• Title/Summary/Keyword: water corrosion

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Dual-mode diagnosis system for water quality and corrosion in pipe using convolutional neural networks (CNN) and ultrasound (합성곱 신경망과 초음파 기반 상수도관 수질 및 부식 분석용 이중모드 진단 시스템)

  • So Yeon Moon;Hyeon-Ju Jeon;Yeongho Sung;Min-Seo Kim;Daehun Kim;Jaeyeop Choi;Junghwan Oh;O-Joun Lee;Hae Gyun Lim
    • Annual Conference of KIPS
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    • 2023.11a
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    • pp.685-686
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    • 2023
  • 상수도관의 수질 및 부식도 검사에는 파이프에 손상을 입히지 않고 지속적인 방법이 필요하다. 초음파는 이를 만족하면서 상태를 확인할 수 있고 주파수가 높을수록 해상도가 좋아져 정밀한 측정이 가능하다는 장점이 있다. 이러한 특성을 이용해 상수도관 모니터링 시스템으로 초음파 기반의 Scanning Acoustic Microscopy(SAM)과 Convolutional Neural Network(CNN)을 사용하는 새로운 방법을 제안한다. 기존의 Non-Destructive Testing(NDT)방식의 단점을 보완하면서 더 높은 해상도로 상수도관을 점검하는 방식으로, SAM 을 이용하여 부식으로 인한 파이프 두께 변화와 부유물의 여부 및 수질을 동시에 감지하고 얻은 데이터를 CNN 으로 분석했다. CNN 의 높은 정확도 결과로 이 시스템의 파이프 부식도 및 수질 모니터링에 대한 적합성을 보여주었다.

System Configuration of Ultrasonic Nuclear Fuel Cleaner and Quantitative Weight Measurement of Removed CRUD (초음파 핵연료 세정장비의 시스템 구성과 제거된 크러드의 정량적 무게 측정법)

  • Jung Cheol Shin;Hak Yun Lee;Un Hak Seong;Yeong Jong Joo;Yong Chan Kim;Wook Jin Han
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.1-6
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    • 2024
  • Crud is a corrosion deposit that forms in equipments and piping of nuclear reactor's primary systems. When crud circulates through the reactor's primary system coolant and adheres to the surface of the nuclear fuel cladding tube, it can lead to the Axial Offset Anomaly (AOA) phenomenon. This occurrence is known to potentially reduce the output of a nuclear power plant or to necessitate an early shutdown. Consequently, worldwide nuclear power plants have employed ultrasonic cleaning methods since 2000 to mitigate crud deposition, ensuring stable operation and economic efficiency. This paper details the system configuration of ultrasonic nuclear fuel cleaning equipment, outlining the function of each component. The objective is to contribute to the local domestic production of ultrasonic nuclear fuel cleaning equipment. Additionally, the paper introduces a method for accurately measuring the weight of removed crud, a crucial factor in assessing cleaning effectiveness and providing input data for the BOA code used in core safety evaluations. Accurate measurement of highly radioactive filters containing crud is essential, and weighing them underwater is a common practice. However, the buoyancy effect during underwater weighing may lead to an overestimation of the collected crud's weight. To address this issue, the paper proposes a formula correcting for buoyancy errors, enhancing measurement accuracy. This improved weight measurement method, accounting for buoyancy effects in water, is expected to facilitate the quantitative assessment of filter weights generated during chemical decontamination and system operations in nuclear power plants.

Temperature-dependent Diffusion Coefficient of Chloride Ion in UAE Concrete (UAE 콘크리트에 대한 염화물 확산의 온도의존성)

  • Ji-Won Hwang;Seung-Jun Kwon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.4
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    • pp.48-54
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    • 2024
  • NPP (Nuclear power plant) structures have been constructed near to the sea shore line for cooling water and exposed to steel corrosion due to chloride attack. Regarding NPP structures built in the UAE, chloride transport may be more rapid than those in the other regions since the temperature near to the coast is high. In this study, concrete samples with 5,000psi (35MPa) design strength grade were manufactured with the materials and mix proportions, which were the same as used in the UAE NPP structures, then chloride diffusion coefficients were evaluated considering temperature and curing age. The compressive strength and the diffusion coefficient were evaluated and analyzed for the samples with 28 and 91 curing days. In addition, chloride diffusion tests for 91-day-cured condition were carried out in the range of 20℃ to 50℃. The activation energy was obtained through converting the temperature slope to a logarithmic function and it was compared with the previous studies. The proposed activation energy can be useful for a reasonable durability design by using actual temperature-dependent chloride diffusion coefficient.

