• Title/Summary/Keyword: water soluble curing agent

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A Study on the Mechanical Properties of Water Soluble Curing Agent and Epoxy Resins (수용성 경화제에 의한 에폭시 수지의 물성에 관한 연구)

  • Kim, Yong-Ho;Lee, Kwang-Won;Kwak, Young-Chae
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.12-18
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    • 2000
  • With growing concerns of environment and due to strengthening the government regulations on volatile organic compounds(VOC) the coatings industries are developing new technologies to reduce the amount of VOC released from coatings. In this study. a water soluble curing agent of amino-epoxy adduct was synthesized and its structure was identified by FT-IR, GPC and TG/DTA. The mechanical properties of the new curing agent in combination of KER-828 and KER-500 were investigated respectively. As an experimental result, the drying time of KER-828 was faster than that of KER-500 but the adhesion and impact strength of KER-500 was better than that of KER-828.

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Photolithography Process of Organic Thin Film with A New Water Soluble Photoresist

  • Kim, Kwang-Hyun;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1038-1039
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    • 2004
  • We developed a new photoresist which was composed of polyaniline, uv-curing agent, N-methyl-2- pyrrolidine (NMP) and N-Butyl alcohol (BuOH) as solution. The photoresist is characterized by the capability of being developed in water. We successfully patterned pentacene thin film, which was vulnerable to organic solvent and thus could not be patterned by the conventional photolithography process, with the water soluble photoresist and the minimum feature size was found to be 2um.

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One-side Water-repellent Finish of PET Fabrics using UV/Ozone (UV/Ozone 조사에 의한 PET 직물의 편면 발수가공)

  • Kim, Su-Jin;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.100-106
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    • 2011
  • UV-curable water-repellent finish was carried out to impart one-side repellency to the PET fabrics using a formulation of a UV-active fluorocarbon agent and a water soluble photoinitiator. The aqueous formulation was padded on the PET fabrics and it was subsequently UV-cured. The unirradiated side of the cured fabrics was made to wetteable to water by the prolonged UV/ozone irradiation. The influence of photoinitiator concentration, agent concentration and UV energy for photodegradation on the performance of the finished fabrics were investigated. The difference in the functional property of front and back sides was examined by measuring water repellency at each side of the treated fabrics, which resulted in four rating difference between two-side. The UV-cured and photodegraded PET surfaces were characterized by ATR, ESCA and FE-SEM.

Dyeing of Cotton/Polyester Blends with Disperse Dyes in the Presence of DMDHEU/PEG (DMDHEU/PEG와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.7
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    • pp.1025-1034
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    • 2000
  • Cotton differs from polyester in physical and chemical properties. When cotton/polyester blends are dyed, water-soluble dyes are generally used for cotton and disperse dye for polyester. Thus, two bath or one bath-two step dyeing process are usually accepted. These processes consume more energy and cost compared to a single step process. To save energy and cost, a single step dyeing and finishing is carried out with disperse dyes in the presence of a crossslinking agent. K/S values of the dyed fabrics were determined to examine the dyeing property of cotton, cotton/polyester, polyester fabrics dyed with disperse dyes in the presence of DMDHEU/PEG. The concentration of DMDHEU, molecular weight and concentration of PEG, curing time and curing temperature were varied.

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Characterization of Mold Releasing Agent Obtained from Carbon Black Suspension in Natural Polymer Solution (카본 블랙과 천연 고분자를 이용하여 제조한 금속 주조용 이형제의 특성)

  • Lee, Soo;Jin, Seok-Hwan;Park, Jung-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.13-18
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    • 2012
  • A die casting mold releasing agent was prepared from aqueous mixture of powdery carbon black and water soluble natural polymeric materials such as xanthan gum(X-gum) and carboxymethyl cellulose(CMC), which were used as thickening agent as well as curing agent with aldehydes. The suitable concentration of natural polymers for stable dispersion of carbon black in water was 0.25 wt% of X-gum or 1.0 wt% of CMC. When CMC was used less than 1 wt%, the final carbon black disperion showed a rapid phase separation. The adhesion of carbon black releasing agent on glass plate was improved with the amount of crosslinking agent, glutaraldehyde and chain extender, oligosaccharide. However, the affinity of carbon black releasing agent prepared with X-gum was stronger than that with CMC on glass plate. The final carbon black mold releasing agents prepared under our mixing conditions can be applied to the production of castings of high quality with good workability and without worthening evironmental situations.

