• Title/Summary/Keyword: water hardness

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A Novel Method for Calcium Hardness Control of Closed OCC Recycling System

  • Ow, Say-Kyoun;Shin, Jong-Ho;Song, Bong-Keun;Ryu, Jeong-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.164-171
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    • 1999
  • A new technique for recycling process water was developed in order to reduce the calcium hardness of the closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by a reaction with sodium carbonate and the CaCO$_3$precipitates were easily removed from the system by a dissolved air flotation(DAF) method. After the DAF stage, CO$_2$-gas was purged into the water because the pH of Na$_2$CO$_3$-treated white water was reduced to neutral by CO$_2$gas. Since CaCO$_3$precipitate tends to stick onto the fine fiber surface and then is selectively removed from the water, a proper amount of suspended solid in the process water acts as an important factor in deciding the removal efficiency. By the application of Na$_2$CO$_3$addition - DAF - CO$_2$purging to the short circulated white water the calcium hardness was significantly reduced by 92% and more. The removal of calcium ions with fine fibers led to drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

Study of Hardness Effects of Water in Alcohol Fermentation to Focus Effect of Ozone (물의 경도가 알코올발효에 미치는 영향 연구 -오존의 영향을 중심으로-)

  • 박영규
    • KSBB Journal
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    • v.19 no.2
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    • pp.98-103
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    • 2004
  • The aim of the present study was to investigate how the hardness of groundwater affects in the alcohol fermentation. Ozone plays an important role to enhance the water quality, resulting in 85% reduction of hardness, and 30% increase in total glucose produced due to increased conductivity and biodegradability of water. After all, experiments using ozone are presented for the improvement of alcohol productivity. Although initially increased slightly alcohol production, higher than expected ethanol production was observed, with ozone treatment resulting in 20% higher production.

Dynamics of Hexavalent Chromium in Four Types of Aquaculture Ponds and Its Effects on the Morphology and Behavior of Cultured Clarias gariepinus (Burchell 1822)

  • Mustapha, Moshood Keke
    • Toxicological Research
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    • v.33 no.2
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    • pp.119-124
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    • 2017
  • Hexavalent chromium is a bio accumulative toxic metal in water and fish. It enters aquaculture ponds mainly through anthropogenic sources. Hexavalent chromium concentrations and its effects on the morphology and behavior of Clarias gariepinus were investigated from four aquaculture ponds for 12 weeks. Chromium was measured using diphenyl carbohdrazide method; alkalinity and hardness were measured using colometric method and analyzed with Bench Photometer. Temperature and pH were measured using pH/EC/TDS/Temp combined tester. Temporal and spatial replications of samples were done with triplicates morphological and behavioural effects of the metal on fish were observed visually. Chromium ranged from no detection to 0.05 mg/L, alkalinity 105 to 245 mg/L, hardness 80 to 165 mg/L, pH 6.35 to 8.03 and temperature 29.1 to $35.9^{\circ}C$. Trend in the chromium concentrations in the ponds is natural > earthen > concrete > collapsible. There was a significant difference (P < 0.05) in chromium, alkalinity, water hardness, pH and temperature among the four ponds. Significant positive correlation also existed between alkalinity, water hardness, pH, with chromium. Morphological and behavioural changes observed in the fish include irregular swimming, frequent coming to the surface, dark body colouration, mucous secretion on the body, erosion of gill epithelium, fin disintegration, abdominal distension and lethargy. High chromium concentration in natural pond was due to anthropogenic run-off of materials in to the pond. Acidic pH, low alkalinity, low water hardness also contributed to the high chromium concentration. Morphological and behavioural changes observed were attributed to the high concentrations, toxicity and bio accumulative effect of the metal. Toxicity of chromium to fish in aquaculture could threaten food security. Watershed best management practices and remediation could be adopted to reduce the effects of toxicity of chromium on pond water quality, fish flesh quality and fish welfare.

