• Title/Summary/Keyword: water in glass

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Preparation of Porous Glass-Ceramics by the Sintering (소결법에 의한 다공질 결정화유리의 제조)

  • 박용완;이준영
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1218-1230
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    • 1994
  • In manufacturing process of porous glass-ceramics by the filler method, the sintering behaviour of crystallizable glass powder mixed with various salts was studied and also the effects of precipitated crystal phases on the properties of porous glass-ceramics were investigated. Fine-grained crystallizable glass powder was homogeneously mixed with various slat having grain size 100~200 ${\mu}{\textrm}{m}$ and sintered for densification. After washing out the inorganic salt with distilled water, the porous sintered body was heat treated additionly for crystallization. The MgO-Al2O3-SiO2 base glass was used as crystallizable glass powder and the water soluble salts such as K2SO4 and MgSO4 were used as filler. When K2SO4 was used, leucite crystal phase was formed as a result of the ion exchange and porous glass-ceramics which exhibit high temperature resistance and high thermal expansion coefficient of 17$\times$10-6/$^{\circ}C$ could be obtained. On the contrary, when MgSO4 was used, only slight ion exchange is observed and $\mu$-cordierite and $\alpha$-cordierite crystal phases were formed and porous glass-ceramics which exhibit low thermal expansion coefficient schedule were determined with the results of DTA curves, thermal shrinkage curves and XRD patterns analysis. From DTA curves and thermal shrinkage curves, it was found that the sintering densification have been completed at the temperature range of exothermic peak for crystallization. The pore size distributions and pore diameters were measured by mercury porosimeter. The pore diameter of porous glass-ceramics was 10~15 ${\mu}{\textrm}{m}$ when 100~200${\mu}{\textrm}{m}$ grain size of K2SO4 was used and it was 25~30 ${\mu}{\textrm}{m}$ when the same grain size of MgSO4 was used. The porous glass-ceramics K2SO4 used shows bimodal pore size distribution and its porous skeleton structure was ascertained by SEM observation.

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Prevention of Exit Crack in Mirco-drilling of Soda-lime Glass (유리의 미세구멍 가공시 출구 크랙 발생 방지)

  • 박병진;최영준;주종남
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1052-1055
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    • 2001
  • In micro-drilling of brittle materials including glass, cracks occur at the exit surface. In drilling glass, the main type of crack is cone crack. Cone crack is generated by thrust force acting at the bottom surface of the workpiece. Cone crack size could be reduced by changing cutting conditions, but cone crack still existed. Two methods were proposed to prevent crack formation and perfect hole shapes were obtained. One method is attaching two glass plates with water and the other method is constraining two glass plates. The proposed methods eliminated tensile stress acting on the exit surface of glass and prevented crack propagation.

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A Study on the Hardening Characteristics of Ground Injection Grout under Various Curing Conditions (다양한 양생조건에서 지반주입 그라우트의 경화특성에 대한 연구)

  • Heo, Hyungseok;Park, Innjoon
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.11
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    • pp.11-20
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    • 2020
  • For water barrier and reinforcing grout in soft ground, the verification of durability was conducted over the initial and long-term ages under various curing conditions. The grout was made of water glass system, fast-hardening mineral (FHM) system, and acrylic polymer system. There were three types of curing conditions that were tab water curing, artificial seawater curing, and atmospheric curing. And the various tests were performed for each sample by age, uniaxial compressive strength, length change, and weight change. As artificial seawater, MgCl2 and MgSO4 aqueous solutions were prepared and used, respectively. As the test results, the fast-hardening mineral system and acrylic polymer system were cured stably without significant change in durability in tap water and artificial sea water, whereas water glass system showed a very rapid drop in durability under artificial sea water conditions compared to tap water. In atmospheric curing conditions, durability is lowered compared to water curing in all cases, and in particular, the weight loss in the FHM system and water glass system is about 62% and 60%, respectively, resulting in a significant decrease in durability.

