• Title/Summary/Keyword: water-dispersed

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Electrorheological Properties of Water Activated Silica Gel Suspensions (수분 활성 실리카 겔 분산계의 전기유변학적 특성)

  • 안병길;최웅수;권오관;문탁진
    • Tribology and Lubricants
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    • v.13 no.3
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    • pp.115-123
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    • 1997
  • The electrorheological (ER) behavior of suspensions in silicone oil of silica gel powder (average particle size 49 $\mu$m) absorbed water was investigated at room temperature with electric fields up to 2.4 KV/mm. In this paper, for development of succcessful ER fluids used for wide temperature range later, we would like to know a fundamental understanding of water on ER effect. As a first step, the ER fluids involving water activated silica gel were measured not only the electrical characteristics such as dielectric constant, current density and electrical conductivity but also the rheological properties on the strength of electric field, the quantity of dispersed phase and absorbed water. From the experimental results that water absorbed to the particles directly affects to the surface charge density of electric double layer model proposed by Schwarz and makes dielectric constant and current density of ER fluids increase. The current density and dynamic yield stress $($\tau$_y)$ of water activated silica gel suspensions was in exponential proportion to the strength of electric field, the quantity of dispersed phase and absorbed water. And the optimum water quantity and weight concentration of silica gel for electrorheological effect were 4-5 wt% and 15 wt%, respectively.

Printing Performance Evaluation of Water-dispersed Pigment Ink according to Additive Conditions of Film Substrate Surface Coating Agent (필름기재 표면 코팅제의 첨가물질 조성 조건에 따른 수분산 안료잉크의 프린팅 성능 평가)

  • Hyeok-Jin Kim;Hye-Ji Seo;Eun-Ha Kang;Min-Woo Han;Dong-Hyeon Lee;Dong-Jun Kwon;Jin-Pyo Hong
    • Textile Coloration and Finishing
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    • v.35 no.4
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    • pp.196-205
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    • 2023
  • Water-dispersed pigment is on-going study for without air pollution in the textile and print industry. Primer treatment is essential for the substrate to improve the printing quality of eco-friendly water-dispersed pigment ink. Otherwise in the case of untreated primer, the water-dispersed pigment ink will dry onto the surface and cause defective images. This study was conducted on film substrate coating (primer) to fix eco-friendly water-dispersed pigment ink on film substrate. The drying, bleeding, and color strength of the pigment ink were examined depending on the composition and mixing ratio of the coating solution. The mixing ratio of silica gel in the coating film is increased to 0, 0.5, 1, 2 and 3 and results that DK-1-3 of silica gel ratio of 1 showed the lowest bleeding such as 52%, the letter thickness of 0.76mm and DK-1-5 of SG ratio of 3 showed the highest bleeding such as 304%, the letter thickness of 2.02mm. The mixing ratio of SPA in the coating film is increased to 2.5, 5, 7.5, SPA ratio of 7.5 has a bleeding ratio of 9% and letter thickness of 0.544mm. It showed the closest value to 0.5mm. According to the result, the optimal mixing ratio of binder, polymer coagulant, silica gel is 100:7.5:1.

Geometry Optimization of Dispersed U-Mo Fuel for Light Water Reactors

  • Ondrej Novak;Pavel Suk;Dusan Kobylka;Martin Sevecek
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3464-3471
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    • 2023
  • The Uranium/Molybdenum metallic fuel has been proposed as promising advanced fuel concept especially in the dispersed fuel geometry. The fuel is manufactured in the form of small fuel droplets (particles) placed in a fuel pin covered by a matrix. In addition to fuel particles, the pin contains voids necessary to compensate material swelling and release of fission gases from the fuel particles. When investigating this advanced fuel design, two important questions were raised. Can the dispersed fuel performance be analyzed using homogenization without significant inaccuracy and what size of fuel drops should be used for the fuel design to achieve optimal utilization? To answer, 2D burnup calculations of fuel assemblies with different fuel particle sizes were performed. The analysis was supported by an additional 3D fuel pin calculation with the dispersed fuel particle size variations. The results show a significant difference in the multiplication factor between the homogenized calculation and the detailed calculation with precise fuel particle geometry. The recommended fuel particle size depends on the final burnup to be achieved. As shown in the results, for lower burnup levels, larger fuel drops offer better multiplication factor. However, when higher burnup levels are required, then smaller fuel drops perform better.

