• 한국환경과학회지
• /
• 제11권6호
• /
• pp.489-496
• /
• 2002

The purpose of this study was to investigate spatial distributions of total deposition. A total number 79 samples were collected at 17 sampling sites from September 1999 to January 2000. Total (=wet+dry) atmospheric depositions were collected by filtered deposition sampler at sampling site (the Western Part of Kyongsangnam Province). In addition, the deposition of soluble and insoluble fraction was also investigated to find a suitable simplified collection method for a long-term monitoring of total deposition. The total depositions were measured soluble amount(mm/month), insoluble amount(kg/km$^2$/month), pH, conductivity(E.C.) and eight ionic components. The spatial distribution of deposition flux was to estimated by using a kringing analysis. The 17 sites mean fluxes of water soluble ionic components; SO$_4$$\^$2-/, Cl$\^$-/, NO$_3$$\^$-/, Na$\^$+/, NH$_4$$\^$+/, K$\^$+/, Mg$\^$2+/, Ca$\^$2+/ were 100.7∼315.6kg/km$^2$/month, 30.1∼234.3kg/km$^2$/month, 64.4∼ 139.4kg/km$^2$/month, 7.5∼68.3kg/km$^2$/month, 10.7∼48.7kg/km$^2$/month, 5.6∼27.9kg/km$^2$/month, 4.5∼17.5kg/km$^2$/month, 27.6∼81.7kg/km$^2$/month, respectively.

• 한국대기환경학회지
• /
• 제8권3호
• /
• pp.191-197
• /
• 1992

In order to investigate the chemical components of acid precipitation at Kangwha near the Yellow Sea and Seoul in Korea, the precipitation samples were collected by wetonly precipitation sampler from February 1991 to January 1992, and pH, electric conductivity(E. C.) and major water-soluble ionic components were analyzed. Strong negative linear correlations were observed between the rainfall amount and the sum of major ionic components in $\mu eq/\ell$ at two sites. The sum of major ionic components also correlated negatively with rain intensity. The analytical results of precipitation samples at two sites were compared each other. Average values of volume-weighted pH were found to be 5.21 at Kangwha and 5.09 at Seoul. The cationic abundance($\mu eq/\ell$) in rainwater showed the general trend $NH_4^+ > Na^+ > Ca^{2+} > Mg^{2-+} > H^+ > K^+$ at Kangwah and $NH_4^+ > Ca^{2+} > Na^+ > H^+ > Mg^{2+} > K^+$ at Seoul. The anionic abundance showed the general trend $SO_4^{2-} > Cl^- > NO_3^-$ at Kangwha and $SO_4^{2-} > NO_3^- > Cl^-$ at Seoul. The concentrations of seasalt such as $Na^+ and Cl^-$ were higher at Kangwha than Seoul. The concentrations of $nss-SO_4^{2-}, nss-Cl^- and NO_3^-$ which are acid composition were higher at Seoul(96.3 $\mu eq/\ell$) than Kangwha(69.0 $\mu eq/\ell$). The contribution of seasalt to the composition of precipitation were higher at Kangwha(34.1%) than Seoul(15.7%). Ammonia and calcium species in rainwater at Kangwha and Seoul are interpreted to have 91% of neutralizing capacity of the original sulfuric and nitric acids. Provided that the precipitation acidity originates primarily from sulfate and nitrate, sulfate was found to contribute about 73-75% of the free precipitation acidity.

• 농약과학회지
• /
• 제20권2호
• /
• pp.128-132
• /
• 2016

본 연구에서는 유기농업자재 중 잔류 휘발성 유기용매의 정성 및 정량분석을 위해 Headspace-GC 분석법을 matrix 조성을 달리하여 검출능을 중심으로 시험하였다. Headspace sampler내 흡습제처리 혹은 DMSO molar ratio를 증가시키는 방법을 통해 친수성기를 갖는 유기용매의 분석능이 최대 715% 향상되었으며, 특히 농자재의 보조제로 많이 사용되는 계면활성제의 경우 시료 중 농도가 계면활성제의 종류보다 유기용매 분석능에 미치는 영향이 큰 것을 확인할 수 있었다(68.5-179.1%). 특히 병해충 관리용 유기농업자재의 보조성분 및 함량이 정확히 공개되지 않은 상황에서 유기용매의 함량 정량분석을 위해서는 각각의 분석시료마다 matrix-matched calibration을 통한 정량 분석으로의 접근이 검토되어야 할 것으로 판단된다.

