• Journal of the Korea Convergence Society
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• v.9 no.4
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• pp.151-160
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• 2018

Waxes currently used as a coating material to preserve surfaces of outdoor iron sculptures tend to face lower coating strength and efflorescence due to the aging from air pollution and acid rains. Consequently, they are subjected to repeated corrosions shortly after the treatment. And the sculptures face the problem losing their original nature because of the changes of colors and lusters, so this convergence study aims at developing wax with better performance than the existing materials. For this reason, the study identified the effects of physical property using the environmental experiments such as the tests of salt spray and gas corrosion as well as the analysis of luster level and thermo-gravimetry. As this study result, the developed ISC wax showed the excellent blocking effect from salt water and coating durability more than five times compared with the existing waxes, better acid resistance by two-four times, sun block effect by 2-10 times, improved luster variance by 3-16 times, improved thermo-stability and durability by 0.5-5 times, and therefore demonstrating far better coating effect than the existing waxes. In the light of these findings, this study contributes for this new development which can replace the existing waxes used so far in order to preserve the outdoor iron sculptures.

• Journal of Technologic Dentistry
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• v.33 no.2
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• pp.121-128
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• 2011

Purpose: The purpose of this study is to investigate the level of each metal in non-precious metal alloys dental casting, still used even banned for use and trade by the law, for oral health. Methods: Two kinds of metal alloys were analyzed. One was Ticonium 100 for removable prosthesis and the other was Rexillium V for dental porcelain. Two samples of each metal alloy were made in 0.5g, 1.0g, and 1.5g. Total number of samples were 12. Two kinds of lactic acid Solution, pH7 and pH4.6, were injected into each samples. After injection, each samples had been for 21days ${\pm}$ 1 hour in the water tank of which temperature was $37^{\circ}C$. The level of metal was measured in each sample by inductively couplled plasma-atomic emission spectrometer. Results: In both metal alloys, metals, chrome, nickel, beryllium, and molybdenum, were founded. In Ticonium 1000, the highest level of nickel was 2.531ppm in 1.5g pH4.6 sample while the highest level of nickel was 4.062ppm in 1.5g pH4.6 sample of Rexillium V. In chemical composition of these methal alloys, chrome(14~17%) was much more than beryllium(1.95~1.99%) and molybdenum(5.0~9.0%) but berllium and molybdenum were founded more than chrome in samples. Therefore, chrome showed better anti-corrosion than other metal alloys. In both metal alloys, more metals were founded in higher pH level and more mass. Levels of chrome was significantly different in samples of both metal alloys in each pH level(p<0.05). Levels of nickels was significantly different in samples of both metal alloys in each pH level(p<0.05). Conclusion: For oral health, further studies are needed in nickel-chrome metal alloy and cobalt metal alloy of non-beryllium in addittion to beryllium metal alloy and also long-term studies needed in various period and other non-percious metal alloys for dental casting.

• Economic and Environmental Geology
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• v.29 no.2
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• pp.215-225
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• 1996

All the radionuclides in high-level nuclear waste will decay to harmless levels eventually but for some radionuclides decay is so slow that their radiation remains dangerous for times on the order of tens or hundreds of thousands of years. At the present time, the most favorite disposal plan for high-level radioactive waste is a mined geological disposal in which canister enclosing stable solid form of radioactive waste is placed in mined cavities locating hundred meters below the surface. The chief hazard in such disposal is dissolution of radionuclides from the waste in the groundwater that will eventually carry the dissolved radionuclides to surface environments. The hazard from possible escape of the radionuclides through groundwater can be delayed by engineered and geologic barriers. The engineered barriers can become useless by unexpected geologic catastrophe such as volcanism, earthquake, and tectonic movement and by fraudulent work such as careless construction, improperly welded canisters within the first few decades or centuries. As a result, dangerously radioactive waste which is still intensively radioactive is directly exposed to attack by moving groundwater. All the more, it is almost impossible to control repositories for times more than 10,000 years. Therefore, naturally controlled geologic, barriers whose properties will not be changed within 10,000 years are important to guarantee the safety of repositories of high-level radioactive waste. In Sweden and France, the suitability of granite for the mined geological disposal of high-level waste has been studied intensively. According to the research in Sweden and France, granites has the following physio-chemical characteristics which can delay the transportation of radionuclide by groundwater. First, the permeabilities of granites decreases as the depth increases and is $10^{-8}{\sim}10^{-12}m/s$ at depth below 300 m. Second, groundwater at depth below 300 m has pH=7-9 and reducing condition (Eh=-0.1~0.4). This geochemical condition is desirable to prevent both canister and solid waste from corrosion. Third most radionuclides are not transported by low solubilities and some radionuclide with high solubility such as Cs and Sr are retarded by absorption of geologic media through which ground water flows. Therefore, if high-level waste is disposed at depth below 300 m in the granite body which has a low permeability and is geologically stable more than 10,000 years, the safety of repositories from the hazard due to radionuclide escape can guaranteed for more than 10,000 years.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.2
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• pp.469-483
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• 2018

