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Decomposition of PVC and Ion Exchange Resin in Supercritical Water

  • Kim Jung-Sung;Lee Sang-Hwan;Park Yoon-Yul;Yasuyo Hoshikawa;Hiroshi Tomiyasu
    • Journal of Environmental Science International
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    • v.14 no.10
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    • pp.919-928
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    • 2005
  • This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.

Effects of Spray Characteristics of Water Mist on The Extinction of a Liquid Pool Fire (분무수 분무특성이 액체연료 Pool 화염의 소화에 미치는 영향)

  • Kim, Ho-Young;Oh, Sang-Youp;Chung, Jin-Taek
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1591-1599
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    • 2004
  • A series of experiments were conducted to study the effectiveness of the extinction of a liquid pool fire with two different water atomizing nozzles. Fire source is a small-scale circular stainless steel pan of 120mm in diameter with the fuels of hexane and ethanol. K-type thermocouples were used to measure the flame and fuel temperature along the pool centerline and under fuel surface. A digital camera was used to visualize the process of the fire suppression. The experimental results show that water mist droplet size is l15∼180${\mu}{\textrm}{m}$ with nozzle A and 130∼190${\mu}{\textrm}{m}$ with nozzle B. The extinguishing time of pool fire was reduced with the increase of pressure. When water droplets are small, they do not reach the flame base since they may be deflected or evaporated by the fire plume. However, influence of flow rate is more important than droplet size on fire extinction. Among the fire extinction mechanisms, drop of flame temperature is superior to suffocation of $O_2$ concentration.

The Effects of Spray Characteristics of Water Mist on the Fire Suppression of Liquid Pool Fire (미분무수 분무특성이 액체연료 Pool 화염의 소화에 미치는 영향)

  • Oh, Sang-Youp;Kim, Ho-Young;Chung, Jin-Taek
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.215-221
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    • 2003
  • A series of experiments were conducted to study the effectiveness of the extinction of a liquid pool fire with two different water atomizing nozzles. Fire source is small-scale circular stainless steel pan of 120mm in diameter with the fuels of hexane and ethanol. K-type thermocouples were used to measure the flame and fuel temperature along the pool centerline and under fuel surface. A digital camera was used to visualize the process of the fire suppression. The experimental results show that water mist droplet size is $115{\sim}180{\mu}m$ with nozzle A and $130{\sim}190{\mu}m$ with nozzle B. The extinguishing time of pool fire was reduced with the increase of pressure. When water droplets are small, they do not reach the flame base since they may be deflected or evaporated by the fire plume. However, influence of flow rate is more important than droplet size on fire extinction. Among the fire extinction mechanisms, drop of flame temperature is superior to suffocation of O2 concentration.

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Performance Characteristics of a CO2 Cooling and Water Heating System with a Twin-rotary Compressor (트윈로터리 압축기 적용 냉방 및 급탕 겸용 이산화탄소 시스템의 성능특성에 관한 연구)

  • Cho, Hong-Hyun;Lee, Ho-Sung;Baek, Chang-Hyun;Kim, Yong-Chan;Cho, Sung-Wook
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.4
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    • pp.230-237
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    • 2008
  • The objective of this paper is to investigate the performance characteristics of a $CO_2$ cooling and water heating system using a twin-rotary compressor with the compression volume ratio of 0.6. The cooling performances of the $CO_2$ heat pump were measured and analyzed with the variations of charge amount, EEV opening, and compressor frequency. In addition, the performance of the combined system including cooling and water heating was also measured and analyzed by varying inlet temperature of the EEV. As a result, the optimal normalized charge and cooling COP in the cooling mode were 0.307 and 2.06, respectively. The application of the water heating into the $CO_2$ heat pump improved the cooling performance over 78% and decreased the EEV inlet temperature by $8^{\circ}C$, which can increase system reliability.

Superheated Water-Cooled Small Modular Underwater Reactor Concept

  • Shirvan, Koroush;Kazimi, Mujid
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1338-1348
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    • 2016
  • A novel fully passive small modular superheated water reactor (SWR) for underwater deployment is designed to produce 160 MWe with steam at $500^{\circ}C$ to increase the thermodynamic efficiency compared with standard light water reactors. The SWR design is based on a conceptual 400-MWe integral SWR using the internally and externally cooled annular fuel (IXAF). The coolant boils in the external channels throughout the core to approximately the same quality as a conventional boiling water reactor and then the steam, instead of exiting the reactor pressure vessel, turns around and flows downward in the central channel of some IXAF fuel rods within each assembly and then flows upward through the rest of the IXAF pins in the assembly and exits the reactor pressure vessel as superheated steam. In this study, new cladding material to withstand high temperature steam in addition to the fuel mechanical and safety behavior is investigated. The steam temperature was found to depend on the thermal and mechanical characteristics of the fuel. The SWR showed a very different transient behavior compared with a boiling water reactor. The inter-play between the inner and outer channels of the IXAF was mainly beneficial except in the case of sudden reactivity insertion transients where additional control consideration is required.

