• Journal of Korean Society of Water and Wastewater
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• v.35 no.6
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• pp.533-544
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• 2021

Ion exchange (IX) performance on the exchanger bed is essentially evaluated for the generation of ultrapure water in electronics and chemical industries and for the corrosion control in nuclear power plants. The breakthrough characteristics of IX bed with multi-component were investigated with both cation- and mixed-IX beds of H- and ETAH-form for four kinds of cation exchange resins by using the combined solution of ethanolamine (ETA) and ammonia (NH₃) at trace NaCl. Unlike major components (ETAH⁺ and NH₄⁺ ), the phenomena of breakthrough and overshooting at bed outlet were not observed by Na⁺ over the test period (> 3 times theoretical exchange capacity of IX bed). The breakthrough from H-form resin bed was sequentially reached by ETAH⁺ and NH₄⁺, while the overshooting was observed for ETAH⁺ at the breakthrough of NH₄⁺. NH₄⁺ was 51.5% higher than ETAH⁺ in terms of the relative selectivity determined with the width of breakthrough zone. At the increased concentration of Na⁺ at bed inlet, the selectivity and the overshooting were decreased and increased, respectively. Na⁺ leakage was higher from ETAH-form resin bed and was not identical for four kinds of cation-exchange resins, which may be reduced by improving the intrinsic property of IX resin.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.4A
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• pp.753-759
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• 2006

To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.

• Journal of Bio-Environment Control
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• v.26 no.4
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• pp.317-323
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• 2017

In this study, the heating performance and the energy saving effect of the heat pump system using hot waste water(waste heat) of the thermal power plant discharged from a thermal power plant to the sea were analyzed. The greenhouse area was $5,280m^2$ and scale of the heat pump system was 120 RT(Refrigeration Ton), which was divided into 30 RT, 40 RT and 50 RT. The heat pump system consisted of the roll type heat exchangers, hot waste water transfer pipes, heat pumps(30, 40, 50 RT), a heat storage tank and fan coil units. The roll type heat exchangers was made of PE(Poly Ethylene) pipes in consideration of low cost and durability against corrosion, because hot waste water(sea water) is highly corrosive. And the heating period was 5 months from October to February. During the heating performance test(12 hours), the inlet water temperature of evaporator was changed from $32^{\circ}C$ to $26^{\circ}C$, and heat absorption of he evaporator was changed from 175 kW to 120 kW. The inlet water temperature of the condenser rose linearly from $15^{\circ}C$ to $50^{\circ}C$, and the heat release of condenser was reduced by 40 kW from 200 kW to 160 kW. And the power consumption of the heat pump system increased from 30 kW to 42 kW. When the inlet water temperature of condenser was $15^{\circ}C$, the heating COP(Coefficient Of Performance) was over 7.0. When it was $30^{\circ}C$, it dropped to 5.0, and when it was above $40^{\circ}C$, it decreased to less than 4.0. It was analyzed that the reduction of heating energy cost was 87% when compared to the duty free diesel that the carbon dioxide emission reduction effect was 62% by recycling the waste heat of the thermal power plant as a heat source of the heat pump system.

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.30-38
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• 2013

In this study, a catalyst slurry was prepared with a Pt/C catalyst, Nafion ionomer solution as a binder, an ionic liquid (IL) (1-butyl-3-methylimidazolium tetrafluoroborate), deionized water and ethanol as a solvent for the application to polymer electrolyte fuel cells (PEFCs) at high-temperatures. The effect of the IL in the electrode of each design was investigated by performing a cyclic voltammetry (CV) measurement. Electrodes with different IL distributions inside and on the surface of the catalyst electrode were examined. During the CV test, the electrochemical surface area (ESA) obtained for the Pt/C electrode without ILs gradually decreased owing to three mechanisms: Pt dissolution/redeposition, carbon corrosion, and place exchange. As the IL content increased in the electrode, an ESA decrement was observed because ILs leaked from the Nafion polymer in the electrode. In addition, the CVs under conditions simulating leakage of ILs from the electrode and electrolyte were evaluated. When the ILs leaked from the electrode, minor significant changes in the CV were observed. On the other hand, when the leakage of ILs originated from the electrolyte, the CVs showed different features. It was also observed that the ESA decreased significantly. Thus, leakage of ILs from the polymer electrolyte caused a performance loss for the PEFCs by reducing the ESA. As a result, greater entrapment stability of ILs in the polymer matrix is needed to improve electrode performance.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.3
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• pp.313-318
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• 2012

In CANDU, feeder pipes supply heavy water to pressure tube and steam generator. Under service conditions, Flow-Accelerated Corrosion (FAC) produces local wall-thinning in the feeder pipes. The wall-thinning in these pipes affects the integrity of the piping system, as verified in previous research. This paper provides limit loads for wallthinned feeder pipes with $45^{\circ}$ and $60^{\circ}$ bend angles, and proposes an equation that predicts the limit loads for wallthinned feeder pipes with arbitrary bend angles. On the basis of finite element limit analyses, limit loads are obtained for wall-thinned feeder pipes under in-plane bending and internal pressure. There are two cases of in-plane bending: the in-plane closing direction and the in-plane opening direction. The material is considered the effect of the large deformation, so an elastic-perfectly-plastic material is assumed in the calculations.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.4
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• pp.783-794
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• 1994

Recently, several failure cases of concrete structures during construction have been reported. The main reason for these failures is attributed to the poor quality of concrete during construction. It is, therefore. necessary to develop and use high quality concrete. The purpose of the present study is to explore the characteristics of superplasticized concrete, especially the effects of mineral admixtures on the fluidity and strength characteristics of high performance concrete. The mineral admixtures considered in the present study are fly ash, blast furnace slag and silica fume, respectively. The major test variables include the amount of these mineral admixtures, cement contents and water-cement ratios. The compressive strengths for various cases were measured and reported. Optimum contents of mineral admixtures for strength development were derived. The corrosion phenomena of reinforcements embedded in various concrete specimens have been also studied. The present study provides useful basis to apply high-performance concrete to actual structures.

