• Title/Summary/Keyword: water corrosion

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An Experimental Study for Improving the Durability of Concrete Bridge Decks (교량 바닥판 콘크리트의 내구성 증진을 위한 실험적 연구)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung;Shin, Do-Chul
    • Journal of the Korea Concrete Institute
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    • v.19 no.4
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    • pp.393-399
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    • 2007
  • Concrete bridge decks are directly exposed to the severe environmental conditions such as rain water and deicing chemicals resulting in the freeze-thaw action and the rebar corrosion during their service lift. These deteriorations of bridge decks shorten the service lift and consequently they are the major concerns of the maintenance. The high performance concrete (HPC) deck is proposed as the alternative to minimize the deterioration problems. To develop more durable concrete deck, the performance characteristic tests of HPC mixtures were carried out. In this study, 4 different concrete mixtures were used varying the mineral admixtures as the cement replacement; ordinary portland cement (OPC), 20% fly ash (FA),20% fly ash with 4% silica fume (FS), and 40% ground granulated blast-furnace slag (BS). The design compressive strengths of HPC specimens were 27 MPa and 35 MPa, respectively. The results showed that the compressive strength of concrete did not much affect the durability of concrete. HPC with fly ash and silica lune (FS) were turned out to have the good durability and crack resistance.

Studies on Carbonation of Concrete with Low-Calcium Fly Ash and Blast Furnace Slag (플라이 애쉬 및 고로수쇄(高爐水碎)슬래그를 혼화(混和)한 콘크리트의 중성화(中性化)에 관한 연구(研究))

  • Nagataki, Shigeyoshi;Kim, Eun Kyum;Ohga, Hiroyuki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.229-240
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    • 1987
  • Carbonation of concrete is one type of a chemical process. The reaction mechanism is very complex for the case when low-calcium fly ash and blast furnace slag is added. When fly ash and blast furnace slag is used as an admixture in concrete, they improve compressive strength in the long term, permeability and chemical resistance of concrete by a pozzolanic reaction and latent hydraulic property. On the other hand, the pozzolanic reaction of fly ash and latent hydraulic property of the blast furance slag leads to a reduction of the alkalinity of the concrete. It has been pointed out that this will accelerate the carbonation of the concrete and the corrosion of reinforcement steel embedded in the concrete. In order to clarify the effect of fly ash and blast furance slag on the carbonation of concrete, an accelerated carbonation testing of concrete was carried out by varying the conditions of concrete and the initial curing period in water. The test results of accelerated carbonation were compared to the carbonation test results of concrete stored for 15 years in open air, but protected from rain. As a result, the equation for the rate of carbonation based on compressive strength of concrete was proposed.

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Stress Distributions at the Dissimilar Metal Weld of Safety Injection Nozzles According to Safe-end Length and SMW Thickness (안전단 길이 및 동종금속용접부 두께 변화에 따른 안전주입노즐 이종금속용접부의 응력분포)

  • Kim, Tae-Jin;Jeong, Woo-Chul;Huh, Nam-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.10
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    • pp.979-984
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    • 2015
  • In the present paper, we evaluate the effects of the safe-end length and thickness of the similar metal weld (SMW) of safety injection nozzles on stress distributions at the dissimilar metal weld (DMW). For this evaluation, we carry out detailed 2-D axisymmetric finite element analyses by considering four different values of the safe-end length and four different values of the thickness of SMW. Based on the results obtained, we found that the SMW thickness affects the axial stresses at the center of the DMW for the shorter safe-end length; on the other hand, it does not affect the hoop stresses. In terms of the safe-end length, the values of the axial and hoop stresses at the inner surface of the DMW center increase as the safe-end length increases. In particular, for the cases considered in the present study, the stress distributions at the DMW center can be categorized according to certain values of safe-end length.

Engineering Characteristics of Liquid Filler Using Marine Clay and In-situ Soil (해양점토와 현장토를 활용한 유동성 채움재의 공학적 특성)

  • Oh, Sewook;Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.9
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    • pp.25-32
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    • 2020
  • The underground utilities installed under the ground is an important civil engineering structure, such as water supply and sewerage pipes, underground power lines, various communication lines, and city gas pipes. Such underground utilities can be exposed to risk due to external factors such as concentrated rainfall and vehicle load, and it is important to select and construct an appropriate backfill material. Currently, a method mainly used is to fill the soil around the underground utilities and compact it. But it is difficult to compact the lower part of the buried pipe and the compaction efficiency decreases, reducing the stability of the underground utilities and causing various damages. In addition, there are disadvantages such as a decrease in ground strength due to disturbance of the ground, a complicated construction process, and construction costs increase because the construction period becomes longer, and civil complaints due to traffic restrictions. One way to solve this problem is to use a liquid filler. The liquid filler has advantages such as self-leveling ability, self-compaction, fluidity, artificial strength control, and low strength that can be re-excavated for maintenance. In this study, uniaxial compression strength test and fluidity test were performed to characterize the mixed soil using marine clay, stabilizer, and in-situ soil as backfill material. A freezing-thawing test was performed to understand the strength characteristics of the liquid filler by freezing, and in order to examine the effect of the filling materials on the corrosion of the underground pipe, an electrical resistivity test and a pH test were performed.

