• Korean Journal of Materials Research
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• v.29 no.1
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• pp.1-6
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• 2019

Recent industrialization has led to a high demand for the use of fossil fuels. Therefore, the need for producing hydrogen and its utilization is essential for a sustainable society. For an eco-friendly future technology, photoelectrochemical water splitting using solar energy has proven promising amongst many other candidates. With this technique, semiconductors can be used as photocatalysts to generate electrons by light absorption, resulting in the reduction of hydrogen ions. The photocatalysts must be chemically stable, economically inexpensive and be able to utilize a wide range of light. From this perspective, cuprous oxide($Cu_2O$) is a promising p-type semiconductor because of its appropriate band gap. However, a major hindrance to the use of $Cu_2O$ is its instability at the potential in which hydrogen ion is reduced. In this study, gold is used as a bottom electrode during electrodeposition to obtain a preferential growth along the (111) plane of $Cu_2O$ while imperfections of the $Cu_2O$ thin films are removed. This study investigates the photoelectrochemical properties of $Cu_2O$. However, severe photo-induced corrosion impedes the use of $Cu_2O$ as a photoelectrode. Two candidates, $TiO_2$ and $SnO_2$, are selected for the passivation layer on $Cu_2O$ by by considering the Pourbaix-diagram. $TiO_2$ and $SnO_2$ passivation layers are deposited by atomic layer deposition(ALD) and a sputtering process, respectively. The investigation of the photoelectrochemical properties confirmed that $SnO_2$ is a good passivation layer for $Cu_2O$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.124-132
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• 2022

The corrosion potential in concrete varies greatly with exposure and concrete mix conditions. In this study, RC (Reinforcement Concrete) samples were prepared considering cover depth, chloride concentration, and W/C(water to cement) ratio as variables, and HCP(Half Cell Potential) was measured, which evaluated comparative potential between embedded steel and concrete surface. In addition, OCP(Open Circuit Potential) was measured using buried steel and CE(Counter Electrode). Agar and NaOH solution were used as ion exchange materials and Hg/HgO was used for RE(Reference Electrode), which was more sensitive to temperature than HCP. Among the influencing factors, the exposure period and chloride concentration had a relatively greater effect than cover depth and w/c ratio. Additionally, the entire measured HCP and OCP showed a clearly linear relationship with increasing cover depth and w/c ratio. Through multiple regression analysis, the relationship between HCP and OCP was quantified, and an improved correlation was obtained with temperature effect.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.420-420
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• 2021

상수도관은 시간이 경과됨에 따라 부식이 발생하고 이로 인해 관의 두께 및 강도가 감소하여 점차 상수도관의 기능을 상실하게 된다. 이러한 노후 상수도관은 누수, 적수 등 수자원에 막대한 경제적인 손실을 발생시키고 사람들에게 많은 불편을 끼친다. 현재 우리나라도 전체 상수도관 중 노후 상수도관이 많은 부분을 차지하고 있기 때문에 교체나 개선이 시급한 실정이다. 하지만 전체 상수도관을 교체하는 것은 막대한 예산이 필요하기 때문에 현실적으로 어려운 문제이다. 따라서 상수도관의 노후도 분석을 통하여 상수관망의 최적 교체 우선순위를 판단하고 교체를 실시하는 것이 필요하다. 본 연구에서는 노후도 분석에 중요한 관의 부식깊이와 잔존수명을 예측하고 신뢰성해석을 통해 파괴확률을 산정하였다. 이를 위해 Romanoff(1957)와 환경부(2002)에서 실측한 상수관의 관종에 따른 관두께 변화를 적용하여 해석하였다. 실측 자료를 통해 부식깊이, 잔존수명 예측 모델을 수립하였으며 이에 따른 관의 파괴확률을 산정하였다. Romanoff(1957)의 혼합강관과 주철관에 대한 실측 자료를 사용하여 상수관의 사용연수가 10년, 20년, 30년 경과됨에 따른 부식깊이와 관파괴확률을 산정하였다. 혼합강관의 경우 사용연수에 따른 부식깊이는 0.57mm, 0.92mm, 1.21mm으로 산정되었으며, 주철관의 경우 0.16mm, 0.24mm, 0.31mm으로 산정되었다. 또한 신뢰성모형을 직경 300mm관에 적용한 결과 최대 상수도압 15kg/cm²에서 혼합강관의 사용연수에 따른 파괴확률은 3.36%, 4.65%, 6.18%로 나타났으며 주철관은 1.36%, 2.50%, 2.68%로 나타났다. 환경부(2002)의 주철관에 대한 부식 실측 자료를 통해 상수관의 사용연수 10년, 20년, 30년 경과에 따른 부식깊이와 관파괴확률을 산정하였으며 초기 관두께 측정 자료를 통해 잔존수명도 예측하였다. 부식깊이는 1.02mm, 1.25mm, 1.41mm으로 산정되었으며, 파괴확률은 5.15%, 6.30%, 7.35%로 산정되었다. 그리고 잔존수명의 경우 부식률이 20%일 때, 잔존수명은 약 30년으로 산정되었다.

