• Title/Summary/Keyword: water corrosion

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The influence of L-arginine as an additive on the compressive strength and hydration reaction of Portland cement

  • Yildiz, Mine Kurtay;Gerengi, Husnu;Kocak, Yilmaz
    • Computers and Concrete
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    • v.29 no.4
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    • pp.237-246
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    • 2022
  • The concrete quality relies on general factors like preparation technique, uniformity of the compaction, amount and appropriateness of the additives. The current article investigates the impact of a well knows amino acid, L-arginine as an additive on water requirements, setting durations and characterization of various cement samples. Compressive strength tests of reference and L-arginine added cements at age of 2, 7 and 28 days were carried out according to TS-EN 196-1. Samples were blended by incorporating various amounts of L-arginine (25 ppm, 50 ppm and 75 ppm) in the cement water mixture which were tested with Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TG), scanning electron microscopy (SEM) and the energy-dispersive X-ray spectroscopy (EDS) on the 28th day. Results revealed that L-arginine does not affect the setting time, volume expansion of cement and water demands negatively; rather it imparts enhanced sustainability to the samples. It was determined that the highest value belonged to the 75L mortar with an increase of 2.6% compared to the reference sample when the compressive strengths of all mortars were compared on the 28th day. Besides, it has been observed that the development of calcium silicate hydrate or C-S-H gel, calcium hydroxide or CH and other hydrated products are associated with each other. L-arginine definitely has a contribution in the consumption of CH formed in the hydration process.

Development of Testing and Analysis Model for Evaluation of Absorbed Water Diffusion into Concrete (콘크리트 흡수 수분확산계수 산정을 위한 실험 및 수치해석 모델 개발)

  • Park, Dong-Cheon;Ahn, Jae-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.4
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    • pp.371-378
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    • 2011
  • Concrete is affected by various deterioration factors, such as $CO_2$ and chloride ions from the sea, which cause carbonation and salt attack on concrete. These deterioration phenomena cause steel corrosion in RC structures. Although a great deal of research has been carried out in this area thus far, it is difficult to know the point at which corrosion will occur to a reinforced bar. As the diffusion of deterioration factors depends on the water content in concrete, it is imperative to assess the condition of absorbed water content. A mass measuring method was applied to calculate the absorbed water diffusion coefficient, as well as non-linear finite element method(FEM) analysis. As a result, it was found that W/C and unit water content in concrete mixture affect the diffusion coefficient decision.

Characteristic of organic/inorganic composite formed grounding resistance lowering agents (유/무기 복합재료형 접지저감제의 특성)

  • Kim, Jang-Wook;Chung, Chul-Hee;Cho, Dae-Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.05a
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    • pp.74-80
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    • 2004
  • Among inorganic materials, it is grounding resistance lower agent of new form that use being strata style clay and makes using water soluble polymer by main material to organic substance. Water soluble polymer chains are dispertion in water because water soluble polymer reacts with water if is done and these discrete polymer chains are inserted to floor of being strata style clay with water. This material that moisture content is very excellent and rate of expansion, electrical conductivity that measure after supplies water of 300wt % as well as is excellent. Can prevent corrosion or electrolytic corrosion of grounding bar securing very environmentally, chemically and pollution of soil. When applied to general grounding rod worker $7{\sim}8$ times ground resistance reduction effect of not application.

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Modified indirect evaluation method for deterioration assessment of drinking water pipes (상수도 노후도 평가를 위한 수정 간접평가법)

  • Kwon, Hyuk Jaea
    • Journal of Korea Water Resources Association
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    • v.56 no.11
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    • pp.697-703
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    • 2023
  • In this study, a modified indirect evaluation method was developed to predict the deterioration level of water pipes. The accuracy of the modified method was verified by comparing it with the direct method. The weights of index were adjusted by reducing the weight of water quality corrosion, soil corrosion, lay depth and road type according to the importance of the existing evaluation factors and adding the weight of pipe thickness. In the results, the weight of pipe thickness was determined to be 0.1530. Comparing with the direct evaluation method, the accuracy of the modified indirect evaluation method increased by 31.03% compared to the indirect evaluation method. The modified indirect evaluation method will be able to select relatively old pipes more accurately and efficiently than the existing indirect evaluation method when prioritizing the improvement of old water pipes.

