• Membrane and Water Treatment
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• 제13권1호
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• pp.1-6
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• 2022

The regulations of the International Maritime Organization (IMO) have been steadily strengthened in ship emissions. Accordingly, there is a growing need for development of related technologies for the removal of contaminants that may occur during the treatment of SOx and NOx using a wet scrubber. However, this system also leads to wastewater production when the exhaust gas is scrubbed. In this research, we evaluated the performance of an ion selective resin process in accordance with scrubber wastewater discharge regulations, specifically nitrate discharge, by the IMO. Accelerated real and synthetic wastewater of wet scrubbers, contained high amounts of TDS with high nitrate, is used as feed water in lab scale systems. Furthermore, a pilot scale dissolved air flotation (DAF) using microbubble generator with ion exchange resin process was combined and developed in order to apply for the treatment of wet scrubber wastewater. The results of the present study revealed that operating conditions, such as resin property, bed volume (BV), and inlet wastewater flow rate, significantly affect the removal performance. Finally, through a pilot test, DAF with ion exchange resin process showed a noticeable improvement of the nitrate removal rate compared to the single DAF process.

• 한국물환경학회지
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• 제23권1호
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• pp.122-130
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• 2007

This study was conducted to evaluate water treatment characteristics according to vegetated wetland(V) and open water(O) arrangements in free water surface constructed wetland. Three pilot-scale wetlands, V-V, O-V and V-O, were built and operated. $BOD_5$ was a slightly reduced at all the arrangements because the influent concentration was so low as background concentration of constructed wetlands. While T-N and T-P removal efficiency showed higher than 50% for all cases. The O-V arrangement showed the highest removal efficiency: 20% for $BOD_5$, 56% for SS, 59% for T-N and 72% for T-P. Effluent concentration of the O-V were significantly low compared with those from the V-O. O-V arrangement would be beneficial in the light of pollutant removal efficiency as well as construction cost.

• 한국입자에어로졸학회지
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• 제13권3호
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• pp.119-125
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• 2017

A novel two stage cylindrical cyclone was developed for a 3 phase separator in shale oil production industry. The cyclone performance was compared with a cone type cyclone and multi cyclone at the same experimental condition using water and oil mists generated by a humidifier and atomizer at the flow rate 1 to $2m^3/min$. The removal efficiency of total suspended water droplets by the novel cyclone, calculated using inlet and outlet concentrations measured by an optical particle counter, was 99% which is higher than 90% of oil droplet removal efficiency at $2m^3/min$. It might be due to the evaporation of small water droplets during the tests. The water and oil droplet removal performance of the novel cyclone based on the quality factor which is a function of pressure drop and removal efficiency was the highest among three cyclones. The results indicate that the cyclone could be an economical device to remove water and oil mists from shale gas generation processes where a huge three phase separator is commonly used.

• 한국농공학회논문집
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• 제56권6호
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• pp.85-91
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• 2014

In this study, the water quality purification of new medias which were NPS media, hyugato, mineral stone, charcoal for applying soil media of Integrated Management Practices (IMPs) of Low Impact Development (LID) were evaluated. The influent concentrations of COD, T-N, and T-P were 117.8 mg/L, 17.1 mg/L, and 2.062 mg/L, respectively. The infiltration capacities of NPS media, hyugoto, mineral stone, charcoal, and gravel were $7.1{\times}10m/s$, $7.3{\times}10^{-5}m/s$, $7.9{\times}10^{-5}m/s$, $6.0{\times}10^{-5}m/s$, respectively. All media meet criteria of infiltration capacity as surface soil layer at IMPs which is over $1.0{\times}10^{-5}m/s$. Maximum removal rates of COD, T-N, and T-P occurred at Charcoal with 98 % of COD removal rate, NPS with 78 % of T-N removal rate, and hyugato with 75 % fo T-P removal rate, respectively. For more high removal efficiency of all water quality item, the mixed media which is 4.5(NPS media): 1(charcoal) : 4.5 (hyugato) as volume ratio was evaluated. The infiltration capacity of mixed media was $7.9{\times}10^{-5}m/s$ and met the criteria of infiltration as surface soil layer. The water quality removal efficiencies of mixed media were very high with showing 70 % for COD, 85 % for T-N, and 71 % for T-P. The mixed media could purify the water quality of surface runoff and was recommended to used at the LID site of ground water quality problem.