• Magazine of the Korean Society of Agricultural Engineers
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• v.14 no.2
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• pp.2622-2633
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• 1972

This study was attempted in order to search for phyosical properties on various mix designs of concrete as ne of studies relating top revention against corrosion by action of sea water in the West Sea. In this study, as concerete mix design, fly ash, pozzolith and vinsolresin were used as admixtures for normal portland cement respectively, and pozzolan cement and normal cement were also used for each plain concrete. Concrete specimens were made and cured in accordance with the Korean Standard Specifications for concrete. In thetest, compressive strengths of the specimens were measured at the following ages; 7-day, 28-days and 3-months. Absorption test was made by immersing the specimens in water kept at boiling temperature for 5 hours. The results obtained from the tests are summarized as follows; 1. The use of fly ash as an admixture in mix design of concrete, has an effect on compressive strength at each age. But it is actually not effective on absorption by concrete, as the result of the fly ash concrete is almost the same at that of ordinary plain concrete. 2. The use of pozzolith as an admixture in mix design of concrete, has an effect on both of compressive strength at each age and absorption rate. The pozzolith is more effective than vinsol resin, relating to improvement for physical proreties of concrete. 3. The use of vinsol resin as an admixture in mix design of concrete, has also an effect on both of compressive strength at each age and absorption rate. As the above fact, effectiveness of the vinsol resin is some what lower than pozzolith, as far as physical properties of the concrete are concerned. 4. Plain concrete used pozzolan cement only is the most effective on both of strength at each age and absorption rate in this study. The pozzolan cement is characteristic of higher strenth as the age is later. 5. Relationship between compreessive strengths and absorption rates of the concrete is shown by a different regression line dependingon ages. The gradient of the regression line is steeper as the age is later. 6. Throught physical test, it may be expected that the use of pozzolith and vinsol resinas asan admixture respectively will be better resistant than fly ash or ordinary plain concrete and that plain pozzolan concrete will also be the best resistant to action of sea water due to improvement of theirphysical properties.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.13-29
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• 2016

In this study, we analyzed the causes of major faults in the biogas plant through the case of gas engine failure when cogenerating electricity and heat using biogas as a fuel in the actual sewage treatment plant and suggested countermeasures. Hydrogen sulfide in the biogas entering the biogas engine and water caused by intermittent malfunction of the water removal system caused intercooler corrosion in the biogas engine. In addition, the siloxane in the biogas forms a silicate compound with silicon dioxide, which causes scratches and wear of the piston surface and the inner wall of the cylinder liner. The substances attached to the combustion chamber and the exhaust system were analyzed to be combined with hydrogen sulfide and other impurities. It is believed that hydrogen sulfide was supplied to the desulfurization plant for a long period of time because of the high content of hydrogen sulfide (more than 50ppm) in the biogas and the hydrogen sulfide was introduced into the engine due to the decrease of the removal efficiency due to the breakthrough point of the activated carbon in the desulfurization plant. In addition, the hydrogen sulfide degrades the function of the activated carbon for siloxane removal of the adsorption column, which is considered to be caused by the introduction of unremoved siloxane waste into the engine, resulting in various types of engine failure. Therefore, hydrogen sulfide, siloxane, and water can be regarded as the main causes of the failure of the biogas engine. Among them, hydrogen sulfide reacts with other materials causing failure and can be regarded as a substance having a great influence on the pretreatment process. As a result, optimization of $H_2S$ removal method seems to be an essential measure for stable operation of the biogas engine.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.7
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• pp.875-881
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• 2013

