• Membrane and Water Treatment
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• 제2권1호
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• pp.1-24
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• 2011

The deficiency of clean water is a major global concern because all the living creatures rely on the drinkable water for survival. On top of this, abundant of clean water supply is also necessary for household, metropolitan inhabitants, industry, and agriculture. Among many purification processes, advances in low-energy membrane separation technology appear to be the most effective solution for water crisis because membranes have been widely recognized as one of the most direct and feasible approaches for clean water production. The aim of this article is to give an overview of (1) two new emerging membrane technologies for water reuse and desalination by forward osmosis (FO) and membrane distillation (MD), and (2) the molecular engineering and development of highly permeable hollow fiber membranes, with polyvinylidene fluoride (PVDF) and polybenzimidazole (PBI) as the main focuses for the aforementioned applications in National University of Singapore (NUS). This article presents the main results of membrane module design, separation performance, membrane characteristics, chemical modification and spinning conditions to produce novel hollow fiber membranes for FO and MD applications. As two potential solutions, MD and FO may be synergistically combined to form a hybrid system as a sustainable alternative technology for fresh water production.

• Membrane and Water Treatment
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• 제5권2호
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• pp.87-108
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• 2014

Electrodeionization (EDI), which combines electrodialysis (ED) and conventional ion-exchange (IX), is a mature process which has been applied since more than twenty years on commercial use for the production of ultrapure water (UPW). Eliminating chemical regeneration is the main reason for its commercial success. The increase in acceptance of EDI technology has led to an installation of very large plant as the commercial state of the art that produces $1,500m^3/h$ of water for high pressure steam boiler. More recently, EDI system has found a number of new interesting applications in wastewater treatment, biotechnology industry, and other potential field. Along with further growth and wider applications, the development of stack construction and configuration are also become a concern. In this paper, the principle of EDI process is described and its recent developments, commercial scale, and various applications are pointed out.

• Journal of Power Electronics
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• 제11권4호
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• pp.612-619
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• 2011

This paper presents a water treatment system for leachate from sewage-filled ground that uses a pulsed-power modulator developed based on semiconductor switches in order to realize a long life, a high repetition rate, and a fast rising time. The specifications of the developed pulsed-power modulator are the pulsed output voltage, the output current, the pulse repetition rate (PRR), the pulse width, and an average output power of $60\;kV_{max}$, $300\;A_{max}$, 3000, $50\;{\mu}s$, and 15 kW, respectively. The pulsed-power water treatment system was introduced and analyzed using an equivalent electrical circuit model to optimize the output voltage waveform. The experimental results verify that the proposed water treatment system can be effectively used for industrial applications.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.6-13
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• 2018

Well-modified amino-appended ${\beta}$-cyclodextrin ($AA-{\beta}-CD$) with an amino group at the primary face of the ${\beta}-CD$ was synthesized and used in the catalytic synthesis of chromeno pyrimido[1,2-b]indazol as supramolecular catalysts in water for the first time. $AA-{\beta}-CD$ was characterized by FT-IR, NMR, MALDI-TOF mass spectrometry, and SEM analysis. A possible reaction mechanism featuring molecular complexation was suggested based on 2D NMR (ROESY) spectroscopy, FE-SEM, DSC, and FT-IR. Advantages such as operational simplicity, recyclability of the catalysts, and accessibility in aqueous medium render this protocol eco-friendly.

• 한국산학기술학회논문지
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• 제12권5호
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• pp.2327-2331
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• 2011

