• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1181-1181
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• 2001

Robinson with ${coworkers}^{1}$ have introduced two-state outer-neighbor bonding model to explain the anomalies of water. The studies on the properties of water as a function of temperature and pressure revealed that, unlike other ideas, all $H_2O$ molecules in liquid are tetrabonded. On the average they are forming two different bonding types. One type is the regular tetrahedral water-water bonding similar to that found in the ordinary ice Ih, whereas the other is a more dense nonregular tetrahedral bonding similar to that appearing in the ice II. The transformation between these two bonding forms is evidenced by FT-NIR experiment. The FT-NIR measurements were done for liquid water in the temperature range from $20^{\circ}C$ up to $80^{\circ}C$ in a wide extent of frequencies: 12 000 - 4000 $cm^{-1}$ /. Temperature dependent variations in the volume fraction of these two structures are directly related to the spectral changes. The absorbance variations are explored by means of the two-dimensional correlation spectroscopy (2DCOS), principal component analysis (PCA), curve fitting and second derivatives. The presence of the isosbestic points in a range of the combination and overtone transitions indicates that the experimental spectra are a superposition of two temperature independent components. One component of diminishing intensity with temperature increase, is assigned to a stronger hydrogen bonds occurred in the Ih type, whereas the second component showing an opposite behavior, one can attribute to a weaker H-bonds characteristic for the II type. The understanding of the hydrogen bonding network in the liquid water is very important in interpretation of the interaction between water and protein chain. The two-state model of water surrounding the protein surface could advance an understanding of the hydration process.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1286-1286
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• 2001

Despite extensive theoretical and experimental studies the structure of the protein-solvent interface is subject of many controversy. Understanding the processes that occur in aqueous solution requires understanding of the solvent influence on the structure of protein. The aim of this study is to investigate the applicability of NIR methods in the study of hydration phenomena in protein solutions. Temperature-induced changes in NIR spectra of -lactoglobulin (BLG) in aqueous solutions have been investigated by means of two-dimensional correlation spectroscopy (2DCOS) and principal component analysis (PCA). With the temperature increase the balance of forces between the BLG's interaction with itself and the BLGs interaction with its environment is disrupted leading to BLG unfolding. Significant differences of 2D signals and distinct discrepancies of loading on PC1 and PC2 were observed as a result of temperature increase. In the native folded conformation of BLC, most of the nonpolar amino acids are hidden in the centre of the structure, out of contact with water molecules, while charged groups are outside, in the contact with water. The polar groups promote low density Ih-type structure in the water outside this first hydration shell. When BLG unfolds it assumes a more extended configuration on which the previously buried nonpolar groups are exposed to water and promote the higher density II-type structure outside its first shell. Detailed assignments of bands attributed to the bulk water, different states of the hydrated water and the changed conformation of BLG are proposed.

• Explosives and Blasting
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• v.29 no.1
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• pp.34-40
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• 2011

In this study, effects that thermal stress and water pressure have on the deformation behaviour of granite specimens recovered in Gagok Mine are estimated. To analyze effects of the thermal stress and water pressure on the deformation behaviour, granite specimens were preheated with cycles of predetermined temperatures ranging $200^{\circ}C$ to $700^{\circ}C$ and 500, 600, $700^{\circ}C$ specimens were pressurized to 7.5 MPa. The deformation behaviour of the specimens had been studied by performing uniaxial compressive tests. Axial and lateral strains of specimens were found to increase with increasing temperature, and above $600^{\circ}C$, the increase of strains were more pronounced. The reduction trends of uniaxial compressive strength and Young's modulus with temperature appeared to follow an exponential decay function. Specimens under water pressure showed the more inelastic deformation characteristics, which means that water pressure has an effect on the widening and extending of micro-cracks existed in preheated specimens.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.46 no.2
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• pp.201-215
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• 2013