Relationship between Mechanical Properties and Porosity of Porous Polymer Sheet Fabricated using Water-soluble Particles (수용성 입자를 이용한 다공성 폴리머 구조체의 공극률 향상과 기계적 물성과의 관계)

  • So, Sae-Rom;Park, Suk-Hee;Park, Sang-Hu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.6
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    • pp.16-23
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    • 2018
  • A polymer porous sheet, which can be applied to diverse wearable devices, has some advantages such as light-weight, high flexibility, high elongation, and so many others. In order to fabricate a porous sheet, water-soluble particles like sugar were utilized frequently, and there has been great advances. However, with our best knowledge, there are not enough reports on the mechanical behavior of porous sheets having different porosity. So, in this work, we tried to find out the relationship between porosity and mechanical deformation of a porous sheet. The process parameters such as a particle size, sheet thickness and PDMS mixing ratio with curing agent were analyzed on the effect of increasing the porosity of a sheet. Also, mechanical deformation of a sheet was tested using a tensile experiment. Through the experimental results, we make a conclusion that a highly porous sheet with thin thickness has high flexibility, and it deformed nearly double elongation comparing to worst one among nine cases.

Synthesis and Characterization of Water-soluble Polyamine Durable Antistatic Agent (수용성 폴리아민 내구성 대전방지제의 합성과 그의 특성화)

  • Kim, Seung-Jin;Kim, Han-Ku;Keun, Jang-Hyoun;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.466-477
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    • 1994
  • PEG 600-diglycidyl ethers(PDE) were synthesized using $BF_3$ catalyst by the reaction of epichlorohydrin and PEG 600 which is known to have the hygroscopicity, softening property, and antistatic property. Water-soluble long chain polyamines(PDET) were synthesized by coreaction of PDE and triethylenetetramine which is high conductive aliphatic amine curing agent. To prevent the gelation of the PDET and increase the water-solution stability, water-soluble quaternary ammonium polyamines were synthesized by cationation of PDET with acetic acid. Antistatic agents PDET-2A, PDET-5A, PDET-6A, PDETA-2A and PDETA-4A were prepared by the mixing of PDET-2, PDET-5, PDET-6, PDETA-2 and PDETA-4 with water. Synthesized antistatic agents were treated on PET textiles with and without resin. Then surface electrical resistivity and half life characteristics value were tested. As the results there were no remarkable decreasing changes in antistatic abilities of the textiles treated with PDETA-2A and PDETA-4A after 50 times washing. So PDETA-2A and PDETA-4A were proved to be durable antistatic agents. Surface electrical resistivity of the textiles treated with PDETA-2A and PDETA-4A before washing were $1{\times}10^7{\Omega}$ and $2{\times}10^7{\Omega}$, respectively, and half life characteristics values were 0.8sec and 1.1sec, respectively. Therefore PDETA-2A and PDETA-4A were proved to be good antistatic agents.

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Preblending Effects of Curing Agents on the Characteristics of Mechanically Deboned Chicken Meat (염지제 종류와 혼합에 따른 기계발골 계육의 가공 특성과 저장성)

  • Kang, Soo-Yong;Park, Ki-Soo;Choi, Yang-Il;Lee, Sang-Hwa;Auh, Joong-Hyuck
    • Food Science of Animal Resources
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    • v.29 no.2
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    • pp.220-228
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    • 2009
  • This study was conducted to determine the preblending effect of curing agents on the characteristics of mechanically deboned chicken meat (MDCM), including the pH, water-holding capacity (WHC), and stability under refrigeration conditions. MDCM was preblended with different curing agents [NaCl, 0.75 or 1.5%; sodium tripolyphosphate (STPP), 0.25 or 0.5%; ascorbic acid, 250 or 500 ppm; sodium nitrite, 75 or 150 ppm] and were stored at $4^{\circ}C$ overnight. The preblending of NaCl was found to have improved the WHC and emulsion stability; STPP was found to have improved the pH, WHC, and emulsion stability; and ascorbic acid or sodium nitrite did not affect the pH, WHC, and emulsion stability. The addition of ascorbic acid or sodium nitrite, however, decreased the 2-thiobarbituric acid (TBA) and volatile basic nitrogen (VBN) values of the preblended MDCM through the antioxidizing properties. The mixing effects of different curing agents on MDCM were also evaluated with nine different conditions. Among the treatments, the mixture of NaCl and STPP improved the WHC and emulsion stability due to the increased solubility of salt-soluble protein in the preblended MDCM. The mixture of NaCl, STPP, and ascorbic acid increased the pH, WHC, and emulsion stability, but the mixture of NaCl, STPP, ascorbic acid, and sodium nitrite improved the WHC, emulsion stability, and redness of the surface color with improved storage stability due to the decreased VBN and TBA values. As a result, the mixture of 1.5% NaCl, 0.5% STPP, 500 ppm ascorbic acid, and 75 ppm sodium nitrite showed the best properties as curing agents for MDCM preblending.