Chemical Durability of Simulated Waste Glasses (모의 폐기물유리의 화학적 내구성)

  • 현상훈;송원선
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.521-531
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    • 1989
  • The dependence of the chemical durability of simulated waste glasses containing the simplified waste similar to the SRP waste on compositions of host glasses, amounts of waste loading, and kinds of leachants has been investigated as a basic study on the waste immobilization through vitrification. The maximum limit of the amount of waste loading for glassforming with the host sodium borosilicate glasses selected in this study was 50wt%. The chemical durability of waste glasses whose host glass belonged to the immiscible composition region was much higher than that of waste glasses whose host glass belonged to the miscible composition region. The former waste glass showed lower chemical durability in deionized and silicate waters than in brine, while the latter glass showed the lowest chemical durability in deionized and silicate waters than in brine, while the latter glass showed the lowest chemical durability in silicate water. It was also observed that the total leaching rates in brine were noticeably small in comparison with those in other solutions. The composition of the host borosilicate glass which was suitable for the treatment of the waste through vitrification was found to be 25 Na2O-5B2O3-70SiO2(wt.%).

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The Performance Simulation of All-Glass Vacuum Tubes with Coaxial Fluid Conduit (등축 유로를 가진 이중진공관형 태양열 집열기의 열성능에 관한 시뮬레이션 연구)

  • Lee, Sang-Jin;Hyun, Myung-Taek;Park, Youn-Cheol;Chun, Won-Gee;Lee, Jung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.24 no.3
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    • pp.27-38
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    • 2004
  • A numerical investigation has been carried out for a solar system, which consists of all glass solar vacuum tubes Water is heated as it flows through the coaxial fluid conduit inserted in each tube. The space between the exterior of the fluid conduit and the glass tube is filled with antifreeze solution. This is to facilitate heat transfer from the solar heated absorber surface to water and to prevent the functional problems due to freezing in frigid weather conditions. A one-dimensional steady state model is fully described which will be used to develop three-dimensional model using STAR-CD. These models could be used efficiently in designing all-glass solar collector tubes with different geometrical parameters other than those considered in the present analysis. Results show good agreement when compared with other experimental data demonstrating the reliability of the present model.

Durability of Fiber Reinforced Composites under Salt Water Environments (염수환경을 고려한 섬유강화 복합재의 내구성 평가)

  • Yoon Sung-Ho;Hwang Young-Eun
    • Proceedings of the KSR Conference
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    • 2005.05a
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    • pp.391-396
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    • 2005
  • Salt water spray test and salt water immersion test were experimentally conducted in order to investigate the durability of fiber reinforced composites under salt water environment. The specimens were made of glass fabric reinforcement and phenolic resin. Mechanical test was performed to obtain mechanical properties such as tensile properties, flexural properties, and shear properties by varying with exposure times. Also dynamic mechanical test and FTIR were conducted to investigate a change in chemical structure as well as thermal analysis properties such as storage shear modulus, loss shear moduls, and tan ${\delta}$. According to the results, salt water environment has effected on mechanical properties and thermal analysis properties and especially the durability of glass fabric/phenolic composites were severely affected on salt water immersion environment rather than salt water spray environment.

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Improvement of Transmittance and Surface Integrity of Glass Mold for light-hardening polymer Using MR Polishing (HR polishing에 의한 광경화성수지 성형용 글래스 몰드의 투과율 및 표면품위 향상)

  • Lee, J.W.;Kim, D.W.;Cho, M.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.78-83
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    • 2009
  • In general, Light-hardening polymer was used UV nanoimprint technology. A light-hardening polymer was had the problem of poor hardness, durability. In order to overcome the problem of polymer, inter change optical glass. However glass is very manufacture and a lowering of standars transmittance. In order to glass recover was necessary polishing process. The process is magnetorheological fluids polishing. MR polishing has been developed as a new precision finishing technique to obtain a fine surface. Hence, Magnetorheological fluids has been used for micro polishing to get micro parts. This polishing process guarantees high polishing quality by controlling the fluid density electrically. The applied material in experiments is fused silica glass. Fused silica glass is widely used in the optical field because of high degree of purity. For MR polishing experiments, MR fluid was composed with DI-water, carbonyl iron and nano slurry ceria. The wheel speed and electric current were chosen as the variables for analyzing the characteristics of MR polishing process. Outstanding surface roughness of Ra=1.58nm was obtained on the fused silica glass specimen. And originally glass transmittance was recover on the fused silica glass.

