• Title/Summary/Keyword: water corrosion

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A Study on the Mechanical Properties of Nuclear Fuel Cladding Materials (원자로용 핵연료 피복재의 인장특성에 관한 연구)

  • Bae, Bong-Kook;Song, Chun-Ho;Seok, Chang-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.2
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    • pp.231-238
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    • 2003
  • The fuel of light water reactor is used for several years under high temperature and pressure, so it needs to be clad with high corrosion resistance material. The cladding materials must have the characteristics of low absorption of a neutron and high corrosion resistance. Zircaloy-2 in Boiling Water Reactor, Zircaloy-4 in Pressurized Water Reactor have been used as cladding materials and Zirlo has been developed as the material for preventing the corrosion. If the fracture of the cladding tube occurs during operation, it will cause the economic loss to shut down and replace the system. So it is needed to evaluate the integrity of the cladding materials. In this paper, the tensile characteristics of the cladding materials were investigated for the basic research of fracture characteristics. Also the residual stress was analyzed to compare the tube type(original type) specimen and the flattened type specimen.

A Study on Mechanical Properties of Fuel Cladding Materials (원자로용 핵연료 피복재의 인장특성에 관한 연구)

  • Bae, Bong-Kook;Song, Chun-Ho;Seok, Chang-Sung
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.489-494
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    • 2001
  • The fuel of light water reactor used far several years at high temperature and pressure, so it needs to clad with high corrosion resistance material. The cladding materials need low absorption of a neutron and high corrosion resistance. Cladding materials used Zircaloy-2 in Boiling Water Reactor, Zircaloy-4 in Pressurized Water Reactor and Zirlo has good for long term corrosion. If fracture of cladding tube occured during operation, it caused disaster. So it is needed to estimate of integrity fur cladding materials. In this paper, tension characteristics of cladding materials are investigate which is basic research far fracture characteristic. Also analysis of residual stress effect between tube type(original type) specimen and flattened type specimen.

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Extract of Camellia sinensis as Green Inhibitor for the Corrosion of Mild Steel in Aqueous Solution

  • Fouda, Abd El-Aziz S.;Mekkia, Dina;Badr, Abeer H.
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.264-271
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    • 2013
  • Corrosion inhibition of mild steel used in water station in 35 ppm aluminum sulfate and 10 ppm chloride solution by Camellia sinensis leaves extract was studied using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques at $30^{\circ}C$. Results show that the inhibition efficiency increases with increasing concentration of the extract and decreases with increasing temperature. Inhibitive effect was afforded by adsorption of the extract's components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

The Corrosion Control Using CCPP(Calcium Carbonate Precipitation Potential )Index in Metallic Coupons ($CaCO_3$침전능 조절에 의한 금속시편에서의 부식방지)

  • 이재인;임진경;서상훈;김동윤;신춘환
    • Journal of Environmental Science International
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    • v.9 no.6
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    • pp.505-509
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    • 2000
  • The purpose of this study was to evaluate the effects of $Ca(OH)_2$ and $CO_2$ additions on the corrosion of metal coupons(ductile iron, galvanized steel, copper and stainless steel). Corrosion rate and released metal ion concentration of ductile iron and galvanized steel decreased by adjusting alkalinity, calcium hardness and pH with $Ca(OH)_2$ & $CO_2$ additions on copper and stainless steel were less than those on ductile iron and galvanized steel. When ductile iron coupon was exposed to water treated with Ca(OH)$_2$&$CO_2$, additions, the main components of corrosion product formed on its surface were $CaCO_3$ and $Fe_2 O_3 or Fe_2 O_4$ which often reduce the corrosion rate by prohibiting oxygen transport to the metal surface.

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A Study on the Galvanic corrosion and its Protection on Heat Exchanger Tube Plate (열교환기 관판의 전지작용부식과 방지에 관한 연구)

  • 임우조;홍성희;윤병두
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.344-350
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    • 2001
  • This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

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A Study on the Galvanic corrosion and its Protection on Heat Exchanger Tube Plate (열교환기 관판의 전지작용부식과 방지에 관한 연구)

  • U-J Lim;S-H Hong;B-D Yun
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.2
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    • pp.345-345
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    • 2001
  • This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

The Crevice Corrosion Behavior of AISI 304 & 316L Stainless Steel Welded by TIG, MIG, CO2 and SMA (용접방법에 따른 AISI 304 및 316L스테인리스강 용접부의 틈부식 거동)

  • 백신영
    • Journal of Advanced Marine Engineering and Technology
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    • v.15 no.4
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    • pp.22-28
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    • 1991
  • The crevice corrosion behavior on austenitic AISI 304 and 316L stainless steel welded by TIG, MIG, $CO_2$ and SMA was studied. The results are as follows : In 10% $FeCl_3$ solution and natural sea water sampled near Mokpo port, the base metal of 304 stainless steel showed small amount corrosion, whereas 316L stainless steel did not showed any corrosion in the test periods. The weight loss caused by crevice corrosion increased with increasing weld heat input and residual .delta. ferrite formed in welded part. The corrosion resistance of the welded part was in the order of TIG, MIG, $CO_2$ and SMA. From this tendency, it is proved that the smaller heat input gives the better corrosion resistance.

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Corrosion Resistance of Super Duplex Stainless Steel (수퍼 2상 스테인리스강의 부식 저항성에 관한 연구)

  • 강흥주;남기우;안석환;강창룡;도재윤;박인덕
    • Journal of Ocean Engineering and Technology
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    • v.17 no.2
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    • pp.40-46
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    • 2003
  • The corrosion resistance of super duplex stainless steel on both its fibrous and dispersed phase was investigated. These structures consist of various volume fraction and distribution of austenite structure, which were obtained by changing the heat treatment temperature and cycle. The fibrous phase had higher austenite volume fraction than that of the dispersed phase at the same temperature. Corrosion resistance of super duplex stainless steel was evaluated through an immersion test and an impingement test, using 35% HCI and sea water, respectively. Super duplex stainless steel was compared with STS316L and STS304. The corrosion resistance of super duplex stainless steel was superior to ST316L and STS304. The dispersed phase of super duplex stainless steel was more stabilized than the fibrous phase in corrosion. The magnitude of corrosion rate was in order STS304, STS316L, fibrous phase of super duplex stainless steel and dispersed phase of super duplex stainless steel.

The Prediction of Remaining Service Life of Land Concrete Due to Steel Corrosion (철근부식에 의한 육지 콘크리트의 잔존수명 예측)

  • 정우용;윤영수;송하원;변근주
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.69-80
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    • 2000
  • This paper presents the prediction of remaining service life of the concrete due to steel corrosion caused by the following three cases; carbonation, using sea sand and using deicing salts. The assessment of initiation period was generalized considering the existing perdiction models in the literature, corrosion experiment and field assessment. To evaluate the prediction equation of rust growth, the corrosion accelerating experiments was performed. The polarization resistance was measured by potentiostat and the conversion coefficient of polarzation resistance to corrosion rate was determined by the measurement of real mass loss. Chloride content, carbonation, cover depth, relative humidity, water-cement ratio(W/C), and the use of deicing salts were taken into account and the resulting prediction equation of rust growth was proposed on the basis of these properties. The proposed equation is to predict the rust growth during any specified period of time and be effective in particular for predicting service life of concrete in the case of using sea sand.

The Performance of Cathodic Protection with ICCP

  • Oh, Jin-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.8
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    • pp.1286-1290
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    • 2004
  • This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.