Changes in Absorbency and Drying Speed of a Quick-drying Knit Fabric by Repeated Laundering

  • Roh, Eui-Kyung;Kim, Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.12
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    • pp.2062-2072
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    • 2010
  • This research evaluates the change of the water absorbency and drying speed of a quick-drying knit fabric by repeated laundering and laundering conditions and investigates the influence of laundering conditions on the functional properties of the knit fabric. Four factors of laundering conditions were studied: detergent, water hardness, water temperature, and frequency of rotation. Knit fabrics were washed for 25 laundering cycles in a drum-type washing machine with nine different laundering conditions derived from an orthogonal array. The properties of knit fabrics were measured with a drop absorption test, a strip test, and a drying time test. Relaxation shrinkage pointed to a change in the structural characteristics of the knit fabric. Wetting time was faster and wickability was greater in the knit fabrics that underwent 5 laundering cycles; in addition, there were no obvious changes in wetting time and wickability. The detergent was the most important factor in wetting time (40.4%) and wickability (60% or above). Water hardness, water temperature and RPM had less of an effect on wetting time and wickability. There were no significant differences between the levels of laundering conditions (except for detergent) on wetting time and wickability. Drying times with neutral and alkali were slower by repeated laundering; however, there was no obvious change in drying time. Hardness, water temperature and RPM had less of an impact on drying time.

Assessment of Groundwater Quality for Irrigation and Agro-based Industrial Usage in Selected Aquifers of Bangladesh

  • Rahman, Md. Mokhlesur;Hoque, Syed Munerul;Jesmin, Sabina;Rahman, Md. Siddiqur;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.24 no.2
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    • pp.98-105
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    • 2005
  • Groundwater sampled from 24 tube wells of three districts namely Sherpur, Gaibandha and Naogaon in Bangladesh was appraised for their water quality for irrigation and agro-based industrial usage. All waters under test were slightly alkaline to alkaline (pH = 7.2 to 8.4) in nature and were not problematic for crop production. As total dissolved solid (TDS), all groundwater samples were classified as fresh water (TDS<1,000 mg/L) in quality. Electrical conductivity (EC) and sodium adsorption ratio (SAR) values reflected that waters under test were under medium salinity (C2), high salinity (C3) and also low alkalinity (S1) hazard classes expressed as C2S1 and C3S1. As regards to EC and soluble sodium percentage (SSP), groundwater samples were graded as good and permissible in category based on soil properties and crop growth. All water samples were free from residual sodium carbonate (RSC) and belonged to suitable in category. Water samples were under soft moderately hard, hard and very hard classes. Manganese, bicarbonate and nitrate ions were considered as major pollutants in some water samples and might pose threat in soil ecosystem for long-term irrigation. For most of the agro-based industrial usage, Fe and Cl were considered as troublesome ions. On the basis of TDS and hardness, groundwater samples were not suitable for specific industry. Some water samples were found suitable for specific industry but none of these waters were suitable for all industries. The relationship between water quality parameters and major ions was established. The correlation between major ionic constituents like Ca, Mg, K, Na, $HCO_3$ and Cl differed significantly. Dominant synergistic relationships were observed between EC-TDS, SAR-SSP, EC-Hardness, TDS-Hardness and RSC-Hardness.

A Study for Characteristics of Geofiber Reinforced Soil System Practiced on Stone Gabion Bank of River (하천 돌망태 호안에 적용된 토목섬유보강토공법의 녹화 특성)

  • Jeong, Dae-Young;Kim, Jae-Hwan;Shim, Sang-Ryul
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.6
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    • pp.81-90
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    • 2008
  • Recently, geofiber(polyester) reinforced soil was added on soil-seed mixture spray to control erosion and to improve vegetation growth on rocky slope sites. This research was conducted to compare vegetation effects and soil hardness on three types of soil-seed mixture spray on stone gabion river bank [A type : soil-seed mixture spray underlying 30cm thick sand with geofiber(geofiber reinforced soil system), B type : soil-seed mixture spray underlying 30cm thick sand without geofiber, C type : soil-seed mixture spray]. Evaluation were made concerning vegetation coverage, soil hardness and moisture content. The results of this study showed that A type system was effective for the growth of vegetation and soil hardness when compareed to B type and C type. A type and B type showed higher covering rate than C type on stone gabion river bank, and especially A type showed the highest covering rate. Soil hardness and water content were high on A type vegetation system compared to B type and C type. We noted that high soil hardness and high moisture content with geofiber(geofiber reinforced soil system) were effective both to control erosion from water current impact and to be high coverage and species of vegetation on stone gabion river bank.