The characteristics of the oceanographic environment in the Aleutian Basin of the Bering Sea during spring in 1996, 1997, and 1999 were clarified. An investigation of the water properties revealed five basic layers in the Bering Sea during spring: (1) a surface layer of warm and low-salinity water induced by solar heating, (2) a subsurface layer of cold and low-salinity water propagated slowly by heat from the surface layer, (3) a thermocline layer where salinity was constant but temperature sharply decreased, (4) a temperature inversion layer, and (5) a deep layer with a gradual decrease in temperature and increase in salinity toward the bottom. The ranges of water temperature and salinity were $1.8-5.5^{\circ}C$ and 31.81-34.08 in 1996, $1.5-7.2^{\circ}C$ and 31.9-34.06 in 1997, and $0.5-5.6^{\circ}C$ and 32.0-34.11 in 1999, respectively. The water temperature of the surface layer was approximately $1.6^{\circ}C$ higher in 1997 than in 1996 and 1999. The lowest temperature at a depth of 100-150 m was about $1^{\circ}C$ lower in 1999 than in 1996 and 1997. Nutrient levels (nitrate, phosphate, and silicate) contributing to the control of the growth of phytoplankton were higher in the Aleutian Basin than in the eastern continental shelf and Bogoslof Island area. This was closely associated with the phytoplankton distribution. Nutrient concentrations were lowest at a depth of 25 m. The high primary production at that depth was confirmed from the vertical distribution of chlorophyll a. Chlorophyll a levels were above $4.0{\mu}L^{-1}$ in some areas in 1996 and 1999, but below $2.0{\mu}L^{-1}$ in most areas in 1997. Zooplankton density was about three times higher in 1999 than in 1997.

• Textile Coloration and Finishing
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• v.25 no.3
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• pp.206-214
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• 2013

There has been an increasing demand for high performance and energy-saving of blind. In order to develop the eco-friendly blind textiles, heat treatment process has been utilized for LM(Low Melting) polyester fabrics and the changes of the physical properties of the treated fabrics were examined according to temperature of heat treatment. Morphology, surface reflectance, contact angle, luster, thermal property and mechanical property of heat treated LM polyester fabrics were investigated. As results, morphology analysis of thermal treated fabrics confirmed that degree of fusion of LM polyester yarns improved with increase of temperature. Surface reflectance of thermal treated fabrics decreased with increase of temperature. Luster and contact angle of a water droplet on thermal treated fabrics increased slightly with increase of temperature. The mechanical properties of the fabrics by KES-FB system were found to be temperature-dependent and especially, bending and shear properties among them were highly related to temperature.

• Journal of Biosystems Engineering
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• v.8 no.1
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• pp.38-46
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• 1983

This study was carried out to investigate the possibility of improving the performance of a kerosene engine with water addition. The engine used in this study was a single-cylinder, four-cycle kerosene engine with the compression ratio of 4.5. Water could be successfully added into the inlet manifold by an extra carburetor for the volumetric ratios of 5, 10, 20, and 30 percents. Variable speed tests at wide-open throttle were performed for five speed levels in the range of 1,000 to 2,200rpm for each fuel type. Volumetric efficiency and brake specific fuel consumption were determined, and brake thermal efficiency based on the lower heats of combustion of kerosene was calculated. To examine variation in fuel consumption, CO concentration, and cooling water temperature, part load tests were also performed. The results obtained are summarized as follow. (1) Brake torque increased almost in proportion to volumetric efficiency. But the ratio of increase in torque was greater than that of volumetric efficiency. Mean torque over the speed range of 1,000 to 2,200rpm increased 1, 3, 7, and 2 percents for 5, 10, 20, and 30 percents water addition, respectively. The increase in brake torque with water addition was greater at lower speeds. (2) Mean brake specific fuel consumption over the speed range of 1,000 to 2,200rpm decreased 1, 2, 3, and 3 percents for 5, 10, 20, and 30 percents water addition, respectively. (3) Mean temperature of cooling water over the speed range of 1,000 to 2,200rpm decreased 2, 4, 8, and 12 percents for 5, 10, 20, and 30 percents water addition, respectively. (4) The effects of decreasing CO concentration in the exhaust emissions with water addition were significant. At the speed range of 1,000 to 2,200rpm, CO concentration in the exhaust emissions decreased 2, 10, 23, percents for 5, 10, and 20 percents water addition, respectively. (5) Deposits were not discovered in the combustion chamber during the experiment. However, a little rust was formed in the water-supply carburetor.