• 대한본초학회지
• /
• 제30권3호
• /
• pp.19-24
• /
• 2015

Objectives : HPL-1, a novel herbal medicine which is composed of five herbs such as Kalopanacis Cortex, Chaenomelis Fructus, Raphani Semen, Atractylodis Rhizoma and Pulvis Aconiti Tuberis Purificatum, was developed for treatment of osteoarthritis. This study is aimed to develop analytical method for consistent quality control of HPL-1 and validate chromatographic method. Methods : Chromatographic analysis was performed using ultra-high performance liquid chromatography - diode array detector (UHPLC-DAD) equipped with RP-amide column, column oven, and auto sampler. Marker compounds [protocatechuic acid, chlorogenic acid, liriodendrin, 3,5-dicaffeoylquinic acid, ${\beta}$-D-(3-O-sinapoyl)-fructofuranosyl-$\alpha$-D-(6-O-sinapoyl)glucopyranoside and benzoylmesaconine] were separated by step gradient elution of acetonitrile and 0.1% phosphoric acid/water. The method validation was evaluated by quantitative validation parameters of linearity, accuracy, precision, limit of detection (LOD) and limit of quantification (LOQ) according to KFDA guideline.Results : An optimized method for six marker compounds in HPL-1 was established by UHPLC-DAD. The correlation coefficient (R²) with each calibration curve was greater than 0.99. The LOD and LOQ were within the range of 0.008-0.090 and $0.023-0.274{\mu}g/mL$, respectively. The relative standard deviation (RSD) of intra- and inter-day variability were less than 4.0%. The result of recovery test was range from 93.3-106.3% with RSD < 4.0%.Conclusions : These results suggest that the quantitative UHPLC method is precise, accurate, effective for quality evaluation of HPL-1. The method may also contribute to improve quality of crude drug preparations used for treatment of various diseases.

• Journal of Korean Society for Atmospheric Environment
• /
• 제19권E4호
• /
• pp.177-186
• /
• 2003

The total of 1,454 aerosol samples were collected by high volume tape sampler at the Gosan Site in Jeju Island from 1992 to 1999, and the major water-soluble ionic components were chemically analyzed. The mean concentrations of nss-S $O_4$$^{2-}$, N $H_4$$^{＋}$, and N $O_3$$^{[-10]}$ showed high values, which were 6.73, 1.45, and 1.45 ${\mu}{\textrm}{m}$/㎥, respectively, while $Ca^{2+}$ and $K^{+}$ concentrations were low with the values of 0.49 and 0.42 $\mu\textrm{g}$/㎥. The concentrations of most components increased in spring but decreased in summer, especially with the remarkable increase of $Ca^{2+}$ and N $O_3$$^{[-10]}$ concentrations in spring. The seasonal comparison of nss-S $O_4$$^{2-}$ concentrations showed higher values with the order of spring > fall 〉 winter〉 summer, but spring 〉 winter〉 fall 〉 summer for N $O_3$$^{[-10]}$ Meanwhile, the concentration levels of N $a^{+}$ and C $l^{[-10]}$ increased more in winter season. According to the investigation of wind direction effect, the concentrations of most aerosol ionic components showed higher values consistently at the westerly and northerly wind conditions. Based on the factor analysis, the atmospheric aerosols in the Gosan Site are considered to be largely affected by marine sources, followed by anthropogenic and soil sources.urces..

