• Corrosion Science and Technology
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• v.6 no.2
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• pp.50-55
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• 2007

The smaller size and higher integration of advanced electronic package systems result in severe electrochemical reliability issues in microelectronic packaging due to higher electric field under high temperature and humidity conditions. Under these harsh conditions, electronic components respond to applied voltages by electrochemical ionization of metal and the formation of a filament, which leads to short-circuit failure of an electronic component, which is termed electrochemical migration. This work aims to evaluate electrochemical migration susceptibility of the pure Sn, Sn-3.5Ag, Sn-3.0Ag-0.5Cu solder alloys in $Na_{2}SO_{4}$. The water drop test was performed to understand the failure mechanism in a pad patterned solder alloy. The polarization test and anodic dissolution test were performed, and ionic species and concentration were analyzed. Ag and Cu additions increased the time to failure of Pb-free solder in 0.001 wt% $Na_{2}SO_{4}$ solution at room temperature and the dendrite was mainly composed of Sn regardless of the solders. In the case of SnAg solders, when Ag and Cu added to the solders, Ag and Cu improved the passivation behavior and pitting corrosion resistance and formed inert intermetallic compounds and thus the dissolution of Ag and Cu was suppressed; only Sn was dissolved. If ionic species is mainly Sn ion, dissolution content than cathodic deposition efficiency will affect the composition of the dendrite. Therefore, Ag and Cu additions improve the electrochemical migration resistance of SnAg and SnAgCu solders.

• Proceedings of KOSOMES biannual meeting
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• 2005.05a
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• pp.161-165
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• 2005

Recently, it is on the increase interest for Al alloy with new material for ship application to substitute for FRP ship. The reason is thatAl alloy ship has beneficial characteristics such as high sea speed, increase of loadage and easy to recycle compared with FRP ship. In this paper, mechanical and electrochemical properties are investigated by slow strain rate test experiment in various applied potential condition. These results will provide as reference data to design ship by deciding optimum protection potential regard to hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys are not corroded with forming film which has the corrosion resistance property in neutral solution. However, it was observed that formation and destruction of passive film by $Cl^-$ ion in sea water environment. At comparison of current density after 1200 sec in potentiostatic experiment, the current density in the potential range of -0.68 $\~$-1.5 V is shown low value. The low current density means protection potential range. Elongation in applied potential of 0 V was high. However, the corrosion protection application in this condition is impossible potential because the toughness is low value by decreasing strength by active dissolution reaction at parallel part of specimen. The film composed with $CaCO_3$ and $Mg(OH)_2$ has a corrosion resistance property. However, the uniform electrodeposition coating at below -1.6 V potential is not formed since the time to form the uniform electrodeposition coating is short. Therefore, it is concluded that mechanical property is poor because effect by hydrogen gas generation is larger than that of electrodeposition coating. It is concluded that the optimum protection potential range from comparison of_maxim urn tensile strength, elongation and time to fracture is -1.3$\~$0.7 V (SSCE).

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2015.05a
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• pp.32-32
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• 2015

Electrophoretic paint (E-paint) was investigated on four different magnesium substrates: as-extruded AZ61 (AZ61), heat-treated AZ61 (AZ61-H), as-extruded TZ61 (TZ61) and heat-treated TZ61 (TZ61-H), to elucidate the effect of heat treatment and alloying elements on the deposition and corrosion resistance of E-paint. It was found that, a rapid increase of voltage, indicating that the deposition of E-paint had started, was observed after an induction time of 0.39 min for AZ61-H, 0.43 min for AZ61, 0.51 min for TZ61-H and 0.58 min for TZ61. The amount of E-paint deposited on the four samples was approximately similar, but the electrical charge used for the deposition process on the heat-treated samples was smaller than that on the as-extruded samples. The current efficiencies of E-paint on AZ samples (AZ61 and AZ61-H) were higher than those of TZ samples (TZ61 and TZ61-H), and on the heat-treated samples were higher than on as-extruded samples. All E-paintings on the four magnesium substrates had an excellent adhesion without any paint detached by tape peel-test. However, many large blisters were formed on the surface of AZ samples, and none, or very small blisters were observed on TZ samples after immersion test in DI-water for 500 h at $40^{\circ}C$. Under salt spray test (SST) conditions, E-paint on AZ samples showed blistering adjacent to scribes, while blistering of E-paint occurred on intact areas of TZ samples. The E-paint on heat-treated samples showed much better corrosion resistance than that on as-extruded samples. The ranking of greater to lesser corrosion resistance of the E-paint on these four different magnesium substrates is indicated by the order: AZ61-H > AZ61 > TZ61-H > TZ61.