Observation of Water Consumption in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.10 no.4
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    • pp.381-386
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    • 2019
  • Zn-air battery uses oxygen from the air, and hence, air holes in it are kept open for cell operation. Therefore, loss of water by evaporation through the holes is inevitable. When the water is depleted, the battery ceases to operate. There are two water consumption routes in Zn-air batteries, namely, active path (electrolysis) and passive path (evaporation and corrosion). Water loss by the active path (electrolysis) is much faster than that by the passive path during the early stage of the cycles. The mass change by the active path slows after 10 h. In contrast, the passive path is largely constant, becoming the main mass loss path after 10 h. The active path contributes to two-thirds of the electrolyte consumption in 24 h of cell operation in 4.0 M KOH. Although water is an important component for the cell, water vapor does not influence the cell operation unless the water is nearly depleted. However, high oxygen concentration favors the discharge reaction at the cathode.

Dominant Migration Element in Electrochemical Migration of Eutectic SnPb Solder Alloy in D. I. Water and NaCl Solutions (증류수 및 NaCl 용액내 SnPb 솔더 합금의 Electrochemical Migration 우세 확산원소 분석)

  • Jung, Ja-Young;Lee, Shin-Bok;Yoo, Young-Ran;Kim, Young-Sik;Joo, Young-Chang;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.1-8
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    • 2006
  • Higher density integration and adoption of new materials in advanced electronic package systems result in severe electrochemical reliability issues in microelectronic packaging due to higher electric field under high temperature and humidity conditions. Under these harsh conditions, metal interconnects respond to applied voltages by electrochemical ionization and conductive filament formation, which leads to short-circuit failure of the electronic package. In this work, in-situ water drop test and evaluation of corrosion characteristics for SnPb solder alloys in D.I. water and NaCl solutions were carried out to understand the fundamental electrochemical migration characteristics and to correlate each other. It was revealed that electrochemical migration behavior of SnPb solder alloys was closely related to the corrosion characteristics, and Pb was primarily ionized in both D.I. water and $Cl^{-}$ solutions. The quality of passive film formed at film surface seems to be critical not only for corrosion resistance but also for ECM resistance of solder alloys.

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Evaluation on Bearing Capacity of End Girder Member with Local Corrosion (지점부 부재의 부식손상에 따른 강거더 단부 지압강도 평가)

  • Ahn, Jin Hee;Lee, Won Hong;Kim, In Tae;Jeong, Young Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.74-82
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    • 2017
  • Localized corrosions damages in their structural sections can be occurred affected by installed environment conditions with high temperature as near the coastline and humidity or their poor maintenance situation. In bearing supports of steel bridges, especially, lower web and vertical stiffener in end girder support can be easily corroded because of relatively higher humidity due to the narrow space in the end of girder and the wetted accumulated sediments affected by rain water or antifreezing admixture leaked from expansion joint. It can be related to change in their structural performance. In this study, thus, bearing strength test specimens were fabricated considering corrosion damage in the web and vertical stiffeners and the change in their bearing strengths were experimentally evaluated. From the test results, localized corrosion damage of structural members in the end girder affected the bearing strength of end girder support, especially, localized corrosion damage of the vertical stiffener relatively highly affected their bearing strengths.