Dispersion Characteristics Water-Based Magnetic Fluids Using Oleic Acid - Preparation and Re-Dispersion Characteristics of Water-Based Magnetic Fluid with Synthesized Magnetite(2) (오레인산에 의한 수상자성유체의 분산특성 - 합성마그네타이트에 의한 수상자성유체의 제고 및 재분산특성에 관한 연구(2))

  • Oh, Jae-Hyun;Kim, Sam-Ill;Kim, Mahn;Lee, Hong-lim
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.298-304
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    • 1994
  • Water-based magnetic fluids were made of the synthesized ultrafine magnetite with surfactants such as sodium oleate and loeic acid. The water-based magnetic fluid was prepared under the condition that added amounts of sodium oleate and oleic acid dissolved with NH4OH were 2.64$\times$10-2 mol, 1.5~2.0$\times$10-2 mol respectively. The water-based magnetic fluid was stable and should be dispersed well dispersion in the range of pH 9.0 to pH 11.0. As the solid content increased from 0.05 g/cc to 0.4 g/cc, the viscosity of water-based magnetic fluids increased from 2.5 cP to 152 cP and their magnetization at 5 KOe linearly increased from 3.1 emu/g to 26 emu/g. The aggregated powder after drying the water-based magnetic fluid was also successfully re-dispersed in dilute NH4OH solution and in kerosene.

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Experimental Studies on Phase Separation of Steam-Water Two Phase Flow in Horizontal Y-Branching Conduit (수평Y자형 분지관에서 증기-물 이상류의 상분리에 관한 실험적 연구)

  • Ahn, Soo-Whan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.6
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    • pp.886-893
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    • 2000
  • The Characteristics of dividing the dispersed bubble, plug, and slug steam-water flow in the horizontal junctions with horizontal branches have been experimentally investigated. The experimental investigation of the separation phenomena in a $45^{\circ}$ horizontal wye with equal pipe inner diameter of 25 mm is presented to provide a data base for the development and verification of the analytical models. The phase separation and pressure distribution in the three legs of each test section are obtained through the set of measurements made in the present work. And the dependence of phase separation on different parameters, such as inlet quality and mass flux, is discussed.

The Effect of DMPA Contents on the Water Dispersability and Mechanical Properties of Urea Resin (DMPA의 함량이 우레아 수지의 수분산 안정성과 기계적 성질에 미치는 영향)

  • Park, Jae Cheol;Kim, Dong Soo;Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1128-1135
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    • 2019
  • In this study, different types of polyether amines and H12MDI were used to synthesize water dispersed urea resins, which can be applied to coating material on the concrete slabs for bicycle road using the ordinary application equipments. The concentrations of several polyether amines with different molecular weights and the number of amine functionality were varied to set up the optimal condition for water dispersed urea resin preparation with both an excellent tensile strength and an elongation. In addition, the effect of DMPA[2,2-Bis(hydroxymethyl)propanoic acid] concentration on the storage stability of the water dispersed urea resin was also investigated. The formation of urea bonds from isocyanate and polyether amines was confirmed through FT-IR ATR spectroscopy. From the mechanical properties of urea resins, PU-4 and PU-6, which were prepared with both diamines and triamine of different molecular weights and number of functionality, showed the tensile strength of 10.5 N/㎟ and 12.7 N/㎟, respectively and the elongation of 1165 % and 969%, respectively. Among the water dispersed urea resin synthesized with different contents of DMPA, PU-6 showed the highest mechanical properties, a tensile strength of 14.2 N/㎟ and an elongation of 993%. In addition, the water dispersion state of this PU-6 was the most stable even after 8 weeks.

