• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.74-77
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• 2004

Porous membranes were prepared via thermally induced phase separation (TIPS) of (ethylene-co-vinyl alcohol) (EVOH)/glycerol mixtures. The liquid-liquid (L-L) phase boundaries are shifted to higher temperature when the ethylene contents in EVOH increase. Moreover, the kinetic study proved that the growth of droplets formed by the general liquid-liquid (L-L) phase separation obeyed a power-law scaling relationship in the later stage of spinodal decomposition (SD). A new phase separation mechanism was presented, in which the L-L phase separation could be resulted from the crystallization. The hollow fiber membranes were prepared. The membranes showed asymmetric structures with skin layer near the outer surface, the larger pores just below the skin layer and the smaller pores near the inner surface. The effect of ethylene content (EC) in EVOH, cooling water bath temperature and take-up speed on membrane performance was investigated.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.250-255
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• 2003

TMA clathrate that is used as PCM of low temperature thermal storage system in this research creates hydrate crystallization at higher temperature then pure water, and its application is expected as PCM because of comparatively big latent heat without phase separation phenomenon. Acetone, Ethylen Glycol, and Ethanol is used as additive and evaluated experimentally for the purpose of the improvement in subcooling of TMA clathrate. In view of the results so far achieved subcooling is improved, the running time of the refrigerator is reduced. Thus the results are expected to use for the increase of coefficient of performance of low temperature thermal storage system in the building.

• 한국세라믹학회지
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• 제34권5호
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• pp.491-499
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• 1997

High flexible lightweight composites containing tobermorite as a main mineral is produced using various amorphous silicates, lime, cement and fibers. Here, Mechanical properties of the composites were studied by observing microstructures of hydrates and fibers. Amorphous silicates having better hydraulicity retarded the crystallization of tobermorite due to better formation of C-S-H gel in water bath curing, but, difficult conversion from C-S-H gel to tobermorite in hydrothermal reaction. In the low molar ratio of CaO/SiO2 (0.67), faster crystalization was observed dued to more impurities such as Al2O3 alkali, resulting in improving mechanical properties due to small crystal size and many contact points. It was identified that a lot of calcium silicate hydates formed at surface of pulps increase bonding strength and the crack-resistance of matrix in the composites, but decrease hardness and compressive strength. The choice of amorpous silicates having better hydraulicity, low CaO/SiO2 adding each fibers bellow about 5% in the raw mixs and lower molding pressure should be needed at improve mechanical properties of composites.

• KIEAE Journal
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• 제7권5호
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• pp.121-126
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• 2007

This is the experimental study on the functional property of the light-weight concrete according to the mineral composite. According to the increase of the functional mineral, Autoclaved light-weight concrete (ALC) have a effect of high far infrared ray, deodorization, anion and change of chromaticity on D65 of light source. Compressive strength and change of specific gravity by foaming of Mixed Slurry in accordance with additive rates and Water. It chracterizes surface by SEM, chemical component and crystallization by XRD, XRF. the results of this experiment studied influences of ALC by functional minerals.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 춘계학술발표회 논문집
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• pp.330-330
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• 2012

Microstructure of a marine steel with a modified AISI-1004 composition was controlled by cold rolling and heat treatment, which corrosion behavior in an artificial sea water was electrochemically determined for the each deformation direction. The lowest corrosion rate of the surface normal to the rolling direction is related t the (111) fiber structure. Additional annealing at $550^{\circ}C$ for 24 hours improves the corrosion rate which is related to re-crystallization and reduction of (111) concentration.