Properties of Fatigue Crack Initiation and Arrest in Structural Steel Under Acid Fog (산성안개 하의 구조용강에서 피로균열의 발생 및 정류특성)

  • Kim, Min-Geon;Kim, Jin-Hak;Kim, Myeong-Seop;Ji, Jeong-Geun;Gu, Eun-Hoe
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.2
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    • pp.374-379
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    • 2002
  • Corrosion fatigue tests were carried out to clarify the influence of acid fog as environmental factor on the fatigue strength of SM55C using rotary bending fatigue tester. The fatigue strength of acid fog specimen extremely decreased about 80% compared to that of distilled water specimen. In acid fog environment, a number of cracks commenced at corrosion pit and coalesced with the adjacent cracks during they propagate, and they formed a single non-propagating circumferential crack under the endurance stress of N=5$\times$10$\^$7/ cycles. Also, the depth of the crack is smaller than that of normal fatigue crack, so the crack has a veil small aspect ratio. The reason of this peculiar crack growth characteristics is that the crack opening-closure behaviors are hindered by corrosion products on the surface crack faces, and hence it is thinkable that the strong corrosion action like anodic dissolution for crack growth in depth direction is weaker compared with surface, resulting from faint pumping action of crack during loading-shedding processes.

Current Status of Hot Steam Corrosion Evaluation of the Candidate Materials for Intermediate Heat Exchangers of HTSE System (고온전기분해시스템의 열교환기 후보재료에 대한 고온증기 환경에서의 부식평가 현황)

  • Kim, Minu;Kim, Dong Hoon;Jang, Changheui;Yoon, Duk-Joo
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.5 no.1
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    • pp.1-8
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    • 2009
  • Nuclear hydrogen production using high temperature heat of a very high temperature reactor(VHTR) is one of the most attractive ways of mass hydrogen production without greenhouse gas emission. In many countries, sulfur-iodine(S-I) thermochemical process and high temperature steam electrolysis(HTSE) process are being investigated. In such processes, corrosion behavior of Intermediate heat exchanger materials are the most critical issues. Especially in a HTSE system, several heat exchangers will be facing hot steam conditions. In this paper, the status of high temperature corrosion researches in hot steam and supercritical water conditions are reviewed in view of the implication to HTSE conditions. Based on the review, test condition and plan of the hot steam corrosion of the candidate materials are formulated and described in some details along with the schematics of the test set-up. The test results and subsequent evaluation will be used in development of a interface system between the HTSE hydrogen production system and the VHTR.

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Effect of Annealing Heat Treatment to Corrosion Resistance of a Copper (구리의 내식성에 미치는 어닐링 열처리의 영향)

  • Kim Jin-Kyung;Moon Kyung-Man;Lee Jin-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.654-661
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    • 2005
  • Copper is a well known alloying element that is used to improve the resistance to general corrosion of stainless steel And also Cu cation have the anti-fouling effect to inhibit adhesion of the marine algae and shellfish to the surface of heat exchanger cooling pipe or outside wall of the ship, Therefore there are some anti-fouling methods such as anti-fouling Paint mixed with copper oxide or MGPS(Marine Growth Preventing System) by using Cu cation dissolved to the sea wather solution. Cu cation can be dissolved spontaneously by galvanic current due to Potential difference between Cu and cooling pipe of heat exchanger with Ti material, which may be one of the anti-fouling designs. In this study the effect of annealing heat treatment to galvanic current and Polarization behavior was investigated with a electrochemical points of view such as measurement of corrosion Potential, anodic polarization curve. cyclic voltammetric curve, galvanic current etc The grain size of the surface in annealed at $700^{\circ}C$ was the smallest than that of other annealing temperatures. and also the corrosion Potential showed more positive potential than other annealing temperatures. The galvanic current between Ti and Cu with annealed at $700^{\circ}C$ was the largest value in the case of static condition. However its value in the case of flow condition was the smallest than the other temperatures. Therefore in order to increase anti-fouling effect by Cu cation, the optimum annealing temperature in static condition of sea water is $700^{\circ}C$, however non- heat treated specimen in the case of flow condition may be desirable.