• Corrosion Science and Technology
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• v.20 no.4
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• pp.210-229
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• 2021

To safely operate domestic nuclear power plants approaching the end of their design life, the material degradation management strategy of the components is important. Among studies conducted to improve the soundness of nuclear reactor components, research methods for understanding the degradation of reactor internals and preparing management strategies were surveyed. Since the IGSCC (Intergranular Stress Corrosion Cracking) initiation and propagation process is associated with metal dissolution at the crack tip, crack initiation sensitivity was decreased in the hydrogenated water with decreased crack sensitivity but occurrence of small surface cracks increased. A stress of 50 to 55% of the yield strength of the irradiated materials was required to cause IASCC (Irradiation Assisted Stress Corrosion Cracking) failure at the end of the reactor operating life. In the threshold-stress analysis, IASCC cracks were not expected to occur until the end of life at a stress of less than 62% of the investigated yield strength, and the IASCC critical dose was determined to be 4 dpa (Displacement Per Atom). The stainless steel surface oxide was composed of an internal Cr-rich spinel oxide and an external Fe and Ni-rich oxide, regardless of the dose and applied strain level.

• Computers and Concrete
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• v.32 no.2
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• pp.119-138
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• 2023

Concrete carbonation is a prevalent phenomenon that leads to steel reinforcement corrosion in reinforced concrete (RC) structures, thereby decreasing their service life as well as durability. The process of carbonation results in a lower pH level of concrete, resulting in an acidic environment with a pH value below 12. This acidic environment initiates and accelerates the corrosion of steel reinforcement in concrete, rendering it more susceptible to damage and ultimately weakening the overall structural integrity of the RC system. Lower pH values might cause damage to the protective coating of steel, also known as the passive film, thus speeding up the process of corrosion. It is essential to estimate the carbonation factor to reduce the deterioration in concrete structures. A lot of work has gone into developing a carbonation model that is precise and efficient that takes both internal and external factors into account. This study presents an ML-based adaptive-neuro fuzzy inference system (ANFIS) approach to predict the carbonation depth of fly ash (FA)-based concrete structures. Cement content, FA, water-cement ratio, relative humidity, duration, and CO2 level have been used as input parameters to develop the ANFIS model. Six performance indices have been used for finding the accuracy of the developed model and two analytical models. The outcome of the ANFIS model has also been compared with the other models used in this study. The prediction results show that the ANFIS model outperforms analytical models with R-value, MAE, RMSE, and Nash-Sutcliffe efficiency index values of 0.9951, 0.7255 mm, 1.2346 mm, and 0.9957, respectively. Surface plots and sensitivity analysis have also been performed to identify the repercussion of individual features on the carbonation depth of FA-based concrete structures. The developed ANFIS-based model is simple, easy to use, and cost-effective with good accuracy as compared to existing models.

• Korean Journal of Materials Research
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• v.34 no.8
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• pp.377-386
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• 2024

The surface of titanium (Ti) dental implants was modified by applying a zinc (Zn)-doped titanium dioxide (TiO₂) coating. Initially, the Ti surfaces were etched with NaOH, followed by a hydrolysis co-condensation using tetrabutyl titanate (TBT, Ti(OC₄H₉)₄) and zinc nitrate hexahydrate (Zn(NO₃)₂·6H₂O), with ammonia water (NH₃·H₂O) acting as a hydroxide anion source. The morphology and chemical composition of the Zn-doped TiO₂-coated Ti plates were characterized using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and scanning electron microscopy (SEM). Synthesis temperatures were carefully adjusted to produce anatase Zn-doped TiO₂ nanoparticles with a bipyramidal structure and approximate sizes of 100 nm. Wettability tests and cell viability assays demonstrated the biomedical potential of these modified surfaces, which showed high biocompatibility with a survival rate of over 95 % (p < 0.05) and improved wettability. Corrosion resistance tests using potentiodynamic polarization reveal that Zn-TiO₂-treated samples with an anatase crystal structure exhibited a lower corrosion current density and more noble corrosion potential compared to samples coated with a rutile structure. This method offers a scalable approach that could be adapted by the biomaterial industry to improve the functionality and longevity of various biomedical implants.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.6
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• pp.155-162
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• 2012

