• Corrosion Science and Technology
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• v.22 no.3
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• pp.137-152
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• 2023

Polarization behavior and corrosion inhibition of copper in acidic chloride solutions containing benzotriazole were studied. Pourbaix diagrams constructed for copper in NaCl solutions with different BTAH concentrations were used to understand the polarization behavior. Open circuit potential (OCP) depended not only on chloride concentration, but also on whether a CuBTA layer was formed on the copper surface. Only when the (pH, OCP) was located well in the CuBTA region of the Pourbaix diagram, a stable corrosion inhibiting CuBTA layer was formed, which was confirmed by X-ray Photoelectron Spectroscopy (XPS) and a long-term corrosion test. The OCP for the CuBTA layer decreased logarithmically with increasing [Cl^-] activity in the solution. A minimum BTAH concentration required to form a CuBTA layer for a given NaCl concentration and pH were determined from the Pourbaix diagram. It was found that 320 ppm BTAH solution could be used to form a corrosion-inhibiting CuBTA layer inside the corrosion pit in the sprinkler copper tube, successfully reducing water leakage rate of copper tubes. These experimental results could be used to estimate water chemistry inside a corrosion pit.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.77-84
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• 2008

Based upon the good compatibility to neutron irradiation and high temperature water environment, austenitic stainless steels are widely used for core internal structural materials of light water reactors. But, recently, intergranular cracking was detected in the stainless steels for the core applications in some commercial PWR plants. Authors studied on the root cause of the intergranular cracking and developed the countermeasure including the alternative materials for these core applications. The intergranular cracking in these core applications are defined as an irradiation assisted mechanical cracking and irradiation assisted stress corrosion cracking. In this paper, the root cause of the intergranular cracking and its countermeasure are summarized and discussed.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1-6
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• 2004

Lots of researches were gone already about grooving corrosion mechanism of ERW carbon steel pipe. But there is seldom study for water hammer happened by fluid and acceleration of corrosion rate by incresed flow velocity. Therefore, in this study carried out the analysis based on hydrodynamic and fracture mechanics. Analyzed stress that act on a pipe using ANSYS as a program, and also FLUENT and STAR-CD were used for flow phenomenon confirmation. As the result, fatigue failure is happened by water hammer and corrosion rate was increased because of turbulent flow.

• Journal of Ocean Engineering and Technology
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• v.10 no.3
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• pp.14-23
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• 1996

The corrosion fatigue test were carried out to evaluate the fatigue characteristics of accelerated cooled (ACC) TMCP high tensile strength steels and weld joint with high heat input by one side one run submerged are welding. In this paper, the fatigue crack growth behaviors were investigated with the center crack tension specimen of base metal and heat affected zone in substitute sea water and air, respectively Main results obtained are sunnarized as follows: 1. The fatigue crack growth rates in sea water faster than those in air environment for the different heat input values, crack growth rate of base metal is very fast and effect of heat input is not remarkable. 2. In HAZ (82kJ/cm, 116kJ/cm), the crack branching phenomena were observed in both air and sea water environment, 3. In SEM observation, the corrosion effect on base metal was larger than that on HAZ in corrosion environment.

• Journal of Urban Science
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• v.7 no.1
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• pp.23-27
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• 2018

This research was carried out to investigate the corrosion prevention effect in the water distribution system by galvanized zinc-brass pipe which is using potential between brass and zinc. As a result of this study, pH and conductivity of influent were constant in spite of its installation, and it was difficult to estimate the effect of the installation with temporary increased and reduced concentration of Zn and Fe ions, respectively. However, since the corrosion rate of the steel coupon with galvanized zinc-brass pipe was relatively low, it has an effect of inhibiting corrosion.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2006.11a
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• pp.185-188
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• 2006

The sea water pipe of engine room in all kinds of ships is being surrounded with severe corrosive environment. Therefore it's leakage part due to corrosion is inevitably prevented by various welding method. In this case corrosion property of welded zone may be considerably different by each welding materials. In this study corrosion resistance of the welded zone of sea water pipe with some welding materials such as shielded metal arc welding materials, inert gas arc welding materials was investigated with electrochemical method.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.5
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• pp.181-187
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• 2000

Fatigue tests under acid fog environment were carried out to investigate the effect of acid fog on the corrosion fatigue strength of SM55C in comparison with distilled water. Main results obtained are as follows. The fatigue strength of SM55C under acid fog environment are remarkably decreased as compared with that of distilled water specimen. The corrosive effect of acid fog on fatigue strength are more serious under low stress amplitude level than under high stress amplitude level, and this leads to continuous reduction of fatigue strength. Under acid fog environment in early stage of crack growth. because the corrosive components dissolve the crack face offensively. the unstable fracture surface appears. But, the stable corrosion precipitation and products layer are formed on the fracture surface in accordance with the time pass.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.579-584
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• 1997

This experimentation is to apperciation an efficiency of repair for processing crack by corrosion of steel reinforcing, Crack on concrete by corrosion of steel reinforcing is the fact that the first crack appear on the surface of water because of supplying is of oxygen and water. The crack processing is on surface to be contacted by air and to bottom as mainly the vertical direction from a surface of water. The experimentation gives rise to crack in model by electricity. Crack by corrosion of steel reinforcing is more internal crack than external crack. since it is so. crack by corrosion of steel reinforcing have to attention to repair or intermal crack.

• Journal of Korean Port Research
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• v.12 no.1
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• pp.145-154
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• 1998

Protection characteristics of the corroded steel pile which was served as a pier structure over 8 years in seawater have been examined in terms of corrosion potential, electrochemical impedance spectroscopy(EIS) and anodic/cathodic polarization curves. The steel structure was sectioned into two parts, waterline(splash zone, just above the seawater surface) and in-water(underwater), and protection characteristics for the two parts were investigated with the application of cathodic protection(CP) by sacrificial anodes using Zn and Al alloys. The main results obtained were as follows; (1) The corrosion potential of waterline zone was higher than that of in-water, which implied that the corrosion of waterline was more severe than that of in-water, (2) As a result of EIS examination, the transition period from the apparent CP to the substantial CP took about twenty to thirty days according to the corrosion condition.

• Corrosion Science and Technology
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• v.7 no.2
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• pp.92-98
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• 2008

This paper describes the experiments of the corrosion and the sliding tests of the nickel-based alloys for the gate valve seating materials used at high pressure and temperature. The general corrosion rates and IGC susceptibility are tested in pressurized water at 533 K and 575 K and in Strauss test solution. The sliding tests have been done in pressurized water at 293 k, 473 K and 573 k. The alloys containing above 10% chromium may have the anti-corrosion properties that could be applied to the valve seats for the power plants. The good sliding performance and the good pressure tightness are obtained when the disc specimens that have hardness 500 to 600 Hv combined with the seat specimens that have hardness 250 to 410 Hv containing about 40 percent of iron. The large size gate valves sliding tests have certified the test results. The anti-wear properties of the seat alloy and the anti-IGC susceptibility of the disc alloy could be improved by the addition of silicon and niobium, respectively.