Microstructure and Mechanical Properties of Co-Cr-Mo alloy for CAD/CAM Applications fabricated by Powder Metallurgy Process (분말야금공법으로 제조된 CAD/CAM용 Co-Cr-Mo 합금의 미세조직 및 기계적 특성)

  • Cha, Sung-Soo
    • Journal of Technologic Dentistry
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    • v.37 no.4
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    • pp.235-242
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    • 2015
  • Purpose: The aims of this study are compare with microstructure and mechanical properties of Co-Cr-Mo alloys fabricated by powder metallurgy(P/M) process and casting process respectively. Methods: Microstructure and micro-hardness were tested by SEM and Vickers Hardness Tester. The sintered specimen was produced by furnace-coolling after sintering, however the casting specimen were produced thru air-cooling and water-cooling after the casting. For observation of phase transformation during sintering, DSC analyzing was carried out. Results: Mean pore size of sintered Co-Cr-Mo alloy was $4.32{\mu}m$ and that of casting alloy was $1.63{\mu}m$. Hardness of sintered alloy was lower than water-quenched casting alloy. Conclusion: Proper sintering temperature of Co-Cr-Mo alloy was above $1,200^{\circ}C$ and pore size of casting specimen were finer than sintered specimen, but hardness were similar.

울산지역의 지하수 수질에 관한 통계학적 연구

  • 양운진
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.461-466
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    • 1998
  • One hundred and thirty two ground water samples from the Usan area were divided into urban and non-urban groupings and were assessed between 1993 and 1996. The results of statistical analysis were as follows: There were significant differences between the two groupings in the average value of the following water quality parameters: total hardness, nitrate , pH, iron, ammonia and chloride ion in the order of Z-score . Because total hardness, nitrate, and pH were also significant in ANOVA test, these three parameters can be regarded as the most sensitive parameters of artirial pollutants. By the comprehensive com- parison of Ulsan water Quality to that of Kangwon-do, all of the major parameters(pH, KMnO4 consumption, sulfate, chloride and hardness except nitrated were confirmed as being significantly Increased levels.

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EFFECTS OF SUBSTRATE TEMPERATURE ON PROPERTIES OF FLUORINE CONTAINED SILICON OXIDE FILMS PREPARED BY MICROWAVE PLASMA- ENHANCED CVD

  • Sugimoto, Nobuhisa;Hozumi, Atsushi;Takai, Osamu
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.577-584
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    • 1996
  • Silicon oxide films with high hardness and water repellency were prepared by microwave plasma-enhanced CVD using four kind of organosilicon compound-fluoro-alkyl silane mixtures as source gases. An argon gas was used as a carrier gas for fluoro-alkyl silane. The substrate temperatures during deposition were controlled by resistant heating at a constant value between 50 and $300^{\circ}C$. The hardness of the films increased, but the deposition rate and the contact angle for a water drop decreased with increasing substrate temperature. The number of methoxy groups also affected the water repellency and hardness. The deposited films became more inorganic with increasing substrate temperature because of the thermal dissociation of reactants.

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Hardness Correction Algorithm Applicable to Korea as Related to Aquatic Toxicity Variation for Heavy Metals (국내 적용가능한 중금속 수서독성에 대한 경도보정 알고리즘 연구)

  • An, Youn-Joo;Yang, Chang-Yong;Nam, Sun-Hwa
    • Korean Journal of Ecology and Environment
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    • v.41 no.3
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    • pp.275-282
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    • 2008
  • Water hardness is a significant parameter as related to aquatic toxicity of some heavy metals. Hardness dependent metals include cadmium, copper, chromium (III), nickel, lead, zinc and silver. Developed countries have applied the hardness correction procedure to derive the water quality criteria for protecting the aquatic organisms. In the present study, we investigated the hardness correction algorithms used in United States of America, European Union, Australia/New Zealand, and Canada, and analyzed the details associated with those algorithms. Toxicity values of heavy metals were definitely different after hardness correction for all of algorithms analyzed. We found that the hardness corrected toxicity values followed by the algorithms of USA and Australia/New Zealand were very similar or same, however they were slightly different for cadmium at the hardness less than 30 mg $CaCO_3\;L^{-1}$. Among the hardness correction algorithms studied, the algorithm used in Australia/New Zealand appears to be a good choice to apply in Korean situation due to its simplicity compared to the algorithm of USA.