Strategies for Enhancing Zinc Anode Stability and Safety in Aqueous Zinc Secondary Battery (수계 아연 이차 전지 아연 음극 안정성 및 안전성 향상 전략)

  • Jong-Jin Park;Gyeongtae Seo;Yong-Tae Kim
    • Journal of Surface Science and Engineering
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    • v.57 no.5
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    • pp.368-378
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    • 2024
  • The growing environmental concerns due to increased fossil fuel consumption have intensified the demand for sustainable and economically viable energy sources. Among the various energy storage devices, lithium-ion batteries (LIBs) are widely used in electronic devices and electric vehicles due to their high energy density and excellent cycle life. However, LIBs face challenges such as safety concerns due to side reactions, thermal expansion, and explosion risks, along with issues of limited resource availability and high costs. As a result, multivalent metals such as calcium, magnesium, zinc, iron, and aluminum are being explored as alternatives to lithium. Recently, there has been significant interest in developing aqueous zinc-ion battery (AZIB) due to their use of water as an electrolyte solvent, which enhances safety by reducing the risk of fire even in the event of a short circuit. Additionally, AZIBs offer benefits such as non-toxicity, fast ion conductivity, high volumetric capacity, and cost-effectiveness due to the abundance of zinc. Despite these advantages, AZIBs face challenges including dendrite formation on the zinc anode during cycling, leading to short circuits, corrosion, and hydrogen gas evolution, which can compromise battery performance and safety. This review discusses the underlying mechanisms of these issues and explores various strategies to stabilize the zinc anode and improve the overall performance of AZIBs.

Products and pollutants of half dried sewage sludge and waste plastic co-pyrolysis in a pilot-scale continuous reactor (반 건조 하수슬러지와 폐플라스틱 혼합물의 파일롯 규모 연속식 열분해에 의한 생산물과 발생 오염물질)

  • Kim, YongHwa;Chun, Seung-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.327-337
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    • 2017
  • A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

Durability and Crack Control of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 균열제어 및 내구성)

  • Yun, Hyun-Do;Yang, Il-Seung;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.57-64
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    • 2006
  • The crack presented in concrete structures causes a structural defect, the durability decrease, and external damages etc. Therefore, it is necessary to improve durability through the effort to control the crack. Fluosilicic acid($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicates prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.0{\sim}2.0%$ of adding ratio of fluosilicate salt based inorganic compound. To evaluate correlation of concrete strength and adding ratio of fluosilicate salt based inorganic compound, the tests were performed about design strength(21, 24, 27 MPa) with 0.5% of adding ratio of fluosilicate salt based inorganic compound. Applications of fluosilicate salt based inorganic compound to reduce cracks resulted from plastic and drying shrinkage, to improve durability are presented in this paper. Durability was evaluated as neutralization, chloride ion penetration depth, freezing thawing resistant tests and weight loss according reinforcement corrosion. It is ascertained that the concrete added fluosilicate salt based inorganic compound showed m ability to reduce the total area and maximum crack width significantly as compared non-added concrete. In addition, the durability of concrete improved because of resistance to crack and watertightness by packing role of fluosilicate salt based inorganic compound obtained and pozzolanic reaction of soluble $SiO_2$ than non-added concrete.

Experimental Study of Chemical Effects on Head Loss across Containment Sump Strainer under Post-LOCA Environment (LOCA이후 원자로건물집수조 여과기의 수두손실에 대한 화학적 영향의 실험연구)

  • Ku, Hee-Kwan;Jung, Bum-Young;Hong, Kwang;Jung, Eun-Sun;Jeong, Hyun-Jun;Park, Byung-Gi;Rhee, In-Hyoung;Park, Jong-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.12
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    • pp.3748-3754
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    • 2009
  • An integral head loss test in a test apparatus was conducted to simulate chemical effects on a head loss across a strainer in a pressurized water reactor (PWR) containment water pool after a loss of coolant accident (LOCA). The test was conducted during 30 days in the condition of a short spray, a long spray, and no materials with chemical effects. The result exhibited that the head loss was affected on amounts of the exposed materials according to spray conditions. XRD analysis of the collected precipitates showed that the precipitates were phosphate compounds. Comparison of the head loss with dissolved species concentration showed that high increase rate of the head loss resulted from the corrosion of aluminum and zinc but slow increase rate of the head loss resulted from the precipitates induced by Si, Mg, and Ca from leaching reaction at NUKON and concrete after passivation of metal specimens.