Surface-attached Solid Dispersion

  • Park, Young-Joon;Oh, Dong-Hoon;Yan, Yi-Dong;Seo, Yoon-Gee;Lee, Sung-Neug;Choi, Han-Gon;Yong, Chul-Soon
    • Journal of Pharmaceutical Investigation
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    • v.40 no.spc
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    • pp.97-102
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    • 2010
  • A novel surface-attached solid dispersion is designed to improve the solubility and oral bioavailability of poorly water-soluble drugs without crystalline change. Accordingly, it draws increasing interest because of excellent stability and no pollution for accomplishing enhanced solubility and bioavailability, which have recently been highlighted in connection with a number of higher value-added poorly water-soluble drugs. In addition, excellent stability can be attained when the poorly water-soluble drugs are not dissolved but dispersed in water and provide no crystallinity change. This solid dispersion is given by means of attaching the dissolved carriers such as hydrophilic polymer and surfactant to the surface of dispersed drug particles followed by changing the hydrophobic drug to hydrophilic form. The aim of the present review is to outline the preparation, physicochemical property and bioavailability of novel surface-attached solid dispersion with improved solubility and bioavailability of poorly water-soluble drugs without crystalline change.

Silica/polymer Nanocomposite Containing High Silica Nanoparticle Content : Change in Proton Conduction and Water Swelling with Surface Property of Silica Nanoparticles (고농도의 Silica Nanoparticle을 함유한 Silica/polymer 나노복합체 : 실리카 표면 특성에 따른 수소이온 전도성 및 수팽윤도 변화)

  • Kim, Ju-Young;Kim, Seung-Jin;Na, Jae-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.514-521
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    • 2010
  • A new one-shot process was employed to fabricate proton exchange membranes (PEMs) over conventional solvent-casting process. Here, PEMs containing nano-dispersed silica nanoparticles were fabricated using one-shot process similar to the bulk-molding compounds (BMC). Different components such as reactive dispersant, urethane acrylate nonionmer (UAN), styrene, styrene sulfuric acid and silica nano particles were dissolved in a single solvent dimethyl sulfoxide (DMSO) followed by copolymerization within a mold in the presence of radical initiator. We have successfully studied the water-swelling and proton conductivity of obtained nanocomposite membranes which are strongly depended on the surface property of dispersed silica nano particles. In case of dispersion of hydrophilic silica nanoparticles, the nanocomposite membranes exhibited an increase in water-swelling and a decrease in methanol permeability with almost unchanged proton conductivity compared to neat polymeric membrane. The reverse observations were achieved for hydrophobic silica nanoparticles. Hence, hydrophilic and hydrophobic silica nanoparticles were effectively dispersed in hydrophilic and hydrophobic medium respectively. Hydrophobic silica nanoparticles dispersed in hydrophobic domains of PEMs largely suppressed swelling of hydrophilic domains by absorbing water without interrupting proton conduction occurred in hydrophilic membrane. Consequently, proton conductivity and water-swelling could be freely controlled by simply dispersing silica nanopartilces within the membrane.

Production and Properties of Ag Metallic Nanoparticle Fluid by Electrical Explosion of Wire in Liquid (유체 내 전기선폭발법에 의한 은 나노입자 유체의 제조 및 특성)

  • Park, E.J.;Bac, L.H.;Kim, J.S.;Kwon, Y.S.;Kim, J.C.;Choi, H.S.;Chung, Y.H.
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.217-222
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    • 2009
  • This paper presents a novel single-step method to prepare the Ag nanometallic particle dispersed fluid (nanofluid) by electrical explosion of wire in liquid, deionized water (DI water). X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM) were used to investigate the characteristics of the Ag nanofluids. Zeta potential was also used to measure the dispersion properties of the as-prepared Ag nanofluid. Pure Ag phase was detected in the nanofluids using water. FE-SEM analysis shows that the size of the particles formed in DI water was about 88 nm and Zeta potential value was about -43.68 without any physical and chemical treatments. Thermal conductivity of the as-prepared Ag particle dispersed nanofluid shows much higher value than that of pure DI water.