• 제목/요약/키워드: water corrosion

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Study on Surface Crack Propagation Behaviour of Mild Steel Weldment in Synthetic Sea Water (인공해수중에서 연강 용접부의 표면구열 성장거동)

  • 이종기;정세희
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.492-501
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    • 1990
  • It was known that the fracture incidences of offshore structure were mostly originated from the surface defects. Especially, in the case of the welded structures, since the welded region has some defects and incomplete beads which are apt to behave like the surface cracks, it has been necessary to evaluate the environmental effects on crack growth at HAZ for the design crack growth behaviour at multi-pall HAZ for SWS41 steel under free corrosion and cathodic protection(-0.9V vs Ag/Agcl) conditions. The results are summarized as follows ; (1) Crack growth rate of the as weld in air was faster than that of the parent and PWHT specimens over all .DELTA.K rang. (2) In free corrosion test, surface crack growth rate of the as welded was decreased in comparison with that of the parents. (3) In fatigue test under cathodic protection, cathodic electric potential(-0.9V vs Ag/Agcl) for the SWS41 steel parent was effective, while for the as welded ineffective. (4) There was a tendency that the exponent(m) of the Paris' equation was decreased in order of microhardness magnititude in air and under cathodic protection conditions and vise versa in free corrosion. (5) Fracture surface has dimples and ductile striations in air test, but transgranular cracks and brittle striations under cathodic protection test.

Development of chemical conversion coating process for Mg-Al alloy and its anti-corrosion property (마그네슘-알루미늄 합금의 화성처리 공정 개발과 그 내식성 평가)

  • Kim, Seong-Jong
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.265-266
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    • 2006
  • The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

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Development of Moving Alternating Magnetic Filter Using Permanent Magnet for Removal of Radioactive Corrosion Product from Nuclear Power Plant

  • M. C. Song;Kim, S. I.;Lee, K. J.
    • Nuclear Engineering and Technology
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    • v.34 no.5
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    • pp.494-501
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    • 2002
  • Radioactive Corrosion Products (CRUD) which are generated by the neutron activation of general corrosion products at the nuclear power plant are the major source of occupational radiation exposure. Most of the CRUD has a characteristic of showing strong ferrimagnetisms. Along with the new development and production of permanent magnet (rare earth magnet) which generates much stronger magnetic field than the conventional magnet, new type of magnetic filter that can separate CRUD efficiently and eventually reduce radiation exposure of personnel at nuclear power plant is suggested. This separator consists of inner and outer magnet assemblies, coolant channel and container surrounding the outer magnet assembly. The rotational motion of the inner and outer permanent magnet assemblies surrounding the coolant channel by driving motor system produces moving alternating magnetic fields in the coolant channel. The CRUD can be separated from the coolant by the moving alternating magnetic field. This study describes the results of preliminary experiment performed with the different flow rates of coolant and rotation velocities of magnet assemblies. This new magnetic filter shows better performance results of filtering the magnetite at coolant (water). How rates, rotating velocities of magnet assemblies and particle sizes turn out to be very important design parameters.

Failure Behavior of T-joint Pipe with Outer Local Wall Thinning under Internal Pressure (내압을 받는 외부 국부 감육 T-joint 배관의 파손거동)

  • Kim, Soo-Young;Nam, Ki-Woo
    • Journal of Power System Engineering
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    • v.18 no.5
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    • pp.80-87
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    • 2014
  • The pipelines are apt to erosion or corrosion because of the high-speed flow of water and steam with high temperatures or high pressures. This study was carried out a finite element analysis (FEA) and an experimental for the fracture behavior of T-joint pipes with local wall thinning under internal pressure. Local wall thinning was machined on the pipes in order to simulate erosion and corrosion of the metal. The configurations of the eroded area included an eroded ratio of d/t=0.80~0.963 and an eroded length of l=25 mm, 50 mm, and 102 mm. Three-dimensional elastic-plastic analyses were also carried out using FEA, which accurately simulates failure behaviors. In regards to the relationship between pressure and eroded, the criterion that indicates what can be used safely under operating pressure and design pressure were obtained from FEA. The FEA results were in relatively good agreement with that of the experiment.

The characteristics of leachate migration and corrosivity in municipal wastefills at seaside (해안 도시폐기물 매립지의 침출수 이동 특성 및 부식성)

  • Jang, Yeon-Su;Jeong, Ha-Ik;Kim, Jin-Man
    • Proceedings of the Korean Geotechical Society Conference
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    • 1992.12a
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    • pp.33-66
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    • 1992
  • Recently, waste landfills built on seashores have been increased because of the easy availability of broad area near the urban communities. To evaluate the performance of the marine clay landfill liner numerical contaminant transport analyses are performed by selecting the typical section of a waste landfill built on seashores and using hydraulic conductivity data obtained from the site. Also, the laboratory electrical resistivity test and the in-situ corrosion test are performed in order to analyze the influence of the soil and leachates composing the landfills on the construct ion materials. From the results of contaminant transport analyses, it is shown that the leachates can be migrated faster through narrow pervious channels than the wide homogeneous pervious tedium and the importance of good quality barriers to prevent the contaminant migration is recognized. In the laboratory electrical resistivity test all the earth materials except the cover soils saturated with distilled water have small resistivities, which shows a high potential of corrosivity of soils composing landfills. However, the degree of corrosion of specimens buried in the landfills was not so severe except the zinc and carbon steel specimens. This apparently conflict results present the necessity of the investigation of other major factors and the long term in-situ corrosion test.