Development of a Short-term Failure Assessment of High Density Polyethylene Pipe Welds - Application of the Limit Load Analysis - (고밀도 폴리에틸렌 융착부에 대한 단기간 파손 평가법 개발 - 한계하중 적용 -)

  • Ryu, Ho-Wan;Han, Jae-Jun;Kim, Yun-Jae;Kim, Jong-Sung;Kim, Jeong-Hyeon;Jang, Chang-Heui
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.4
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    • pp.405-413
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    • 2015
  • In the US, the number of cases of subterranean water contamination from tritium leaking through a damaged buried nuclear power plant pipe continues to increase, and the degradation of the buried metal piping is emerging as a major issue. A pipe blocked from corrosion and/or degradation can lead to loss of cooling capacity in safety-related piping resulting in critical issues related to the safety and integrity of nuclear power plant operation. The ASME Boiler and Pressure Vessel Codes Committee (BPVC) has recently approved Code Case N-755 that describes the requirements for the use of polyethylene (PE) pipe for the construction of Section III, Division 1 Class 3 buried piping systems for service water applications in nuclear power plants. This paper contains tensile and slow crack growth (SCG) test results for high-density polyethylene (HDPE) pipe welds under the environmental conditions of a nuclear power plant. Based on these tests, the fracture surface of the PENT specimen was analyzed, and the fracture mechanisms of each fracture area were determined. Finally, by using 3D finite element analysis, limit loads of HDPE related to premature failure were verified.

Structural Design Requirements and Safety Evaluation Criteria of the Spent Nuclear Fuel Disposal Canister for Deep Geological Deposition (심지층 고준위폐기물 처분용기에 대한 설계요구조건 및 구조안전성 평가기준)

  • Kwon, Young-Joo;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.3
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    • pp.229-238
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    • 2007
  • In this paper, structural design requirements and safety evaluation criteria of the spent nuclear fuel disposal canister are studied for deep geological deposition. Since the spent nuclear fuel disposal canister emits high temperature heats and much radiation, its careful treatment is required. For that, a long term(usually 10,000 years) safe repository for the spent nuclear fuel disposal canister should be secured. Usually this repository is expected to locate at a depth of 500m underground. The canister which is designed for the spent nuclear fuel disposal in a deep repository in the crystalline bedrock is a solid structure with cast iron insert, corrosion resistant overpack and lid and bottom, and entails an evenly distributed load of hydrostatic pressure from underground water and high pressure from swelling of bentonite buffer. Hence, the canister must be designed to withstand these high pressure loads. If the canister is not designed for all possible external loads combinations, structural defects such as plastic deformations, cracks, and buckling etc. may occur in the canister during depositing it in the deep repository. Therefore, various structural analyses must be performed to predict these structural problems like plastic deformations, cracks, and buckling. Structural safety evaluation criteria of the canister are studied and defined for the validity of the canister design prior to the structural analysis of the canister. And structural design requirements(variables) which affect the structural safety evaluation criteria should be discussed and defined clearly. Hence this paper presents the structural design requirements(variables) and safety evaluation criteria of the spent nuclear fuel disposal canister.

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Developing an improved water discharge anchor & trap bolt to prevent basic salt penetration to harbor structures (해수 염기 침투방지를 위한 성능개선 형 물배출 앵커 및 트랩볼트 개발에 관한 연구)

  • Ock, Jong-Ho;Moon, Sang-Deok;Lee, Hwa-Sun;Shin, Kyung-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.674-682
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    • 2018
  • Large industrial motors require a large area because of the high risk of shutdown accidents and large industrial accidents due to the lowering of the dielectric strength of the armature windings and overheating problems. Therefore, there is a demand for a large-capacity motor that has small size, light weight, and excellent dielectric strength compared with conventional motors. Superconducting motors have advantages of high efficiency and output power, low size, low weight, and improved stability. This results from greatly increasing the magnetic field generation by using superconductive field coils in rotating machines such as generators and motors. It is very important to design and analyze the cooling system to lower the critical temperature of the wires to achieve superconducting performance. In this study, a field loss analysis and low-temperature heat transfer analysis of the cooling system were performed through the conceptual design of a 100-HP high-temperature superconducting synchronous motor. The field loss analysis shows that a uniform pore magnetic flux density appears when high-temperature superconducting wire is used. The low-temperature heat transfer analysis for gaseous neon and liquid neon showed that a flow rate of 1 kg/min of liquid neon is suitable for maintaining low-temperature stability of the high-temperature superconducting wire.