Application for Heating and Cooling System Using Sewage Water (100RT급 하수열원 냉난방시스템 적용)

  • Chang, Ki-Chang;Yoon, Hyung-Kee;Park, Seong-Ryong;Baik, Young-Jin;Ra, Ho-Sang;Shin, Kwang-Ho
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.215-220
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    • 2006
  • Along with socioeconomic development and improving standard of living, the heat demand for heating and cooling in residential and commercial sectors is expected to expand rapidly, reaching over 43 million TOE by 2010 in Korea(about 80% increase compared with that in 1995). Since most of this heat demand is loop temperature below $60^{\circ}C$, the utilization of 'unused energy' is surely one of very effective measures to both environmental preservation and energy conservation. 'Unused energy' in this paper is implicated as 'temperature differential energy' available from treated sewage water, useful and abundant heat source for heat pump(cooler in summer and warmer in winter than outside air). An analysis was carried out to estimate the energy potential of treated sewage water for heat pump heat source. Some analysis were taken to study the characteristics of a heat pump system using the treated sewage water as heat source.

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The water vapor pressure property of 150MPa level ultra high strength concrete reinforced with polypropylene fiber and amorphous steel fiber at high temperature (고온에서 폴리프로필렌섬유와 비정질강섬유를 보강한 150MPa급 초고강도 콘크리트의 수증기 압력특성)

  • Suh, Dong-Kyun;Kim, Gyu-Yong;Lee, Sang-Kyu;Hwang, Eui-Chul;Eu, Ha-Min;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.132-133
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    • 2020
  • The aim of this study is to evaluate the combination effect of amorphous steel fiber and polypropylene fiber on spalling of the 150MPa level ultra high strength concrete. Considering spalling has a great relationship with water vapor pressure, this paper is focusing on water vapor pressure. The test specimens were heated accordance with ISO-834 Standard Curve using electric heating furnace, the depth of 10mm water vapor pressure formation was tend to get faster and spalling damage become severe when the mixing proportion of amorphous steel fiber increase. When using ultra high strength concrete reinforced with amorphous steel fiber, further research about proper mixing proportion of polypropylene fiber.

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Climate Change Impacts on Paddy Water Requirement (기후변화가 논 필요수량에 미치는 영향)

  • Yun, Dong-Koun;Chung, Sang-Ok;Kim, Seong-Joon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.4
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    • pp.39-47
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    • 2011
  • The aim of the study is to predict potential evapotranspiration and crop water requirement using meteorological data from MIROC3.2 with A1B scenario. Increase of evapotranspiration due to temperature rise can be observed out of the analysis, while effective rainfall decreased. The evapotranspiration elevation results in large amount of crop water requirement in the paddy farming. It can be seen that rainfall intensification at non-irrigation period brings effective rainfall decrease, while contributes to higher demand of crop water at irrigation period. It is necessary to secure additional water resources to adapt the climate change. It is expected that estimation on potentialevapotranspiration in this study can be used for formulation of master plan of water resources.

Combustion Characteristics of Gasoline Direct Injection Engine with Water Injection into Intake Port under Low Engine-Load Operating Condition (낮은 엔진 부하의 운전조건에서 흡기포트 내 물 분사에 따른 가솔린 직접분사 엔진의 연소 특성)

  • Jeun, Haegwang;Lee, Kyung-Hwan;Choi, Myungsik;Park, Suhan
    • Journal of ILASS-Korea
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    • v.23 no.2
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    • pp.96-101
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    • 2018
  • The purpose of this study is to investigate the effect of water injection on combustion characteristics of gasoline direct injection (GDI) engine with turbo-charger under low-load operating condition. The test engine used in this study has four-cylinder and 10.2 of compression ratio. In order to study the effect of water injection ratio on combustion characteristics, the water was injected into the intake port from 10% to 50%, based on fuel injection quantity. From the experiment, it revealed that the water injection induced the improvement of fuel economy because of the advance of spark-timing by the reduction of in-cylinder temperature. In addition, the water injection caused the prolong of extension of the ignition delay and slight increase of burn duration.

A Study on the High Temperature Properties (Compressive Strength, Expansion) of Synthetic Sand using Domestic Silica Sand (Mooryang Silica Sand) (국내규사(國內硅砂)를 사용(使用)한 합성사(合成砂)의 고온성질(高溫性質) (압축강도(壓縮强度), 팽장(膨張)) 에 관(關)한 연구(硏究))

  • Yun, Byung-Guk;Lee, Kye-Wan
    • Journal of Korea Foundry Society
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    • v.2 no.4
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    • pp.2-8
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    • 1982
  • The behavior of sand and mold at high temperatures was generally agreed to importantly affect the quality of castings made. By changing water content through 2,4,6 and 8%, and bentonite content through 5,7,9 and 11%, specimens have been made according to the respective composition. Specimens have been subjected to hot compressive strength and thermal expansion at 400, 600, 800 and $1000^{\circ}C$ respectively. The results obtained were as follows ; 1. At each temperature, thermal expansion decreased and hot compressive strength increased with the increase in water content. 2. After thermal expansion was peaked at approximately $1000^{\circ}C$ the contraction and maximum hot compressive strength appeared. 3. At each temperature, maximum hot compressive strength appeared 2%, 4,6% and 8% water content for 7%, 9% and 11% bentonite content respectively. 4. When 2% $H_2O$ was added, though bentonite content was increased, hot compressive strength did not rarely change. 5. Until the thermal expansion was completed the required time was 15-18 minutes at $400^{\circ}C$ and $600^{\circ}C$, and 10-13 minutes at $800^{\circ}C$. At $1000^{\circ}C$, the required time was 7-9 minutes in order to gain the maximum expansion, after that, contraction proceeded during 3-4 minutes before expansion was completed.

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