When RC (Reinforced Concrete) structures are exposed to sea water, steel corrosion can occur and this leads a degradation of structural performance. Referring the electro-deposition system with sea water from the 1st step research, durability and structural performance are evaluated in coated steel and RC members containing it in the 2nd research. In the durability performance test, Half Cell Potential test is performed and the coated steel is evaluated to have the high resistance to corrosion, which shows only 35% of corrosion velocity in normal (bare) steel. In the structural performance test, tensile strength, adhesive strength, and flexural/shear in RC member are performed. For the electro-deposit coated steel, increasing ratios of 3.2% and 8.8% are evaluated in the test of tensile strength and adhesive strength, respectively. For the structural test in RC member, there is no big difference between RC members with coated and non-coated steel in ultimate load and failure pattern It is evaluated that the chemical compound with $CaCO_3$ and $Mg(OH)_2$ from electro-deposition causes slightly increased structural performance. The electro-deposit coated steel can be more widely applied after performance verification from several tests like fatigue, resistance to impact, and long term-submerging test.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.4
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• pp.258-266
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• 2011

Scale induced by hardness materials in water must be controled because of it can be result in remarkable damages of pipeline as well as water quality deterioration. Especially hot water system is one of scale management required facility as scale formation can be accelerated by temperature. The scale control performance of frequency driver (FD) was tested instead of existing methods such as chemical, physical and electromagnetic methods which needs chemicals and electric power. Three kinds of pipe coupons were submerged in test water with 500 mg/L of hardness for 33 days and XRD and SEM were analysed for comparing scale formation characteristics of these coupons. Calcite ($CaCO_3$) which came from hardness of water was formed on only cast iron pipe coupon and this coupon showed higher corrosion rate than copper and stainless steel pipe coupon. Hot water circulating system connected cast iron pipe with and without FD was operated with 300 mg/L of hardness water at $50^{\circ}C$ for monitoring of scale formation and water quality with and without FD. XRD showed that FD leaded to magnetite ($Fe_3O_4$) scale which is good scale for preventing corrosion than calcite and SEM image also indicated the scale control effect of FD. Scales of 16% on pipe joint, 14% on pipe length, and 42% on heat exchanger decreased with FD comparing scales of those parts without FD. From the results of water quality, FD reduced crystallization of hardness material without chemical reaction in water and it can indicate that FD is safe and proenvironmental technology for scale reduction.

• Journal of Korean Society of Water and Wastewater
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• v.36 no.2
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• pp.107-119
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• 2022

The frequent detection and occurrence of micropollutants (MPs) in aquatic ecosystems has raised public health concerns worldwide. In this study, the behavior of 50 MPs was investigated in three different domestic wastewater treatment plants (WWTPs). Furthermore, the Kruskal-Wallis test was used to assess the geographical and seasonal variation of MPs in the WWTPs. The results showed that the concentrations of 43 MPs ranged from less than 0.1 to 237.6 ㎍ L^-1, while other seven MPs including 17-ethynylestradiol, 17-estradiol, sulfathiazole, sulfamethazine, clofibric acid, simvastatin, and lovastatin were not detected in all WWTPs. Among the detected MPs, the pharmaceuticals such as metformin, acetaminophen, naproxen, and caffeine were prominent with maximum concentrations of 133.4, 237.6, 71.5, and 107.7 ㎍ L^-1, respectively. Most perfluorinated compounds and nitrosamines were found at trace levels of 1.2 to 55.3 ng L^-1, while the concentration of corrosion inhibitors, preservatives (parabens), and endocrine disruptors ranged from less than 0.1 to 4310.8 ng L^-1. Regardless of the type of biological treatment process such as MLE, A2O, and MBR, the majority of pharmaceuticals (except lincomycin, diclofenac, iopromide, and carbamazepine), parabens (except Methyl paraben), and endocrine disruptors were removed by more than 80%. However, the removal efficiencies of certain MPs such as atrazine, DEET, perfluorinated compounds (except PFHxA), nitrosamines, and corrosion inhibitors were relatively low or their concentration even increased after treatment. The results of statistical analysis reveal that there is no significant geographical difference in the removal efficacy of MPs, but there are temporal seasonal variations in all WWTPs.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.12
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• pp.1864-1870
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• 2004

A spot welded structures have an influence on a diverse climatic situation, for instance temperature, humidity and precipitation. In addition factors of environmental pollution such as acid rain, that courses corrosion, have the tendency to increase. But spot welded structures strength is affected by humidity and environment temperature. Therefore, it is important to evaluate effect of temperature and water immersion on strength properties of spot welded part. In this study, the strength distribution of spot welded plates is evaluated the environmental temperature of zinc coated steel plates. Test is conducted with welded part immersed in distilled and synthetic sea water. Specimens are immersed into water for 10, 100, 500 and 1000 hours to evaluate the offsets of water immersion time on tensile-shear strength under the conditions of -40, 0, 20 and 5$0^{\circ}C$. From this result, spot welded specimens with 5 mm clearance have lower tensile-shear strength in the distilled water or synthetic sea water than without clearance. And they have lower tensile-shear strength under -4$0^{\circ}C$ and over 5$0^{\circ}C$.