not different among the experimental groups. We also found no significant difference in blood glucose level among the experimental groups. In normal ICR mice fed Makgeolli for 1 week, the area of the blood glucose curve was higher than those of other groups fed 6% ethanol, 2% glucose, or distilled water. Survival rates of STZ-induced diabetic mice fed Makgeolli, 6% ethanol, or DW for 4 weeks were 100%, 25%, and 62.5%, respectively. In conclusion, Makgeolli had no beneficial effect on blood glucose in a STZ-induced diabetic mouse model, although their survival rate was high. These results show that Makgeolli has an effect on type 1 diabetes through other mechanisms than blood glucose control.

A Study on the Dyeability of Urtica Dioica L. Extract (쐐기풀(Urtica Dioica L.추출물의 염색성 연구))

  • Kim, Sojin;Kim, Lione
    • Journal of Fashion Business
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    • v.20 no.4
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    • pp.128-140
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    • 2016
  • In this study, dyeability of Urtica Dioica L. extract, which is relatively less studied, was measured. The extract of this plant was used to dye cellulose and protein fiber to check its usage as a natural green dye. Three different methods were used to produce extract. Dried Urtica Dioica L. was extracted with 100% ethanol, 50% ethanol with 50% distilled water and 100% distilled water. Then dyeing solution was obtained by blending with distilled water at 1-to-1 ratio. The maximum dyeability was obtained when 100% ethanol extract of dried Urtica Dioica L. used to dye fabrics at 60 degrees celsius for 60 minutes without mordant treatment. Cotton, rayon, wool and silk were dyed and dyeability for each fiber was measured for color difference value then compared to its control. The results show that dyeability of rayon and dyeability of wool are stronger, and that when color position for each mordant is measured, color difference is most diverse on cotton with pre-mordant treatment. Color fastness to wash, perspiration and rubbing crockmeter were superb, but color fastness to light was low, therefore, additional study on this is needed to improve. Urtica Dioica L. is now expected to be used practically as green color dye as well as medicinally and edible.