본 논문은 세정기의 세척수를 인체에 유익한 자화육각수로 변환시켜주는 기술로서, 세정기로 세척수가 공급되는 유입 관에 자화기를 설치하여 세척수를 인체에 유익한 자화육각수로 변환시켜 사용함에 따라 비데와 변기를 위생적으로 유지 관리하게 해주는 자화육각수 제조 기술에 관련하여 특허를 시계열분석을 통하여 출원이 많은 대표적인 국가별 출원을 분석하였다. 자화육각수 제조 기술 분야의 특허 출원 동향을 살펴보면 대부분 한국과 일본에 의한 특허 출원임을 알 수 있으며, 일본특허는 특허건수와 출원인수가 모두 증가하는 발전기에서 특허건수와 출원인수가 모두 감소하는 퇴조기 단계에 있는 것으로 나타나고 있으며, 미국 및 유럽특허에서는 대체적으로 출원인수와 특허건수가 감소하는 퇴조기 양상으로. 분석 되었다. 따라서 자화육각수를 활용하는 사업에서는 특허 권리차원에서 한국과 일본특허의 출원 동향을 지속적으로 관찰 할 필요가 있으며, 그리고 현재 자화육각수기술은 사업전략구상과 산업지원정책수립이 필요한 단계에 있다. 따라서 향후 자화육각수관련 제품의 연구개발이 다수 예상됨에 따라 관련제조업체나 연구기관에서는 사업화와 특허연구에 유용하게 활용될 수 있을 것이다.

• EDISON SW 활용 경진대회 논문집
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• 제4회(2015년)
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• pp.367-370
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• 2015

Monolayer transition metal dicalcogenide (TMDC) materials are currently attracting extensive attention due to their distinctive electronic, transport, and optical properties. For example, monolayer $MoS_2$ exhibits a direct band gap in the visible frequency range, which makes it an attractive candidate for the photocatalytic water splitting. For the photoelectrochemical water splitting, the appropriate band edge positions that overlap with the water redox potential are necessary. Similarly, appropriate band level alignments will be crucial for the light emitting diode and photovoltaic applications utlizing heterojunctions between two TMDC materials. Carrying out first-principles calculations, we here investigate how the band edges of $MoS_2$ can be adjusted by surface ligand functionalization. This study will provide useful information for the realization of ligand-based band engineering of monolayer $MoS_2$ for various electronic, energy, and bio device applications.

• 한국염색가공학회지
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• 제29권4호
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• pp.202-210
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• 2017

In recent years, the water-based ink have been widely used in various industrial applications due to environmental problems. Dispersibility of the pigment for applications of the water-based ink is the one of the most important technical factors to produce uniform color products. Thus, in this study, the three-roll mill process was used to improve the dispersion of the water-based ink. The results indicated that the three-roll mill reduced the size of pigment particles in the ink more than 50%. In addition, the dispersant showed an important role to maintain the dispersion stability of the pigment in the water-based ink over 120 hours. We also confirmed the optimum contents of the ink stock solution, drying temperature and drying time by the colorimeter and colorfastness tests on produced PET synthetic suedes.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.394-394
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• 2009

Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

• Nuclear Engineering and Technology
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• 제43권3호
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• pp.217-242
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• 2011

A variety of Generation III/III+ water-cooled reactor designs featuring enhanced safety and improved economics are being proposed by nuclear power industries around the world in efforts to solve the future energy supply shortfall. Thermal-hydraulics is recognized as a key scientific subject in the development of innovative reactor systems. Phase change by boiling and condensation in the reverse process is a highly efficient heat transport mechanism that accommodates large heat fluxes with relatively small driving temperature differences. This mode of heat transfer is encountered in a wide spectrum of nuclear systems,and thus it is necessary to determine the thermal limit of water-cooled nuclear energy conversion in terms of economic and safety. Such applications are being advanced with the introduction of new technologies such as nanotechnology. Here, we investigated newly-introduced nanotechnologies relevant to boiling and condensation in general engineering applications. We also evaluated the potential linkage between such new advancements and nuclear applications in terms of advanced nuclear thermal-hydraulics.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2011년도 학술발표회
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• pp.91-91
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• 2011

In the present study, the proposed EMD and NSOR models has been applied in hydrology and climate sciences. Here, we present those applications as the following: (1) to extend future scenarios of Global Surface Temperature Anomaly including long-term oscillation component; (2) to extend the future evolution of the Eastern Canada winter precipitation; (3) to apply EMD in detecting climate change.