• 한국대기환경학회지
• /
• 제11권2호
• /
• pp.179-184
• /
• 1995

This study was carried out to characterize sources of suspended particulate matter(SPM) in Mt. Soback area from January to Novembver in 1993. The collection and major water soluble ion analysis of SPM were conducted by using a High Volumn Air Sampler(HVAS; W&A Inc., PM-10) and ion chromatograph(DIONEX 4000i), respectively. The variations of SPM and major ion concentrations were found to be 9. sim. 156.mu.g/ $m^{3}$, $F^{-10}$ 0.00 .sim. 0.15.mu.g/ $m^{3}$, C $l^{-10}$ 0.06 .sim. 3.79.mu.g/ $m^{3}$, N $O_{3}$$^{-10}$ 0.90 .sim. 6.85.mu.g/ $m^{3}$, S $O_{4}$$^{2-}$ 1.99 .sim. 9.36.mu.g/ $m^{3}$ N $a^{+}$0.00 .sim. 0.27.mu.g/ $m^{3}$, N $H_{4}$ $^{+}$0.72 .sim. 5.77.mu.g/ $m^{3}$, $k^{+}$0.03 .sim. 0.88.mu.g/ $m^{3}$ and $Ca^{2+}$0.12 .sim. 2.76.mu.g/ $m^{3}$. Tree sources were identified by Principal Component Amalysis(PCA) using a SPSS/P $C^{+}$. The explanation ability of forst, second and third Principal Component were 60.8%, 13.6%, 8.2%, of total variance. The sources classfied by PCA were found to be secondary aerosol/fuel combustion, soil dust related cement production/yellow sand and aerosol related waste burning.related waste burning.g.

• 환경위생공학
• /
• 제9권2호
• /
• pp.8-23
• /
• 1994

During the period from Mar., 1991 to Feb., 1992 66 tSP samples were collected by Hi volume air sampler at 1 sampling site in Seoul and the amount of concentration of 21 components(SO$_{4}$$^{2-}$, NO$_{3}$$^{-}$, NH$_{4}$$^{+}$, Cl$^{-}$, Al, Ba, Ca, Cd, Cr, Cu, Fe, It Mg, Mn, Na, Ni, Pt Si, Ti, Zn, Zr ) were measured. And monthly and seasonal variation were surveyed and the principal component analysis( PCA ) were carried out with respect to these amount of pollutants, minimum of visibility and radiation on a horizontal surface. The total amount of soluble ion in water was high in order o(SO$_{4}$$^{2-}$> NO$_{3}$$^{-}$> N%'>Cl$^{-}$ and metal ion was high in order of Na> Ca>Si> Fe> Al> K> Mg> Zn> Pb> Cu>Ti> Mn > Ba> Cr> Zr> Ni> Cd. There was Seasonal variation in concentration for SO$_{4}$$^{2-}$, NH$_{4}$$^{+}$, Cl$^{-}$, Na, Al, Ca, Bt Mg, Fe and Si. It was assumed that the components of the highest concentration on April were depend on yellow sand and the frequency of wind velocity and direction. As the results of PCA, the amount of pollution components was able to characterized with two principal components(Z$_{1}$, Z$_{2}$ ). The first principal components Z$_{1}$ was considered to be a factor indicating the pollutants originated from natural generation and The second principal components Z$_{2}$ was considered to be a factor indicating the pollutants originated from human work. The monthly concentration of pollutants in ISP, minimum of visibility and radiation on a horizontal surface was possible to evaluate by the use of these two principal components Z$_{1}$ and Z$_{2}$ .

• 한국농공학회논문집
• /
• 제64권3호
• /
• pp.33-43
• /
• 2022

South Korea's agricultural nitrogen balance and phosphorus balance rank first and second, respectively, among OECD countries, and proper nutrient management is required to preserve the water quality of rivers and lakes. This study evaluates the effects of furrow mulching on the reduction of non-point source pollution (NPS) load from a sloped upland. The study site was Wanju-gun, Jeollabuk-do, and the survey period was from 2018 to 2019. The slope of the testbed was 13%, and the soil type was sandy loam. The cropping system consisted of maize-autumn Chinese cabbage rotation. The testbed was composed of bare soil (bare), control (Cont.), furrow vegetation mulching (FVM), and furrow nonwoven fabric mulching (FFM) plots. Runoff was collected for each rainfall event with a 1/100 sampler, and the NPS load was calculated by measuring the concentrations of SS, T-N, and T-P. The NPS load was then analyzed for the entire monitoring and crop cultivation periods. During the monitoring period, the effect of reducing the NPS load was 1.5%~44.5% for FVM and 13.1%~55.2% for FFM. During the crop cultivation period, it was 1.2%~80.5% for FVM and 27.0%~65.1% for FFM, indicating that FFM was more effective than FVM. As the NPS load was fairly high during the crop conversion period, an appropriate management method needs to be implemented during this period.

