• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1A
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• pp.75-84
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• 2009

The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.8 no.2
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• pp.33-41
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• 2012

The component cooling water heat exchangers are critical components in a nuclear power plant. As the operation years of the heat exchanger go by, the maintenance costs required for continuous operation also increase. Most heat exchangers have carbon steel shells, tube support plates and flow baffles. The titanium tube is susceptible to flow induced vibration. The damage on carbon steel tube support rod and titanium tube around cooling water entrance area is inevitable. Therefore, analysis of internal flow around the component cooling water entrance and tube channel is a good opportunity to seek for failure prevention practice and maintenance method. The numerical study was carried out by FLUENT code to find out the causes of tube failure and its location.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.390-393
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• 2007

매설관로상의 전기방식에 대한 경제성을 비교하는 자료는 미국 루지에나주에서 실제로 방식/비방식관로를 구성하고 15년간의 대이타를 기준으로 분석한 내용이 있으나, 실제 우리나라의 대부분의 수도관은 도심지지하에 가스관, 지중시설물 등 각종 설비와 함께 매설되어 메탈터치 및 간섭에 의한 집중부식구간이 우려되는 구간이 많을뿐 아니라 이종 관류에 의한 부식구간도 많아 외국의 데이터를 그대로 적용할수 없어 국내의 공신력있는 실험 데이터를 확보하여 구체적인 경제성을 검증하여 투자의 적정성을 확보하는데 이 연구의 목적이 있음

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.8
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• pp.1392-1397
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• 2008

The mechanical integrity of generator stator windings is one of the critical point because the electric power is generated and conducted to power system through these windings. De-mineralized water is used to cool stator bars during the normal operation of generator in large power plants because the water cooled method has highest cooling efficient. Water absorption of bar insulation is progressed by several causes such as generation of water leak path by corrosion, delamination of insulation by vibration, and inadequate water treatment, etc.. Reliable water absorption diagnostics of generator stator bar is important to ensure the availability of power plant and to reduce maintenance cost by generator accident. It is described that the water absorption characteristics for generator stator bar insulation used in 500MW capacity standard fossil power plant by cooling water temperature. It is verified that the management of stator cooling water temperature is one of the important factors to decrease water absorption rate of generator stator bars.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.5
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• pp.78-87
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• 2012

This study is for developing a system for electro-deposition utilizing sea water containing various ions like calcium and magnesium. This is the first step research for the final goal which is a development of anti-corrosive steel for RC structure, so that this paper is mainly focused on the development for electro-deposition system. Optimum conditions for steel coating is obtained through various tests considering anode type, temperature, duration time, and current density. The composition of electro-deposition is analyzed through SEM, EDS, and XRD and it is evaluated to be $CaCO_3$ and $Mg(OH)_2$. Through measuring polarization potential and current density in the coated steel, the coating layer from the developed system is evaluated to have high resistance to steel corrosion. Additional tests and discussions on durability and structural performance in the coated steel from this work will be performed for the second step research.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.6 no.2
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• pp.20-27
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• 2010

In order to prevent the corrosion of component contacted primary water designed alloy 600 material in the nuclear power plant. But the primary water stress corrosion cracking(PWSCC) of alloy 600 and weld area occurs continuously due to the residual stress. The leakage accident resulted from PWSCC in the drain nozzle of the steam generator of domestic power plants. Heater sleeves of the pressurizer are welded with alloy 600 weld material and therefore exposed to the primary water environment. PWSCC occurred in heater sleeve material and weld area of many foreign power plants. The current issue of domestic nuclear power plants are consequently concentrated to PWSCC of similar material. In order to improve the detection and the sizing of the PWSCC in the welding sleeve of the pressurizer, the automatic UT system and multi-directions probe sets have been developed. The experimental studies have been performed using the mock-up block containing artificial reflectors(ID connected EDM notch) and semi-artificial cracks made from thermal fatigue. The automatic UT System is applied in the detection and the length sizing of the ID/OD on the tube and the J-groove weld area of the artificial reflectors and results of the detection and the sizing are compared respectively. Also, the developed automatic UT system is successfully accomplished to inspect the heater sleeve and the J-groove weld area on the pressurizer for the detection of PWSCC.