A study on the development and field application of SP-Rockbolt with high-strength steel pipe (고강도 강관을 적용한 SP-록볼트 개발 및 현장 적용을 위한 연구)

  • Shin, Hyunkang;Jung, Hyuksang;Ahn, DongWook
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.4
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    • pp.651-668
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    • 2017
  • For initial stability of the tunnel, the primary support, Shotcrete and rockbolt shall be placed in the most appropriate time. This is because the role of such support plays a vital role in long-term and short-term tunnel stability. In this study, the rock bolt is an important supporting system that receives the external pressure generated by the stress relaxation during tunnel excavation as axial force and transmits it to the shotcrete on the tunnel excavation surface. Until now, most of the materials of rock bolts have been used in the field, but there have been many problems such as uncertain quality of Chinese materials entering the market, poor packing due to falling down of rock bolts when filled with mortar, and corrosion due to water. Therefore, in this study, we have developed a high strength steel pipe rock bolt using Autobeam material to solve and improve various problems of existing rock bolts. In order to evaluate the performance of the developed bolt, field tests were carried out and the existing mortar filler in order to improve the performance of the rock bolt, the design and construction criteria were studied and the results were included in this paper.

Evaluation of Shrinkage Cracking Characteristics and Degree of Restraint for Ultra-High-Strength Concrete (초고강도 콘크리트의 수축 균열 특성 및 구속도 평가)

  • Yoo, Doo-Yeol;Min, Kyung-Hwan;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.641-650
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    • 2010
  • The concrete cracking from the restrained stress caused by the shrinkage may play significant cause of deterioration of concrete structures by allowing the permeation of sulphate and chloride ions which in turn triggers corrosion of steel reinforcement. In particular, the cracking becomes more critical as water binder ratio (W/B) is reduced and concrete strength increases. Therefore, it needs to evaluate correctly the comprehensive shrinkage behavior of concrete with high strength: high-strength concrete (HSC), ultra-highstrength concrete (UHSC). The unrestrained shrinkage tests, however, cannot estimate the net shrinkage effectively which affects cracking after full development of strength and stiffness because it does not consider the degree of restraint, strength development, stress relaxation, and so on. Therefore, in this study, both free and restrained shrinkage tests with variables of W/B (W/B of 30, 25 and 16%) and admixtures (fly ash (FA) and granulated blast-furnace slag (BFS)) for HSC, very-high-strength concrete (VHSC) and UHSC were performed. The test results indicated that the autogenous shrinkage and total shrinkage at drying condition were reduced as W/B increased and FA, BFS were added, and the cracking behavior was suppressed as W/B increased and FA was added.

An Analysis of the Application Technology of Heat Recovery System from Dyeing Wastewater (염색폐수 열회시스템 적용기술 분석)

  • 장기창;박성룡;이상남;라호상;박준택;함성원;박영태
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.195-205
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    • 2001
  • A great deal of energy is necessary with emission of lots of wastewater in dyeing and finishing process, but heat recovery from wastewater is not introduced since is technology is not developed yet. In order to obtain the method utilizing hot water produced by heat source, that is, dyeing wastewater it was investigated the characteristics of dyeing and finishing process and energy basic unit. Energy basic unit of polyester/cotton (T/C), polyester/rayon (T/R) and polyester dyeing process are higher than that of the other process. The average quantity of wastewater for each dyeing company is 20,470 ton/month, the average temperature of wastewater is about 41$^{\circ}C$. Because the SS solution of wastewater in polyester dyeing process is lower than that of the other process, the effect of corrosion in heat recovery system is low. Since the energy price for 1000 kcal produced by vapor compression heat pump is presumed to be 22.50 won, it is found to be very economic heat recovery system, and its payback is 2.09 years for the factory with LNG boiler.

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Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.

Evaluation of the Properties of an Environment-Friendly De-icing Agent Based on Industrial By-Products (산업부산물을 활용한 친환경제설제의 특성평가)

  • Heo, Hyung-Seok;Lee, Byung-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.132-139
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    • 2017
  • A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride($CaCl_2$) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.

Crack and Time Effect on Chloride Diffusion Coefficient in Nuclear Power Plant Concrete with 1 Year Curing Period (1년 양생된 고강도 원전 콘크리트의 염화물 확산에 대한 균열 및 시간효과)

  • Chun, Ju-Hyun;Ryu, Hwa-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.83-90
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    • 2017
  • Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.