• KEPCO Journal on Electric Power and Energy
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• v.4 no.1
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• pp.25-31
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• 2018

A boiler system transforms water to pressured supercritical steam which drives the running of the turbine to rotate in the generator to produce electricity in power plants. Materials for building the tube system face challenges from high temperature creep damage, thermal fatigue/expansion, fireside and steam corrosion, etc. A database on the creep resistance strength and steam oxidation of the materials is important to the long-term reliable operation of the boiler system. Generally, the ferritic steels, i.e., grade 1, grade 2, grade 9, and X20, are extensively used as the superheater (SH) and reheater (RH) in supercritical (SC) and ultra supercritcal (USC) power plants. Currently, advanced austenitic steel, such as TP347H (FG), Super304H and HR3C, are beginning to replace the traditional ferritic steels as they allow an increase in steam temperature to meet the demands for increased plant efficiency. The purpose of this paper is to provide the state-of-the-art knowledge on boiler tube materials, including the strengthening, metallurgy, property/microstructural degradation, oxidation, and oxidation property improvement and then describe the modern microstructural characterization methods to assess and control the properties of these alloys. The paper covers the limited experience and experiment results with the alloys and presents important information on microstructural strengthening, degradation, and oxidation mechanisms.

• Journal of Environmental Health Sciences
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• v.28 no.5
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• pp.13-21
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• 2002

This study analyzed the characteristic of basic river structure, a flood level, the tree planting recommendation and syn thetic design, in order to establish a basic plan for preparing a natural practical area of environmental ecosystem at Bukchun and its surroundings. It was also investigated based on the opinion of citizens, geographical condition and the equipment/utilization examination of Bukchun which were included ecological circumstances, and thus provided a composite item for managing the natural river. This study also considered the development of the river in terms of culture, environment and ecology concept. The results were summarized as followed. Bukchun showed that the speed of a funning fluid is very fast on a period of flood. but very slow in a period of water shortage about 0.02 m/s. To prevent the speed change of a running fluid by a steep slope in a riverbed, there established Dongchun sluice gates under a bridge, including three sluice gates under a bridge, but there occurred extremely a riverbed erosion and corrosion section. The result of comparison between real flood degree and prediction flood data, there should perform a countermeasure the riverbed structure regulation of this area. Also, it was needed an exhaustive flood management in summer. According to the Bukchun and Hyungsangang riverbed investigation, there were needed preparation for natural/practical area and ecology Park development in the future. This study was investigated tree Planting/flower/blossom around the Bukchun and its surroundings. It was recommended willow, Italian poplar, bamboos and cherry blossoms in the Hyungsangang and Bukchun. There exist together historical space, environment space iud have enough possibility both natural learning space and civil rest space. And, it is possible to compose ecology natural learning and experimental area.

• Composites Research
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• v.27 no.2
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• pp.59-65
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• 2014

Most of energy are obtained from oil, coal, and natural gas, most likely, fossil fuel which is limited throughout the world. Recently, high crude oil price, climate change, oil depletion, etc. are main reason to get attention to non-fossil energy including renewable energy in the world. In this study, we studied analysis and design of structure system composed of pultruded fiber reinforced polymer composite (PFRP) which has many advantages such as high specific strength and stiffness, high corrosion resistance and chemical resistance. For the design and construction of floating-type structure, PFRP structural members may be the first choice. Design of tracking-type floating PV generation structure was performed by using the results of the finite element analysis. The structure is fabricated and installed on the water surface. Before the installation of the structure, safety related problems associated with installation and operation are investigated using the finite element simulation and it was found that the structure is safe enough to resist externally applied loads.

• Laser Solutions
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• v.12 no.3
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• pp.18-22
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• 2009

Experimental results for the laser shock peening of stainless steels, duplex stainless steel and STS304, for the enhancement of surface hardness are reported. A high power Nd:YAG laser (532 nm, 2nd harmonics) was used to irradiate the workpiece in water at the irradiances of 5, 10, $15\;GW/cm^2$. The surface of a workpiece was covered with Fe or Al foil for protection of the original surface and reduction of laser reflection. The laser pulse densities were varied from $25\;pulse/mm^2$ to $75\;pulse/mm^2$. In the case of the STS304, the surface hardness increased with increasing pulse density and the maximum increase of about 29% was achieved using Fe foil at $10\;GW/cm^2$ and $75\;pulse/mm^2$ conditions. The maximum increase in surface hardness of duplex stainless steel was about 8% at $10\;GW/cm^2$ and $75\;pulse/mm^2$ with also Fe foil. In the case of the Al foil, less increase of surface hardness was obtained, possibly due to the thermal expansion effect.