• Clean Technology
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• 제18권1호
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• pp.63-68
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• 2012

In this study, aluminum hydroxide ($Al(OH)_3$) was synthesized by Bayer process and sodium contained in $Al(OH)_3$ was removed with the acid solution such as HCl and acetic acid for the synthesis of high purity alumina. The bauxite produced in Queensland of Australia was used for the production of alumina by Bayer, and was crushed to a particle size of below 10 um by attrition mill. The crushed bauxite was treated in sodium hydroxide solution of 5 N for the elution of aluminum component. The elution of aluminum from bauxite was carried out at $140^{\circ}C$ and 3.4 atm in autoclave. The sample solution was separated to the red mud and liquid solution by filter paper. The elution of aluminum from bauxite was confirmed with changing a structure and aluminum content in both bauxite and red mud analyzed by XRD and EDX. Aluminum contained in the separated solution was crystallized to $Al(OH)_3$ with the addition of aluminum hydroxide used as the seed material. $Al(OH)_3$ powder obtained during the crystallization process was purified by several times washing with distillated water. It was also confirmed that the sodium remained in $Al(OH)_3$ powder is removed with acid solution. The purity of $Al(OH)_3$ powder produced in this study was 99.3% and the content of sodium was reduced to approximately 0.009% after the acid treatment.

• Journal of the Mineralogical Society of Korea
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• 제2권2호
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• pp.81-89
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• 1989

Alunite occurs as massive, cavity-filling and veinlets in the Cretaceous Hwangsan Formation in the Sungsan mine, Korea. It is a hydrothermal alteration product of rhyolitic tuffs, and associated with dickite, quartz and barite. The average chemical formula of alunite in the mine is $(K_{0.93}Na_{0.07})_{1.00}Al_{3.00}(SO_4)_{2.00}(OH)_6$. Atomic percentage of Na substituting for K in A site of the alunite structure varies from 5.9 to 9.2. Unit-cell volume and c dimension decrease with increasing Na atomic percentage. On the basis of thermal and high temperature XRD analyses, the decomposition of alunite into $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ concomitant with the liberation of structural water (12.86%) occurs at about $550^{\circ}C$. The reconstruction of $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ to $Al_2(SO_4)_3$, arcanite and thenardite, and the crystallization of ${\gamma}-Al_2O_3$ take place at about $720^{\circ}C$. The destruction of $Al_2(SO_4)_3$ structure takes place at about $760^{\circ}C$ removing 3/4 of total $SO_3$ (27.32%).

• Applied Chemistry for Engineering
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• 제5권6호
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• pp.1036-1043
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• 1994

The silane crosslinking method was applied for the crosslinking of polyethylene (PE). Crosslinking of PE was performed by, first grafting vinyltrimethoxysilane(VTMOS) to the main chain of PE using an extruder at $200{\sim}210^{\circ}C$, followed by exposure to three different silane crosslinking conditions (1. immersed in $80^{\circ}C$ water, 2. at $80^{\circ}C$ air forced convection oven, 3. exposed to air at room temperature ). The thermal characteristic changes of PE resins with respect to the silane crosslinking conditions were studied by measuring the crystalline melting temperature, density and crosslinking reaction rate. Because silane crosslinking was carried out at solid state, crystalline melting temperature, crystallinity, crystal growth rate, crosslinking reaction rate and the change in the density of silane crosslinked PE were affected by crosslinking condition and the type of base resin. The properties of silane crosslinked PE were different from those of Peroxide crosslinked PE which was crosslinked at the molten state. It was found, from the result of DSC analysis, that silane crosslinked linear low density polyethylene(LLDPE) crosslinked at room temperature had no secondary melting peak because the crosslinking reaction proceeds slowly as the crystalline grows. After crystallization, the melting point of PE was lowered by crystalline interruption of crosslinked site.

• Korean Chemical Engineering Research
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• 제52권4호
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• pp.530-537
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• 2014

Moisture is a major factor causing the deteriorative physical change, microbial growth, and chemical reaction of the products. In this study, the moisture absorbing composite films have been prepared with moisture absorbing material of polyacrylic acid partial sodium salt (PAPSS) impregnated on LLDPE polymer for the functional packaging applications. The results showed that PAPSS impregnated film illustrated uniformly dispersed PAPSS particles in the LLDPE polymer matrix. The transparency of the PAPSS impregnated film decreased slightly at higher PAPSS concentrations. An increase in the PAPSS content for moisture-absorbing films showed a similar decrease in tensile strength, percent elongation at break, and tear strength. Their values of films impregnated with PAPSS of 0.5, 1, and 2% showed no significant difference. Meanwhile, 4% PAPSS films significantly decreased the values of mechanical properties compared to the films impregnated with different PAPSS levels. Values of the oxygen permeability and water vapor permeability for PAPSS impregnated films decreased significantly with greater PAPSS. The results indicate that 4% PAPSS impregnated in LLDPE films had high affinity of moisture absorbencies compared to the other films. The mathematical equation that best described the moisture sorption isotherm of each film sample was the GAB equation at $25^{\circ}C$. The crystallization and melting temperatures of PAPSS films were influenced by the addition of PAPSS material, but showed good thermal stability.