• 한국농공학회논문집
• /
• 제65권4호
• /
• pp.1-10
• /
• 2023

As a result of climate change, non-point source pollution (NPS) from farmland with the steep slope during the rainy season is expected to have a significant impact on the water system. This study aimed to evaluate the effect of furrow mulching using alfalfa and PAM (Polyacrylamide) materials for each rainfall event, while considering the load characteristics of NPS. The study was conducted in Wanju-gun, Jeollabuk-do, in 2022, with a testbed that had a slope of 13%, sandy loam soil, and maize crops. The testbed was composed of four plots: bare soil (Bare), No mulching (Cont.), Vegetation mulching (VM), and PAM mulching (PM). Runoff was collected from each rainfall event using a 1/40 sampler and the NPS load was calculated by measuring the concentrations of SS, T-N, T-P, and TOC. During farming season, the reduction efficiency of NPS load was 37.1~59.5% for VM and 38.2~75.7% for PM. The analysis found that VM had a linear regression correlation (R²=0.28~0.86, P-value=0.01~0.1) with elapsed time of application, while PM had a quadratic regression correlation (R²=0.35~0.80, P-value=0.1). These results suggest that the selection of furrow mulch materials and the appropriate application method play a crucial role in reducing non-point pollution in farmland. Therefore, further studies on the time-series reduction effect based on the application method are recommended to develop more effective preemptive reduction technologies.

• 생태와환경
• /
• 제54권4호
• /
• pp.272-279
• /
• 2021

필터의 손상 없이 포집할 수 있는 필터케이스를 적용하고, 전압 제어와 압력 제어를 각각 할 수 있는 펌프 방식의 eDNA 포집 및 채수 시스템을 개발하여 집수매거 취수원을 대상으로 종래의 진공압 방식의 포집 및 추출 실험과 eDNA 농도를 비교함으로써 개발 시스템의 필터링 성능을 평가하였다. 개발된 시스템은 전압제어(Manual pump system) 방식과 압력제어(Automatic pump system) 방식으로 구분하여 필터링 시 필터기 내부 압력을 측정하고 각 시스템의 압력 변화를 비교하였다. 전압제어 방식은 필터링 초기에 65 [KPa]로 시작하여 필터링 시간이 경과함에 따라 필터에 축적되는 여과물의 양이 증가하므로 압력이 점진적으로 증가하였다. 압력제어 방식은 설계된 알고리즘에 따라 일정 압력을 유지하도록 제어한 결과, 압력 센서의 피드백 시간에 따라 필터링 과정에서 압력 변동의 폭은 차이가 있으나 목표 압력에 수렴하는 것을 확인하였다. 개발된 시스템의 필터링 성능을 확인하기 위해 eDNA 농도를 측정하고 전압제어 방식과 압력제어 방식을 대조군과 비교하였다. 전압제어 방식은 대조군과 유사한 결과를 얻을 수 있었으나 압력제어 방식은 대조군에 비해 낮게 나타났다. 압력제어 방식의 경우 필터링 시 압력 편차가 크고, 필터링 과정에서 일정한 압력을 유지하기 때문에 나타난 결과로 사료된다. 따라서 필터링 시에는 일정한 압력을 유지하는 것보다 필터링 시간 경과와 함께 여과물의 증가에 따라 압력이 점진적으로 증가하는 전압제어 방식이 eDNA를 포집하는데 적합함을 확인하였다. 정수역과 유수역의 eDNA 평균농도를 대조군으로 비교한 결과, 각각 96.2 [ng µL^-1], 88.4 [ng µL^-1]로 나타났으며, 펌프 방식으로 eDNA 평균농도를 비교한 결과는 각각 90.7 [ng µL^-1], 74.8 [ng µL^-1]로 정수역에서 필터링한 시료에서 높게 나타났다. 정수역에서 eDNA 농도가 높게 나타난 것은 잔존하는 eDNA를 비롯한 미세 유기물의 영향으로 사료된다.