• Title/Summary/Keyword: water corrosion

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Fracture Mechanics Analysis of the Steam Generator Tube after Shot Peeing (숏피닝 증기 발생기 전열관의 파괴역학적 해석)

  • Shin, Kyu-In;Park, Jai-Hak;Jhung, Myung-Jo;Choi, Young-Hwan
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1180-1185
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    • 2003
  • One of the main degradation of steam generator tubes is stress corrosion cracking induced by residual stress. The resulting damages can cause tube bursting or leakage of the primary water which contained radioactivity. Primary water stress corrosion crack occurs at the location of tube/tubesheet hard rolled transition zone. In order to investigate the effect of shot peening on stress corrosion cracking, stress intensity factors are calculated for the crack which is located in the induced residual stress field.

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The Tarnish Process of Silver in H2S Environments

  • Kim, H.;Payer, J.H.
    • Corrosion Science and Technology
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    • v.5 no.6
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    • pp.206-212
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    • 2006
  • The effects of sub-ppm levels of $H_2S$ and the adsorbed water on the atmospheric corrosion of silver were studied with In situ weight balance to study the effect of the adsorbed water on the kinetic behavior and to determine the rate-controlling step, with XPS to analyze the tarnish film, and with calculation of phase equilibrium to predict the stable solid phase, the concentrations of dissolved species ($Ag^-$, $H^+$, $S^{2-}$, $HS^-$) and the equilibrium potentials ($E_{Ag^+/Ag}$, $E_{H^+/H_2}$, $E_{O_2/O^{2-}$). The results of weight measurements showed that oxygen was required for the sulfidation of silver in 100 ppb $H_2S$ and humidified environments enhanced the tarnished rate and oxidizing power. In addition, the rate determining step for tarnishing silver was shown to be changed to transport though the tarnish film.

Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System (희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동)

  • Ha, Ji-Myung;Jin, Chung-Kuk;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.

Reliability Analysis Method for Repeated UT Measurement Data in Nuclear Power Plants (원전 배관의 반복 측정 데이터에 대한 신뢰도 분석 방법)

  • Yun, Hun;Hwang, Kyeong-Mo
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.142-148
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    • 2013
  • Safety is a major concern in Nuclear Power Plants (NPPs). Piping systems in NPPs are very complex and composed of many components such as tees, elbows, expanders and straight pipes. The high pressure and high temperature water flows inside piping components. As high speed water flows inside piping, the pipe wall thinning occurs in various reasons such as FAC (Flow Accelerated Corrosion), LDIE (Liquid Droplet Impingement Erosion) and Flashing. To inspect the wall thinning phenomenon and protect the piping from damages, piping components are checked by UT measurement in every overhaul. During every overhaul, approximately 200~300 components (40,000~60,000 UT data) are examined in NPPs. There are some methods from EPRI for evaluating wear rate of components. However, only few studies have been conducted to find out the raw data reliability for the wear rate evaluation. Securing the reliable raw data is the key factor for a reasonable evaluation. This paper suggests the reliability analysis method for the repeatedly measured data for wear rate evaluation.

Sensitivity analysis of thermal-hydraulic parameters to study the corrosion intensity in nuclear power plant steam generators

  • Tashakor, S.;Afsari, A.;Hashemi-Tilehnoee, M.
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.394-401
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    • 2019
  • The failure of steam generators (SGs) due to corrosion is one of the most important problems in power plants. Impurities usually accumulate in the hot sides of SG and form deposits on the SG surfaces. In this paper, the sensitivity analysis of the accumulation of water impurities in the heat exchangers of nuclear power plants is presented. The convection-diffusion equation of the liquid phase on the heated surfaces is derived and then solved by the finite volume method. Also, the effects of the thermal-hydraulic parameters in the form of dimensionless numbers, such as $Pe_q$, $Pe_u$, $k_q$(relative solubility of impurity between the steam and water) on the impurities concentration are studied.

Stress-assisted oxidation behaviour of inconel 52M/316 austenitic stainless-steel dissimilar weld joints in a simulated pressurised water reactor

  • Xu, Youwei;Yang, Binhui;Shi, Yu
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3778-3787
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    • 2022
  • The stress-assisted oxidation behaviour of Inconel 52 M/316 austenitic stainless-steel (SS) dissimilar weld joints (DMWJ) in a simulated pressurised water reactor environment was investigated. A corrosion galvanic couple formed between the Inconel 52 M and 316 SS due to differences in their nonferrous metal content. The electric field from the corrosion couple attracted metal cations (e.g. Fe2+, Cr3+) to the Inconel 52 M that were deposited as FeCr2O4. An additional corrosion galvanic couple was generated due to variations in the plastic deformation of the DMWJ. The superposition of electric fields from the different couples resulted in ridge-like oxide depositions in the fusion zone.

Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water (인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가)

  • Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Study on Corrosion Resistance Performance of Zn Coating Applied by Arc Thermal and Plasma Arc Spray Process in Artificial Ocean Water (인공해양환경에서 Arc Thermal and Plasma Arc Spray 공법이 적용된 Zn 코팅 강재의 내식성능 평가에 관한 연구)

  • Jannat, Adnin Raihana;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.83-84
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    • 2020
  • In present study, we have deposited the Zinc coating using arc thermal spray and plasma arc spray processes onto the steel substrate and durability of the deposited coating was evaluated. The bond adhesion result shows that plasma arc sprayed Zn coating exhibited higher in its value compared to arc thermal spray. SEM shows that Zn coating deposited by plasma arc process is more compact, less porous and adherent compare to arc spray process. The corrosion resistance properties are evaluated in artificial ocean water solution with exposure periods. EIS results show that total impedance at 0.01 Hz of plasma arc sprayed coating is higher than arc thermal spray owing to the compact and less porous morphology. It is concluded that plasma arc sprayed Zn coating is better than arc thermal spray process.

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Corrosion Behavior Analysis of the Weld Joint between Stainless Steel and Carbon Steel (스테인레스강과 탄소강 용접부의 부식거동 해석)

  • 권재도;이우호;장순식;진영준;문윤배
    • Proceedings of the KWS Conference
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    • 1997.05a
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    • pp.35-38
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    • 1997
  • In order to investigate quantitative behavior of galvanic corrosion in the weld joint between stainless steel and carbon steel, electrochemical polarization experiments are performed for various pH, water temperature with boric acid concentration 4000ppm. The corrosion rate of stainless steel was almost independent of the variation of pH. The significant corrosion rates of carbon steel and the weld joint of carbon-carbon steel were observed at pH 4. The corrosion rates in the weld joint of the carbon-stainless steel were observed depending on the variation of pH level.

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Effect of Admixtures on the Steel Corrosion in Mortar (혼화재를 혼입한 모르터내의 철근부식성상에 관한 연구)

  • 임순지;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.145-149
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    • 1995
  • This study is to recognize the effect of silica-fume, fly-ash, and chemical proportion in mortar that have salt on the inside affect steel bar corrosion. water-binder ratio, 0.5, compounds, each of 10, 15, 20% by weight of cement, Nacl mixing weight, 0.5, 1.0, 2.0% by weight of binder, The speciment is sealed and cured for 28days, the corrosion area ratio and weight reduction ratio is measured after the accelerated corrosion test of 20 cycles. The conclusion shows that there is no suppression effect of steel bar corrosion of silica-fume, fly-ash, in case of having salt on the inside.

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