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Glass Inclusions in Quartz Phenocrysts of Tuff from Sunshin Au Mining Area, Haenam, Jeonnam. (전남 해남의 순신 금광산 지역에 산출하는 응회질암에 포획된 유리포유물)

  • Lee, Seung-Yeol;Yang, Kyoung-Hee;Jeon, Byung-Geun;Bak, Gil;Koh, Sang-Mo;Seo, Jeong-Ryul
    • The Journal of the Petrological Society of Korea
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    • v.18 no.4
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    • pp.337-348
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    • 2009
  • Clear and homogeneous glass inclusions are well preserved at the rim of the quartz phenocrysts of tuff from Sunshin epithermal Au deposit, Haenam, although the host rocks experienced extensive silicification and argillic alteration. Glass inclusion vary in size from $5\;{\mu}m$ to larger than $200\;{\mu}m$ consisting of glass(60~80 vol%) + vapor bubble(15~30 vol%) $\pm$ daughter crystals(<10 vol%). Most of glass inclusions are cubic to rectangular in shape, indicating that the host quartz grew in the stability field of $\beta$-quartz. All the glass inclusions appear to be primary. Glass inclusions are composed of highly evolved high-K calc-alkaline rhyolites, which can represent the final liquidus phase of the magma system. The $Au_2O_3$ concentration (<0.30 wt%) is trivial in the glass, indicating there was no enrichment in the final residual melt. Textural characteristics suggest that magma was water-saturated shortly before or during the eruption. $H_2O$ content of the glass (ca. 2-4 wt%) suggests a water saturation pressure($P_{H2O}$) of about 300-900 bars. This pressure implies a minimum depth of 0.8-2.5 km for the magma chamber.

Reduction of Height of Taylor Cone Caused by Water Surface Discharge and Its Ozone Generation Characteristics (수표면방전의 방전 수돌기의 높이제한과 오존발생특성)

  • Park, Seung-Lok;Kim, Jin-Gyu;Kim, Ju-Yong;Lee, Dae-Hee;Moon, Jae-Duk
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.7
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    • pp.334-339
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    • 2001
  • A silent type ozone generator using water surface has been studied and improved its ozone generation characteristics by the controlling the height of Taylor cone by installing a mesh electrode, a dielectric bed of glass beads in the just under th surface of the water. The current-voltage characteristics and characteristics of ozone generation quantity of the test system were investigated and discharge current oscillograms of the each cases of the mesh electrode and the beds were observed and compared each other to analyze the discharge conditions. The Taylor cone height could be the cause of the discharge bridge to decrease the ozone generation on the discharge spacing. In this study, the hight of Taylor cone could be reduced greatly by installing the mesh and the glass beads bed just under the water surface. Therefore a higher ozone generation also could be obtained.

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Electroless Deposition and Surface-Enhanced Raman Scattering Application of Palladium Thin Films on Glass Substrates

  • Shin, Kuan Soo;Cho, Young Kwan;Kim, Kyung Lock;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.743-748
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    • 2014
  • In this work, we describe a very simple electroless deposition method to prepare moderate-SERS-active nanostructured Pd films deposited on the glass substrates. To the best of our knowledge, this is the first report on the one-pot electroless method to deposit Pd nanostructures on the glass substrates. This method only requires the incubation of negatively charged glass substrates in ethanol-water mixture solutions of $Pd(NO_3)_2$ and butylamine at elevated temperatures. Pd films are then formed exclusively and evenly on glass substrates. Due to the aggregated structures of Pd, the SERS spectra of benzenethiol and organic isonitrile could be clearly identified using the Pd-coated glass as a SERS substrate. This one-step fabrication method of Pd thin film on glass is cost-effective and suitable for the mass production.