• Journal of Korean Tunnelling and Underground Space Association
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• 제22권5호
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• pp.485-500
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• 2020

Due to various advantages such as small facilities, ease of construction and so on, the grouting technology which is widely used in construction field has developed remarkably compared with the past. However, the efforts to improve the homogeneity of quality, long-term durability and environmental problems have been continued. In recent years, new grouting method has been developed in order to solve problems such as low strength, durability and leaching phenomenon of liquid glass (sodium silicate) grouting material in Korea. A newly developed method integrates the injection material with the ground by the self-healing material of crystallization growth type. For this reason, it is known that improvement of the durability and water quality of the ground, prevention of leaching, and environment friendliness can be expected. The present study applied a newly developed method to test sites and verified its effect such as injection range, improvement effect, waterproofing performance and so on. Standard penetration test, field permeability test, borehole shear test, pressuremeter test and pH test were conducted, and the results were compared between before and after developed method application. As results of tests, the field applicability and improvement effect of developed method were proved to be excellent.

• Economic and Environmental Geology
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• 제53권5호
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• pp.553-564
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• 2020

Transition between explosive and effusive eruption in Ulleung Island is observed in the Nari Scoria Deposits and Albong Trachyandesite (lava dome) origined by dome-building eruption and may be related to factors such as magma influx, ascent rate and degassing. However, the interpretation of them has not been resolved yet because the interaction between these factors is not complex but also the resulting behaviour during eruption is unpredictable. This paper focuses on the explosive and effusive activity perceived during building the Albong lava dome in Nari caldera. Samples were collected along with time from the scoria deposits and lava dome, linked to eruption stage and style of activity. Textures of groundmass feldspar microlites from these samples are quantitatively analyzed, including measurements of areal number density, mean microlite size, crystal aspect ratio, groundmass crystallinity and crystal size. The microlite textures show that shallow pre- and syn-eruptive magmatic processes acted to govern the changing behaviour during the eruption. Transition between explosive and effusive eruption was driven by the dynamics of magma ascent in the conduit, with degassing and crystallisation acting via feedback mechanisms, resulting in a cycle of effusive and explosive eruption.

• Korean Chemical Engineering Research
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• 제52권6호
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• pp.768-774
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• 2014

SI process is a thermochemical process producing hydrogen by decomposing water while recycling sulfur and iodine. Various technologies have been developed to improve the efficiency on Section III of SI process, where iodine is separated and recycled. EED(electro-electrodialysis) could increase the efficiency of Section III without additional chemical compounds but a substantial amount of $I_2$ from a process stream is loaded on EED. In order to reduce the load, a crystallization technology prior to EED is considered as an $I_2$ removal process. In this work, $I_2$ particle sinking behavior was modeled to secure basic data for designing an $I_2$ crystallizer applied to $I_2$-saturated $HI_x$ solutions. The composition of $HI_x$ solution was determined by thermodynamic UVa model and correlation equations and pure properties were used to evaluate the solution properties. A multiphysics computational tool was utilized to calculate particle sinking velocity changes with respect to $I_2$ particle radius and temperature. The terminal velocity of an $I_2$ particle was estimated around 0.5 m/s under considered radius (1.0 to 2.5 mm) and temperature (10 to $50^{\circ}C$) ranges and it was analyzed that the velocity is more dependent on the solution density than the solution viscosity.

• Economic and Environmental Geology
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• 제37권5호
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• pp.569-583
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• 2004

The rock properties of the West pagoda in the Gameunsaji temple site are composed mainly of dark grey porphyritic granodiorite with medium grained equigranular texture and developed with small numerous dioritic xenoliths. These xenoliths occurred with small holes due to different weathering processes. As a weathering results, the rock properties of this pagoda occur wholly softened to physical hardness because of a complex result of petrological, meteorological and biological causes. Southeastern part of the pagoda deteriorated seriously that the surface of rock blocks showed partially exfoliations, fractures, open cavities in course of granular decomposition of minerals, sea water spray and crystallization of salt from the eastern coast. The Joint between blocks has small or large fracture cross each other, contaminated and corrupted for inserting with concrete, cement mortar, rock fragments and iron plates, and partially accelerated coloration and fractures. There are serious contamination materials of algae, fungus, lichen and bryophytes on the margin and the surface on the roof stone of the pagoda, so it'll require conservation treatment biochemically for releasing vegetation inhabiting on the surface and the discontinuous plane of the blocks because of adding the weathering activity of stones and growing weeds naturally by soil processing on the fissure zone. Consisting rock for the conservation and restoration of the pagoda would be careful choice of new rock properties and epoxy to reinforce for the deterioration surfaces. For the attenuation of secondary contamination and surface humidity, the possible conservation treatments are needed.