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Electrochemical Characteristics of Arc Zn Thermal Spray Coating Layer in Sea Water (해수 내 아크 아연 용사코팅 층의 전기화학적 특성)

  • Park, Il-Cho;Seo, Gwang-Cheol;Lee, Gyeong-Woo;Kim, Seong-Jong
    • Journal of Surface Science and Engineering
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    • v.48 no.6
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    • pp.343-348
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    • 2015
  • In this paper, arc Zn thermal spray coating was carried out on the SS400 steel, and then various electrochemical characteristics and surface damage behavior of Zn thermal spray coating layer were analyzed. As the results, the potential of Zn thermal spray coating layer presented driving voltage above 300 mV compare to that of SS400 steel. The passivity characteristic in anodic polarization curve was not presented. It was adequate to as sacrificial anode material. In the surface damage after galvanostatic experiments, uniform corrosion tendency of Zn thermal spray coating layer was clearly observed with acceleration of the dissolution reaction. In conclusion, Zn thermal spray coating could be determined to represent the corrosion protection effect by stable sacrificial anodic cathodic protection method in seawater because it had sufficient driving voltage and uniform corrosion damage tendency for the SS400 steel.

Analysis on the Scales formed on the Heat Affected Zone of Low Carbon Steel Weld in NaCl and H2S Water Solutions (저탄소강 용접열영향부의 NaCl, H2S 수용액에서 생성되는 부식스케일 분석)

  • Kim, Min-Jung;Bae, Dong-Ho;Lee, Dong-Bok
    • Journal of Surface Science and Engineering
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    • v.43 no.4
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    • pp.205-210
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    • 2010
  • The A106 Gr B low carbon steel, which was used in the electric power plants and heavy chemical plants, was welded by multi-pass arc welding. The heat affected zone (HAZ) formed by welding was corroded in acid chloride solution, or in saturated $H_2S$ containing acid chloride solution, or in saturated $H_2S$ containing acid chloride solution under applied current. In this order of corrosion solution, the rate of corrosion increased, because $H_2S$ accelerated the iron dissolution, hydrogen evolution, and the formation of nonprotective FeS, whereas the applied current accelerated the electrochemical reaction. The scales formed in acid chloride solution consisted primarily of $Fe_3O_4$, while those formed in $H_2S$ containing acid chloride solution consisted primarily of $Fe_3O_4$ and FeS.

Reliability of Maintained Hull Girders of Two Bulk Carrier Designs Subjected to Fatigue and Corrosion

  • Soares, C.Guedes;Garbatov, Y.
    • Journal of Ship and Ocean Technology
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    • v.3 no.1
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    • pp.27-41
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    • 1999
  • The objective of the paper is to study the impact of changing the traditional hull design of bulk carriers by providing them with a double hull while keeping the same deadweight. It is demonstrated that by introducing the double hull the structural reliability is increased throughout the entire life and also the extend of the needed repair is reduced. The results are obtained with recently developed mathematical tools for the reliability assessment of ship hulls subjected to the existence of multiple cracks both in the stiffeners and in the plating and it models the crack growth process. The effect of corrosion is represented as time dependent. The long-term stress range acting on the elements is defined as a function of the local transverse pressure of the internal cargo and outside sea water combined with the stresses resulting from the longitudinal bending of the hull, which is a combined with the stresses resulting from the longitudinal bending of the hull, which is a combineation of horizontal and vertical bending moments. The effect of maintenance actions is modelled as a stochastic process. The results show that a different design of the midship section improves the structural safety and also the economy with respect to structural repair of bulk carriers.

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A study on repairing construction of Registered Cultural Properties of Jollanamdo -In consideration of material and patterns by repairing project- (전라남도 등록문화재의 수리공사에 관한 조사 연구 -수리공사에 따른 재료 및 형태 변화를 중심으로-)

  • Shin, Woong-Ju;Gill, Jong-Won
    • Journal of the Korean Institute of Rural Architecture
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    • v.12 no.4
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    • pp.1-11
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    • 2010
  • This study is a research examining reshaped pattern in the perspective of repairing parts and materials through repairing renovation of registered cultural properties constructed in modern times and results are as followings. Repairing construction of registered cultural properties of Jollanamdo according to parts is shown numerously in the order of roof, walls and windows, and mostly outworn as time passes on and leakage were the main cause of repair. Also when original shape was damaged by previous repair in the past, and this was another reason of repairing. It was surveyed that among the repairing job repair of damage occurred on the part of roofing area including water leakage, corrosion and damage of roofing material, and damage of groove channel were the most main cause of repair. Especially when roof leakage is occurred by outworn of roofing materials, this cause corrosion and damage of materials due to the damage of leakage parts and this cause repeating cycles of worse leakage again and again. Main repairing materials which deform the original shape of registered cultural properties were confirmed as copper plate used on the roof. Copper plate showing high frequency of application which replaces groove slate or cement roofing tile used on the roof before has high durability and anti-corrosion but it is considered improper material to recover original shape.

Statistical Life Prediction on IASCC of Stainless Steel for PWR Core Internals (가압형 경수로 스테인리스강 내부 구조물의 조사유기 응력부식균열에 대한 통계적 수명 예측)

  • Kim, Sung-Woo;Hwang, Seong-Sik;Lee, Yeon-Ju
    • Korean Journal of Metals and Materials
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    • v.50 no.8
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    • pp.583-589
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    • 2012
  • This work is concerned with a statistical approach to the life prediction on irradiation-assisted stress corrosion cracking (IASCC) of stainless steel (SS) for core internals of a pressurized water reactor (PWR). The previous results of the time-to-failure of IASCC measured on neutron-irradiated stainless steel components were statistically analyzed in terms of stress and irradiation. The accelerating life testing model of IASCC of cold worked Type 316 SS was established based on an inverse power model with two stress-variables, the applied stress and irradiation dose. Considering the variation of the yield strength and applied stress with the irradiation dose in the model, the remaining life of the baffle former bolt was statistically predicted during operation under complex environments of stress and irradiation.