• Journal of the Korean Wood Science and Technology
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• v.52 no.4
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• pp.301-318
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• 2024

Contrary to other materials like metals, glass, etc., wood continuously interacts with the environment, increasing and decreasing its moisture content according to the humidity of the air and changing its dimensions by swelling or shrinking. Water diffusion through laminated solid wood is crucial in wood bonding processes. The adhesive layer might block the diffusion if the water vapor diffusion is perpendicular to the bond line. As a result of this blockage, different proportions of deformation appear on the two sides of the bond line, which causes stresses in the bonded assembly. The question arises of how long the bonded structure will keep its integrity due to moisture diffusion blockage, inevitable tensions appearing in the glue line, and how these stresses could be avoided. With cross laminated timber (CLT) solid wood panel production, this question gains new importance. Despite the relevance, only a limited number of publications are available. Comprehensive research would also be necessary considering both the molecular structure and diffusion properties of the adhesive adjusted to the wood species (covering possible substituting wood species, too). Overall, this review serves as a resource for enhancing our understanding of water vapor diffusion through wood adhesive layers and provides insights that have implications for reducing stresses in bonded wood assemblies and the performance of the bonded group over time. Furthermore, identifying knowledge gaps is necessary to establish the basis for investigating the diffusion property of CLT panels.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.46-56
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• 1998

The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.1
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• pp.59-70
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• 1998

A steady-state molecular diffusion experiment was conducted to evaluate the water vapor proof properties of paper Handsheets prepared from unbleached Itraft pulps(UKP) and old newspapers(ONP) and four different types of polymer-laminated white duplex board were tested under appropriate standard conditions. The diffusivity was determined on the basis of the Fickean first law. Results obtained from this study can be summarized as follows ; 1. The diffusivity data for handsheets showed about $10^{-5}cm^2/min$. whereas polymer-laminated paperboards had remarkably improved water-vapor resistance with about $10^3 to 10^4$ times lower diffusivity : 2. Sheet basis weight, wet-swelling and sizing degree had little influence on the diffusivity of paper; 3 Linear relationship existed between sheet density and diffusivity, and, 4. Highly sfgnificant linear relationship could be observed between diffusivity and Darcy s gas permeability. Results indicate that diffusivity, an intrinsic property of paper, can provide a valuable information for precise evaluation and improved quality control of water-vapor proof properties of paper.

• Journal of the Korean Wood Science and Technology
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• v.20 no.4
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• pp.21-30
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• 1992

An activation energy equation for moisture diffusion in wood was developed with an assumption that activation energy is directly proportional to wood specific gravity. Theoretical activation energies obtained from the activation energy equation were revealed to be always lower than actual activation energies, which implies that activation energy isn't affected only by wood specific gravity. The other affecting factors are possibly anatomical structures of wood which determine a ratio of vapor diffusion to bound water diffusion in wood. For the convenience of estimating actual activation energy by using the activation energy equation, thirteen kinds of species were categorized into three groups according to their anatomical structures.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.4
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• pp.374-380
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• 2015

In this paper, a dynamic model describing the 2 phase effect on the gas diffusion layer depending on load change of a fuel cell stack was developed to examine the effects of liquid water in fuel cell cathode gas diffusion layer on the fuel cell performance. For the developed model, 2 phase effect on the performance of a fuel cell stack depending on the load changes, concentration distribution of water vapor and oxygen inside a gas diffusion layer, the effect of the thickness and porosity of the gas diffusion layer on the fuel cell stack voltage were examined. As a result, a fuel cell stack voltage for the 2 phase model within the scope of the research become lower than that for the 1 phase model regardless of the load. Although oxygen molar concentration for the gas diffusion layer adjacent to the catalyst layer was the lowest, water vapor concentration is the highest. In addition, as thickness and porosity of the gas diffusion layer increased and decreased, respectively, the fuel cell stack voltage decreased.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.2
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• pp.171-181
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• 2007

Blending effects of hydrogen and water vapor on flame structure and NOx emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane and pure hydrogen to the blending fuels of methane-hydrogen-water vapor through the molar addition of $H_2O$. Flame structure is changed considerably for hydrogen-blending methane flames and hydrogen-blending methane flames diluted with water vapor in comparison to pure methane flame. These complicated changes of flame structures also affect NOx emission behavior considerably. The changes of thermal NO and Fenimore NO are analyzed for various combinations of the fuel composition. Importantly contributing reaction steps to thermal NO and Fenimore NO are addressed in pure methane, hydrogen-blending methane flames, and hydrogen-blending methane flames diluted with water vapor.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.418-418
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• 2009

Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.4
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• pp.456-465
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• 1998

Effect of a non-absorbable gas on the absorption process in a vertical tube absorber was investigated numerically. The water vapor mined with air as the non-absorbable gas is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. It was shown that the local absorption rate decreases as the mass fraction of air in water vapor increases. The vapor pressure of water at the liquid-vapor interface reduces significantly since the non-absorbable gas is accumulated near the interface. The effect of non-absorbable gases on absorption rate becomes larger as the mass flow rate of the vapor decreases. For small amount of non-absorbable gases the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. Total absorption rate increases as the mass flow rate of the vapor increases for large concentration of non-absorbables at the inlet of an absorber.

• International Journal of Air-Conditioning and Refrigeration
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• v.7
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• pp.69-78
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• 1999

Effects of a non-absorbable gas on the absorption process in a vertical tube absorber has been investigated numerically. The water vapor mixed with air is absorbed into LiBr/water solution film. The flow is assumed to be laminar and fully developed in both liquid and gas phases. The diffusion and energy equations were solved in both phases to give the temperature and concentrations, from which heat and mass fluxes were determined. The local absorption rate has been shown to decrease as the mass fraction of air in the water vapor increases. The vapor pressure of water at the liquid-vapor is interface reduced significantly since the non-absorbable gas accumulates near the interface. The effects of non-absorbable gases on absorption rate become larger as the mass flow rate of the vapor decreases. For a small amount of non-absorbable gases, the total absorption rate of water vapor increases as the mass flow rate of the vapor decreases. The total absorption rate increases as the mass flow rate of the vapor increases for large concentrations of non-absorbable gases at the inlet of an absorber.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.3
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• pp.414-421
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• 1999

Falling film rectification involves simultaneous heat and mass transfer between vapor and liquid interface. In the present work, the adiabatic rectification process of ammonia-water vapor on the vertical plate was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the mass transfer rate. The effects of Reynolds number and ammonia concentration of solution and vapor mixture, rectifier length, and the enhancement of mass transfer in each phases were investigated. The stripping of water in vapor mixture occurred new the entrance of ammonia solution, which imposed the proper size of an adiabatic rectifier. Rectifier efficiency increased as film Reynolds number increased and as vapor mixture Reynolds number decreased. The improvement of rectifier efficiency was significant with the enhancement of mass transfer in falling film.