• 청정기술
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• 제3권2호
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• pp.31-33
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• 1997

Nitrate contamination in surface water and ground water have increased in Korea. This trend has raised concern because nitrates caused methemoglobinemia in infants. To remove nitrates from waters, various purification processes including ion-exchange, biological denitrification, and chemical denitrification are currently in use for the treatment of water. However, little economically advantageous process exists for the industrial scale treatment of effluents highly polluted with nitrates. A new process has been developed for nitrate and other salts removal from polluted waters. Alumina cement and lime served as precipitating agents to remove nitrate with stirring at basic pH. Decreasing alumina content in alumina cement result in a increasing in nitrate removal yield. Stable removal of nitrate(1000mg/L) was readily achieved by two-stage removal process.

• 상하수도학회지
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• 제10권1호
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• pp.78-84
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• 1996

The presence of ammonia, usually in the form of ammonium ion ($NH_4{^+}$), can enhance bacterial growth m the distribution system and make the production of drinking water more costly if ammonium must be removed to ensure good disinfection. Removal of ammonia by biological oxidation could be economical which prevents excess chlorine dosage In this research, effects of hydraulic retention time (HRT) and media type on the ammonia removal efficiencies of submerged biofilm reactor were investigated. The biofilm reactors combined the characteristics of high biological solids capture efficiency and good hydraulic control. The results indicate that biofilms can remove over 77 percent of the ammonia with HRT of longer than 2 hr even at low temperature ranging from 14.6 to $16.6^{\circ}C$. The HRT has a significant effect on nitrification. The overall nitrification and efficiency of ammonia removal increase with increasing HRT. It has also been observed that when the fibrous media was used, the ammonia removal, nitrification rate and endurance to shock improved.

• Membrane and Water Treatment
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• 제9권1호
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• pp.63-68
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• 2018

Molecular dynamics simulations were used to study the removal of Cd(II) as a heavy metal from wastewater using armchair carbon nanotube, boron nitride nanotube and silicon carbide nanotubes under applied electric field. The system contains an aqueous solution of $CdCl_2$ as a heavy metal and a (7,7) nanotube as a nanostructured membrane, embedded in a silicon nitride membrane. An external electric field was applied to the considered system for the removal of $Cd^{2+}$ through nanotubes. The simulation results show that in the same conditions, considered armchair nanotubes were capable to remove $Cd^{2+}$ from wastewater with different ratios. Our results reveal that the removal of heavy metals ions through armchair carbon, boron nitride and silicon carbide nanotubes was attributed to the applied electric field. The selective removal phenomenon is explained with the calculation of potential of mean force. Therefore, the investigated systems can be recommended as a model for the water treatment.

• Membrane and Water Treatment
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• 제7권2호
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• pp.143-154
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• 2016

Acetic acid can be removed from wastewater by esterification in a membrane reactor. Pervaporation membrane reactor (PVMR) is an alternative process to conventional separation processes. It is an environmentally friendly process. The main advantages of the PVMR are simultaneous water removal and production of an ester economically. In this study, the synthetic wastewater has been used. Esterification reaction of acetic acid with isopropanol has been studied in the presence of tungstosilicic acid hydrate as a catalyst in a batch reactor and in a PVMR. The effects of important operating parameters such as reaction temperature, initial molar ratio of isopropanol to acetic acid and catalyst concentration has been examined. Removal of acetic acid (conversion of acetic acid) was obtained as 85% using a PVMR by removal of water from the reaction mixture.

• 한국응용과학기술학회지
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• 제24권4호
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• pp.332-338
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• 2007

Based on the experiment results of laboratory scale modified anoxic-oxic process for leachate treatment, biological nitrogen removal program was verified in terms of SS, COD, and TN concentration. These measured water qualities concentration could be predicted by biological nitrogen removal program with $R^2$ of 0.994, 0.987, 0.990, respectively. No error was occurred between water qualities concentration and quite wide range of water qualities concentration (i.e., 50-4200 mg/L) during the modelling. Each unit and final effluent of simulated concentration was kept good relationship with that of measured concentration therefore this biological nitrogen removal program for sewage or wastewater treatment plants has good reliance.

• 환경위생공학
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• 제15권2호
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• pp.34-40
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• 2000

In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.