The failure of a bolted joint owing to stress corrosion cracking (SCC) has been considered one of the most important structural integrity issues in a nuclear power plant. In this study, the failure possibility of bolting, which is used to support the steam generator of a pressurized water reactor, owing to SCC and brittle fracture was evaluated in accordance with guidelines proposed by the Electric Power Research Institute, which are called the Reference Flaw Factor method. For this evaluation, first, detailed finite element stress analyses were conducted to obtain the actual nominal stresses of bolting in which either service loads or bolt preloads were considered. Based on these nominal stresses, the structural integrity of bolting was addressed from the viewpoints of SCC and toughness. In addition, the accuracy of the EPRI Reference Flaw Factor for assessing bolting failure was investigated using finite element fracture mechanics analyses.

• Journal of the Korea Concrete Institute
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• v.15 no.1
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• pp.25-34
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• 2003

The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures by chloride attack followed by reinforcement corrosion is one of the serious problems. An objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a chloride ingress model, consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water, was proposed. Moreover, the variability of chloride ion diffusivity due to the degree of hydration of cement, relative humidity in pore, exposure condition, and variation of chloride binding, was considered in the model. In order to verify the proposed model, the results predicted by the proposed model were compared with analysis results of Life-365, a computer program for predicting the service life of reinforced concrete structures exposed to chlorides. In conclusion, the proposed model would be promising to predict the chloride ion profile and to estimate the service life of RC structures.

• Journal of Hydrogen and New Energy
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• v.24 no.3
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• pp.223-229
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• 2013

Polymer Electrolyte Membrane Fuel Cell (PEMFC) is a power generation system to convert chemical energy of fuels and oxidants to electricity directly by electrochemical reactions. As a catalyst support for PEMFCs, carbon black has been generally used due to its large surface area and high electrical conductivity. However, under certain circumstances (start up/shut down, fuel starvation, ice formation etc.), carbon supports are subjected to serve corrosion in the presence of water. Therefore, it would be desirable to switch carbon supports to corrosion-resistive support materials such as metal oxide. $TiO_2$ has been attractive as a support with its stability in fuel cell operation atmosphere, low cost, commercial availability, and the ease to control size and structure. However, low electrical conductivity of $TiO_2$ still inhibits its application to catalyst support for PEMFCs. In this paper, to explore feasibility of $TiO_2$ as a catalyst support for PEMFCs, $TiO_2$ nanofibers were synthesized by electrospinning and calcinated at 600, 700, 800 and $900^{\circ}C$. Effects of calcination temperature on crystal structure and electrical conductivity of electrospun $TiO_2$ nanofibers were examined. Electrical conductivity of $TiO_2$ nanofibers increased significantly with increasing calcination temperature from $600^{\circ}C$ to $700^{\circ}C$ and then increased gradually with increasing the calcination temperature from $700^{\circ}C$ to $900^{\circ}C$. It was revealed that the remarkable increase in electrical conductivity could be attributed to phase transition of $TiO_2$ nanofibers from anatase to rutile at the temperature range from $600^{\circ}C$ to $700^{\circ}C$.

• Journal of Navigation and Port Research
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• v.30 no.6 s.112
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• pp.447-455
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• 2006

Together with the trend of enhancement in domestic industrial development and economic progress due to import and export, the demand for construction of the roads, bridges, especially port facilities, and several coastal protection and ocean structures is increasing rapidly. MOMAF of Korean Government is driving construction cf 9 new ports and renovation cf the existing fishery ports. Among these structures most of bridge base, wharves, dolphins, quays, and jetties are being newly built cf steel or concrete pile. As the base, supporting bulkheads, and piles are underwater after construction, it is difficult to figure out the status of structures and not enough to get maintenance and strengthen the structures. Every year, moreover, these works suck the government budget due to higher incomplete maintenance expense for protection from corrosions cf structures and increased underwater construction period. For the purpose cf cutting down the expense cf government budget, it is necessary to extend the life cycle of the existing structures. Therefore, we developed a new method for maintenance of submerged structures near the waterline by allowing dry work environment with the floating caisson. The method shows easy to move around the working area and handle. It also showed not only a significant reduction of maintenance expenses and time for anti-corrosion work but also better protection This will be a milestone to reduce the maintenance and construction expenses for the shore and water structures.

• Journal of the Korea Concrete Institute
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• v.19 no.3
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• pp.367-375
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• 2007

Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.