• Journal of Ginseng Research
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• v.10 no.1
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• pp.80-93
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• 1986

The tail portion of dried 6-year old white ginseng was extracted and sugars and nitrogen compounds were also evaluated for chemical properties depending on varying conditions of extractions. The factors studied were extraction temperature in the range of 70-$100^{\circ}C$, ethanol concentration of 0-90% and the times of extractions which was taken 8 hours per each extraction in water at $80^{\circ}C$. For the effect of ethanol concentration in the extraction solvent, it was found that the amounts of free, reducing and total sugars and starch recovered in extract were almost linearly decreased along with the increase of concentration and the nonprotein nitrogen accounted over 84% of total nitrogen in extract. As ethanol concentration became increased, extractions of total nitrogen and water souluble nonprotein nitrogen were decreased especially in 90% ethanol. For the extraction temperature, all the sugar fractions with water and 70% ethanol except free sugar have tended to increase along with the temperature raised from 70 to $100^{\circ}C$ and it was found there is little changes of nitrogen compounds in the temperature range except a rapidly increase in water soulble protein at $100^{\circ}C$. For the times of extractions, showed that most of extractable compounds were extracted in 3 times of extractions with water at $80^{\circ}C$. It was shown that more than 95f) of sugars and 80% of nitrogen compounds were yielded with water extraction. Accordingly it was efficient to extract with water or 70% ethanol in 3 times in terms of !actor and energy consumption.

• Journal of the Korean Solar Energy Society
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• v.26 no.3
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• pp.71-78
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• 2006

Thermodynamic irreversibility analysis of an air-to-water heat pump system is analyzed in this study. This analysis shows the distribution of irreversibilities(true losses in thermodynamic sense) through the system components and informs us of a potential improvements with the irreversibility factor decreases. The results show that the largest irreversibilities occur in the motor-compressor unit. The remaining irreversibilities are distributed relatively uniformly through the other parts including utilization system. The increase of performance can be attained through either the improvement of adiabatic efficiency of motor-compressor unit(${\eta}_{mc}$) or the reduction of temperature difference(${\Delta}T$). With the decrease of utilization temperature($T_u$) COPH also increases but the exergetic efficiency decreases. The increase of COPH of about 0.05 can be accomplished with 1K decrease of ${\Delta}T$ or $T_u$.

• Environmental Engineering Research
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• v.20 no.3
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• pp.290-297
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• 2015

This paper presents the evaluation of the impact of climate change on water resources and yield capacity of Asa and Kampe reservoirs. Trend analysis of mean temperature, runoff, rainfall and evapotranspiration was carried out using Mann Kendall and Sen's slope, while runoff was modeled as a function of temperature, rainfall and evapotranspiration using Artificial Neural Networks (ANN). Rainfall and runoff exhibited positive trends at the two dam sites and their upstream while forecasted ten-year runoff displayed increasing positive trend which indicates high reservoir inflow. The reservoir yield capacity estimated with the ANN forecasted runoff was higher by about 38% and 17% compared to that obtained with historical runoff at Asa and Kampe respectively. This is an indication that there is tendency for water resources of the reservoir to increase and thus more water will be available for water supply and irrigation to ensure food security.

• Journal of The Korean Association For Science Education
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• v.10 no.1
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• pp.95-118
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• 1990

This students ideas in science are diverse and unique It is realized that children's preconceptions and misconceptions established before lessoning hgve a crucial in fluence on the following education. so it is meaningful to analyse the children's concept of temperature for the better teaching strategy in this study. This survey of the Elementary school children's concept is designed for the subtopics of temperature as the relation between heat and temperature, He relation between volume(size) and temperature, the temperature of change of state on water, the temperature of substances in the condition of thermal equilibrium. Using Clinical method, this research was executed to 306 children at elementary school. The network method or the analyse of questionnaires were used to analyse the children's response. Findings of this survey are as follow. Students are already familiar with such concept as this increase of temperature by geating, but they think every substance is not the case. Many students appears to believe that the temperature of an object(substance) is related to its size(vloume) Qualitative tasks are difficult than qualitative ones. This trend appear highly in the low grade students. Don't know the temperature of change of state on water and it's stability They think that the temperature is determined by the heating time(period) and the temperature of heating source. Students think, in general that temperature of substance in the condition of thermal equilibrium is different.