• 한국재료학회지
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• 제34권2호
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• pp.79-84
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• 2024

Thin films of yttria-stabilized zirconia (YSZ) nanoparticles were prepared using a low-temperature deposition and crystallization process involving successive ionic layer adsorption and reaction (SILAR) or SILAR-Air spray Plus (SILAR-A+) methods, coupled with hydrothermal (175 ℃) and furnace (500 ℃) post-annealing. The annealed YSZ films resulted in crystalline products, and their phases of monoclinic, tetragonal, and cubic were categorized through X-ray diffraction analysis. The morphologies of the as-prepared films, fabricated by SILAR and SILAR-A+ processes, including hydrothermal dehydration and annealing, were characterized by the degree of surface cracking using scanning electron microscopy images. Additionally, the thicknesses of the YSZ thin films were compared by removing diffusion layers such as spectator anions and water accumulated during the air spray plus process. Crack-free YSZ thin films were successfully fabricated on glass substrates using the SILAR-A+ method, followed by hydrothermal and furnace annealing, making them suitable for application in solid oxide fuel cells.

• ETRI Journal
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• 제26권3호
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• pp.252-256
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• 2004

We formed silver nanocrystallites by the thermal decomposition of a $Ag^{+1}$-oleate complex, which was prepared by a reaction with $AgNO_{3}$ and sodium oleate in a water solution. The resulting monodispersed silver nanocrystallites were produced by controlling the temperature (290$^{\circ}$C). Transmission electron microscopic (TEM) images of the particles showed a 2-dimensional assembly of the particles with a diameter of $9.5{\pm}0.7nm$, demonstrating the uniformity of these nanocrystallites. An energy-dispersive X-ray (EDX) spectrum and X-ray diffraction (XRD) peaks of the nanocrystallites showed the highly crystalline nature of the silver structure. We analyzed the decomposition of the $Ag^{+1}$-oleate complex using a Thermo Gravimetric Analyzer (TGA) and observed the crystallization process using XRD.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1663-1666
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• 2003

TMA clathrate that is used by PCM of ice storage system in this research creates hydrate crystallization at higher temperature than pure water, and application is expected as PCM because having comparative big dormant temperature without phase separation phenomenon. In case this research uses TMA clathrate by PCM, choose admixture by purpose to control or remove subcooling of TMA clathrate and evaluated experimentally. Subcooling is improved and can expect contraction of freezing machine running time and increase of coefficient of performance as that add admixture to TMA clathrate conclusively. Also, may supply thermal storage system that apply low temperature potential heat thermal storage material that subcooling is improved more extensively laying stress on medium size building and small size building, can expect allowance through localization of ice storage system.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 1999년도 추계 기술심포지움 논문집
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• pp.111-115
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• 1999

The $Li_2O-MgO-MgF_2-SiO_2$glasses with addition of $B_2O_3$ were investigated in order to make glass-ceramics for low temperature firing substrate. Glasses were made by melting at $1450^{\circ}C$ in the electronic furnace and crystallized at $750^{\circ}C$. After the crystallization, crystal phases and microstructure were observed. The crystal phases were polycrystalline of lithium boron fluorphlogopite and lithium fluorhectorite. The crystal shape was changed to grande type from needle type with the increase in $B_2O_3$ contents. Average particle size of the glass-ceramics aftar water swelling was $3.77{\mu}{\textrm}{m}$. The optimum sintering temperature and sintering shrinkage of the substrate were $900^{\circ}C$ and 13.4vol%, respectively.

• Journal of Magnetics
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• 제6권1호
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• pp.1-4
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• 2001

We have used acetic acids ethanol and distilled water as a solvent to synthesize $La_{2/3}Sr_{1/3}Mn_{0.99}{^{57}}Fe_{0.01}O_3$(LSMFO) precursor. Crack-free LSMFO granular polycrystalline thin films have been deposited on thermally oxidized silicon substrates by spin coaling. The dependence of crystallization, surface morphology, magnetic and transport properties on annealing temperature was investigated. With increasing annealing temperature, the metal-semiconductor (insulator) transition temperature and the magnetic moment decrease while the resistivity increases. The lattice constants remain almost unchanged. For LSMFO thin films, spin-dependent interfacial tunneling and/or scattering magnetoresistance were observed. Our results indicate that the annealing temperature is very important in determining the intrinsic and extrinsic magnetotransport properties.