Steel bars have been widely used as the primary reinforcement for Precast Segmental Concrete Lining for TBM Tunnels. Previously, studies have been carried out to gauge the potential for steel fiber reinforcement to replace the use of steel bar reinforcements in the segmental lining to reduce the amount of the steel bar reinforcement. Steel fiber reinforcements have been investigated and widely applied to SFRC TBM linings to improve the constructability of SFRC TBM linings worldwide. However, the steel fiber reinforcement often caused punctures to the water membranes inside tunnel lining and had long-term durability deterioration issues caused by steel corrosion, as well as cosmetic problems. Therefore, this paper sought to gauge the potential of synthetic fiber reinforcements, which have proven to be very attractive substitutes for steel fiber reinforcements. This study analyzed the performance of both steel and synthetic fiber reinforcements in segmental linings and evaluated the applicability of the fiber reinforcements to the TBM Precast Concrete Segmental Linings of TBM tunnels. As a conclusion, this study demonstrates that the potential use of steel and synthetic fibers in various combination, can substitute the rebar reinforcement in the concrete mix for segmental concrete linings.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.1
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• pp.81-87
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• 2006

The industrial systems contain many sites and components susceptible to biofilms formation. Biofilms play an important role in microbial growth and industrial fouling. Thus, the control of the biofilms in industrial systems has been emphasized, however, the efficient controlling method was not provided yet. Since silver compounds have no residual and corrosion problem, the interest for silver compounds as a biofilm control disinfectant has been increased. In this study, we attempted to examine the disinfection ability of silver compounds. The disinfection efficiency of two silver compounds(silver ion and silver oxide) were evaluated for biofilms in comparison with suspended cells using well known indicator microorganisms(E. coli, P. aeruginosa) and compared with that of chlorine. Silver compounds were found to be effective in inactivating E. coli and P. aeruginosa biofilms. The reason for superiority of silver compounds as biofilm disinfectant was suggested by that silver can penetrate into the inner biofilm matrix faster than chlorine without consumption. This study reports that the disinfectant which is highly effective in inactivating the suspended cells in water becomes the less effective for controlling biofilm because of its high reactivity. This results imply that the effective strategy for biofilm control can be achieved by considering thoroughly the chemical nature of disinfects and biofilm structure and the reactivity between them.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.4
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• pp.403-409
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• 2017

For dry storage of the spent nuclear fuel (SNF) stored in the storage pool of a nuclear power plant, essentially all moisture must be removed to prevent corrosion of the assembly and canister internals and/or degradation of fuel cladding integrity after SNF canister loading operation. R&D work is now in progress on a forced gas drying system that can be used to remove residual water in canisters. In this work, preliminary design is performed to manufacture the forced gas drying system. This process includes a case study of dry methods for canister moisture removal, relative codes and standards, confirmation of adequate dryness, needs analysis at plant sites, and characteristics of SNF stored in pools. Through this preliminary design work, we obtained a conceptual flow diagram and preliminary P&ID of the forced gas drying system. The results of this study can be used to determine details of the design to manufacture the forced gas drying system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.11
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• pp.355-362
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• 2016