• Journal of Hydrogen and New Energy
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• v.27 no.6
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• pp.636-641
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• 2016

Alkaline water electrolysis is commercial hydrogen production technology. It is possible to operate MW scale plant. Because It used non-precious metal for electrode. But It has relatively low current density and low efficiency. In this study, research objective is development of anode for alkaline water electrolysis with low cost, high corrosion resistance and high efficiency. Stainless steel 316L (SUS 316L) was selected for a substrate of electrode. To improve corrosion resistance of substrate, Nickel (Ni) layer was electrodeposited on SUS 316L. Ni-Fe alloy was electrodeposited on the passivated Ni layer as active catalyst for oxygen evolution reaction(OER). We optimized preparation condition of Ni-Fe alloy electrodeposition by changing current density, electrodeposition time and composition ratio of Ni-Fe electrodeposition bath. This electrodes were electrochemically evaluated by using Linear sweep voltammetry (LSV) and Cyclic voltammetry (CV). The Ni-Fe alloy (Ni : Fe = 1 : 1) showed best activity of OER. The optimized electrode decreased overpotential about 40% at $100mA/cm^2$ compared with Ni anode.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.6
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• pp.254-261
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• 2021

This study was intended to develop an inspection method to detect defects in closed-cell steel members in steel girder bridges. The ultrasonic pulse velocity method was selected as a rapid and effective method to identify thickness changes of steel specimens caused by corrsion. This study developed an algorithm to expedite the process and improve the accuracy in the prediction of steel plate thickness. Also, both static and continuous scanning methods were compared to each other to identify the difference in accuracy, but the results revealed that both methods produce almost the same results. This study also provided the idea to calculate the height of water contained in the closed-cell steel member and results of laboratory experimental results. The water heights which is thicker than the steel plate thickness were detectable and predicted using the idea suggested by this study, but the water heights lower than the steel plate thickness were not possible. However, the results showed whether the steel member contains water or not.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.3
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• pp.259-268
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• 2022

Molten salt consisting primarily of eutectic LiCl-KCl is currently being used in electrorefiners in the Fuel Conditioning Facility at Idaho National Laboratory. Options are currently being evaluated for storing this salt outside of the argon atmosphere hot cell. The hygroscopic nature of eutectic LiCl-KCl makes is susceptible to deliquescence in air followed by extreme corrosion of metallic cannisters. In this study, the effect of occluding the salt into a zeolite on water sorption/desorption was tested. Two zeolites were investigated: Na-Y and zeolite 4A. Na-Y was ineffective at occluding a high percentage of the salt at either 10 or 20wt% loading. Zeolite-4A was effective at occluding the salt with high efficiency at both loading levels. Weight gain in salt occluded zeolite-4A (SOZ) from water sorption at 20% relative humidity and 40℃ was 17wt% for 10% SOZ and 10wt% for 20% SOZ. In both cases, neither deliquescence nor corrosion occurred over a period of 31 days. After hydration, most of the water could be driven off by heating the hydrated salt occluded zeolite to 530℃. However, some HCl forms during dehydration due to salt hydrolysis. Over a wide range of temperatures (320-700℃) and ramp rates (5, 10, and 20℃ min^-1), HCl formation was no more than 0.6% of the Cl^- in the original salt.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.12
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• pp.1249-1256
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• 2005

This study was performed to investigate the efficiency of the corrosion prevention in the simulated distribution system using CCPP(Calcium Carbonate Precipitation Potential) as the anti-corrosive index by adjusting pH, total dissolved solids, alkalinity and calcium hardness in the water treatment pilot process. The materials of the simulated distribution system(SDS) were equiped with same materials of real field water distribution system. CCPP concentrations controlled by $Ca(OH)_2$, $CO_2$ gas and $Na_2CO_3$ in the simulated distribution system and uncontrolled by the chemicals in the general water distribution system were average 0.61 mg/L and -7.77 mg/L. The concentrations of heavy metals like Fe, Zn, Cu ions in effluent water of the simulated distribution system controlled with water quality were decreased rather than the general water distribution system uncontrolled with water quality. In simulated distribution system(SDS), corrosion prevention film formed by CCPP control was observed that scale was come into forming six months later and it was formed into density as time goes on. We were analyzed XRD(X-ray diffraction) for investigating component of crystal compounds and structure for galvanized steel pipe(15 mm). Finding on analysis, scale was compounded to $Zn_4CO_3(OH)_6{\cdot}H_2O$ (Zinc Carbonate Hydroxide Hydrate) after ten months late, and it was compounded on $CaCO_3$(Calcium Carbonate) and $ZnCO_3$(Smithsonite) after nineteen months later.