The pipe material is selected according to the physical and chemical properties of the fluid flowing within it. Because the fluid used in fire extinguish systems is water, the various foreign substances dissolved in it cause scale to form on the pipe wall and accelerate the corrosion and aging of the pipe itself. This results in an increase in the friction loss and eventually degrades the efficiency of the pump. The use of CPVC (Chlorinated Poly-Vinyl Chloride) pipes was confirmed to reduce the friction loss compared to conventional steel pipes in the design and construction stages. The friction loss was found to be 76.64MPa with a C-value of 120 for the steel pipe and 50.72 MPa with a C-value of 150 for the CPVC pipe in an actual apartment construction environment. It was confirmed that the friction loss was improved by about 34% when using the CPVC pipe. When the steel and CPVC pipes were employed in the construction, the construction costs were 1,585,158 and 931,842 won, respectively. Therefore, it was shown that the construction cost was reduced by about 41%. We investigated the safety of the fire extinguishing system and the improvement in the economic performance due to the reduction in the total installed capacity by studying practical applications in the field.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
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• v.29 no.2
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• pp.123-127
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• 2003

Chemical burns onto oral mucosa which are infrequent, may result from contact with a wide variety of chemical agents. The degree of injury depends on the chemical, its concentration, duration of contact, and the natural penetrability and resistance of the tissues involved. Chemicals do not usually "burn" in that they do not cause destruction by hyperthermic activity. Rather, they damage tissue by causing coagulation of protein by one of several processes, reduction, oxidation, desiccation, corrosion, or vesication. Paraquat(Gramoxon) is the most frequently agricultural chemicals that induce the severe toxic reactions onto the organs of human body in Korea. The toxic reaction are composed of pulmonary edema and fibrosis, formation of hyaline membrane, inflammatory reaction and bleeding tendency, owing to the cell damage by the production of superoxide radicals. The contents of essential treatment in paraquat intoxication are commonly airway and breathing maintenance, gastric lavage, much hydration and diuresis, hemoperfusion and medications for the removal of the chemicals and the prevention of various complications. The sedative oral dressings, such as, orabase ointment application, warm saline gargling, lidocaine viscous gargling and oral gargling by the mixed solutions(tetracycline, prednisolone and 10% dextrose water) are important for the improvement of chemical oral mucositis and the comfortable feeding of diet. The authors managed properly two cases of oral chemical mucositis that were occurred by the incorrect use of agricultural chemicals(paraquat) and report the cases with the review of literatures about care of the chemical intoxication and oral mucositis.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.307-314
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• 2017

Concrete is a durable and cost-benefit construction material, however performance degradation occurs due to steel corrosion exposed to chloride attack. Penetration of chloride ion usually decreases due to hydrates formation and reduction of pores, and the reduced chloride behavior is considered through decreasing diffusion coefficient with time. In the work, HPC (High Performance Concrete) samples are prepared with 3 levels of W/B (water to binder) ratios of 0.37, 0.42, and 0.27 and 3 levels of replacement ratios of 0%, 30% and 50%. Several tests containing chloride diffusion coefficient, passed charge, and compressive strength are performed considering age effect of 28 days and 180 days. Chloride diffusion is more reduced in OPC concrete with lower W/B ratio and GGBFS concrete with 50% replacement ratio shows significant reduction of chloride diffusion in higher W/B ratio. At the age of 28 days, GGBFS concrete with 50% replacement ratio shows more rapid reduction of chloride diffusion than strength development, which reveals that abundant GGBFS replacement has effective resistance to chloride penetration even in the early-aged condition.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.85-92
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• 2015

The chloride ions, responsible for the initiation of the corrosion mechanism, intrude from the external medium into the concrete. A part of the intruding chloride ions will be retained by the hydration products of the binder in concrete, either through chemical adsorption or by physical adsorption. Since the hydration products of cement are responsible for the chloride binding in concrete, this study focused on the chloride binding in individual hydrate. The purpose of this study is to explore the time dependant behaviors of chloride ions adsorption with cement hydrates, focused on its mechanism. AFt phase and CH phase were not able to absorb chloride ion, however, C-S-H phase and AFm phase had a significant chloride adsorption capacity. In particular, AFm phase showed a chemical adsorption with slow rate in 40 days, while C-S-H phase showed binding behaviors with 3 stages including momentary physical adsorption, physico-chemical adsorption, and chemical adsorption. Based on the results, this study suggested theoretical approach to depict chloride adsorption behavior with elapsed time of C-S-H phase and AFm phase effectively. It is believed that the approach suggested in this study can provide us with a good solution to understand the mechanism on chloride adsorption with hydrates and to calculate a rate of chloride penetration with original source of chloride ions, for example, marine sand at initial time or sea water penetration later on.