• Title/Summary/Keyword: water corrosion

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A Scientific Analytical on the Ancient Shipwrecks Degradation Products Excavated from Underwater: Focused on Sulfur and Iron Degradation Products

  • Ji-Seon SONG;Yong-Hee YOON;Chang-Hyun PARK
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.3
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    • pp.243-261
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    • 2024
  • In this study, samples were collected from various ancient wooden shipwrecks, including the Shinan shipwreck and Jindo shipwreck that used iron nails, the Yeongheungdo shipwreck carrying iron artifacts, as well as the Sibidongpado shipwreck and Wando shipwreck where degradation products were not observed, all of which were salvaged by the National Research Institute of Maritime Heritage. The aim was to analyze the characteristics of degradation products generated by iron (Fe) within the salvaged wooden shipwreck materials and establish fundamental data on degradation products in waterlogged archaeological wood. The analysis revealed that sulfur (S) is generally accumulated in wood obtained from marine environments. It was observed that the content of inorganic substances such as iron and sulfur was significantly higher in the Shinan shipwreck, Jindo shipwreck, and Yeongheungdo shipwreck compared to Sibidongpado shipwreck and Wando shipwreck, which used wooden nails. This indicates that the presence of iron affects the accumulation of degradation products and suggests that iron is a factor in the corrosion of wood. Furthermore, crystallin compounds were observed within the cell walls, and higher concentrations of iron and sulfur were found in the resin ducts, rays, and radial tissues. This suggests that during desalination and consolidation treatments, warm water or polyethylene glycol (PEG) may move degradation factors into resincanals, rays, radial tissues, etc.

Impact of Wet Etching on the Tribological Performance of 304 Stainless Steel in Hydrogen Compressor Applications

  • Chan-Woo Kim;Sung-Jun Lee;Chang-Lae Kim
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.71-77
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    • 2024
  • Hydrogen has emerged as an eco-friendly and sustainable alternative to fossil fuels. However, the utilization of hydrogen requires high-pressure compression, storage, and transportation, which poses challenges to the durability of compressor components, particularly the diaphragm. This study aims to improve the durability of 304 stainless steel diaphragms in hydrogen compressors by optimizing their surface roughness and corrosion resistance through wet etching. The specimens were prepared by immersing 304 stainless steel in a mixture of sulfuric acid and hydrogen peroxide, followed by etching in hydrochloric acid for various durations. The surface morphology, roughness, and wettability of the etched specimens were characterized using optical microscopy, surface profilometry, and water contact angle measurements. The friction and wear characteristics were evaluated using reciprocating sliding tests. The results showed that increasing the etching time led to the development of micro/nanostructures on the surface, thereby increasing surface roughness and hydrophilicity. The friction coefficient initially decreased with increasing surface roughness owing to the reduced contact area but increased during long-term wear owing to the destruction and delamination of surface protrusions. HCl-30M exhibited the lowest average friction coefficient and a balance between the surface roughness and oxide film formation, resulting in improved wear resistance. These findings highlight the importance of controlling the surface roughness and oxide film formation through etching optimization to obtain a uniform and wear-resistant surface for the enhanced durability of 304 stainless steel diaphragms in hydrogen compressors.

Estimation of residual stress in dissimilar metals welding using deep fuzzy neural networks with rule-dropout

  • Ji Hun Park;Man Gyun Na
    • Nuclear Engineering and Technology
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    • v.56 no.10
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    • pp.4149-4157
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    • 2024
  • Welding processes are used to connect several components in nuclear power plants. These welding processes can induce residual stress in welding joints, which has been identified as a significant factor in primary water stress corrosion cracking. Consequently, the assessment of welding residual stress plays a crucial role in determining the structural integrity of welded joints. In this study, a deep fuzzy neural networks (DFNN) with a rule-dropout method, which is an artificial intelligence (AI) method, was used to predict the residual stress of dissimilar metal welding. ABAQUS, a finite element analysis program, was used as the data collection tool to develop the AI model, and 6300 data instances were collected under 150 analysis conditions. A rule-dropout method and genetic algorithm were used to optimize the estimation performance of the DFNN model. DFNN with the rule-dropout model was compared to a deep neural network method, known as a general deep learning method, to evaluate the estimation performance of DFNN. In addition, a fuzzy neural network method and a cascaded support vector regression method conducted in previous studies were compared. Consequently, the estimation performance of the DFNN with the rule-dropout model was better than those of the comparison methods. The welding residual stress estimation results of this study are expected to contribute to the evaluation of the structural integrity of welded joints.

Linear Static Structural Analysis of the Disposal Container for Spent Pressurized Water Reactor and Canadian Deuterium and Uranium Reactor Nuclear Fuels (차압경수로 및 중수로 폐기물 처분장치에 대한 선형정적 구조해석)

  • 권영주;강신욱
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.14 no.4
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    • pp.515-523
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    • 2001
  • In this paper results of a linear structural analysis for design and dimensioning of disposal containers for spent pressurized water reactor nuclear fuel and spent Canadian deuterium and uranium reactor nuclear fuel are presented. The container structure studied here is a solid structure with a cast insert and a corrosion resistant outer shell, which is designed for the spent nuclear fuel disposal in a deep repository. An evenly distributed load of hydrostatic pressure from the groundwater and large swelling pressure from the bentonite buffer are applied on the container. Hence, the container must be designed to endure these large pressure loads. In this study, the array type of inner baskets and thicknesses of outer shell and lid/bottom are attempted to be determined through a linear static structural analysis.

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A Study on the Performance of Pipe Scale Cleaner using Natural Organic Acid (천연 유기산을 이용한 배관 스케일 세정제 성능에 관한 연구)

  • Kang, Hyung Seok;Yang, Won Suk;Kim, Young Il;Kim, Sean Hay;Choi, Dong Hee
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.10
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    • pp.530-537
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    • 2017
  • Scales generated inside pipes cause negative effects on heat transfer performance, pressure loss and flow rate due to increased thermal resistance and reduced flow cross-sectional area. If these scales are not prevented or eliminated, thermal-fluid performance of the facilities can be deteriorated, or in extreme cases, accidents such as explosion due to overheating can occur. There are two ways to remove the scales, physically and chemically. Removing the scales physically needs specific machines which are expensive, and removing them chemically may provoke corrosion or shorten the age of the facilities. In this study, an eco-friendly pipe scale cleaner using natural organic acid is developed by applying the concept of a limestone cave generation. The manufactured scale cleaner is applied to remove the scales in industrial, water heating and urinal pipes. The results show that this cleaner removes scales more effectively and safely compared to existing scale treatments. Scale removal efficiencies of this work is 1.2~10.7 times for industrial pipes and 1.8~15.5 times for boiler water heating pipes higher than those of conventional cleaners.

The Characteristics of Bubbles in a Column Heat Exchanger for the Application of Direct Contact LNG Evaporator (직접접촉식 LNG기화기 응용을 위한 칼럼 열교환기 기포특성에 관한 연구)

  • Kim, S.J.;Han, S.T.;Kim, J.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.2
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    • pp.142-151
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    • 1991
  • In the present investigation, it has been proposed to utilize a direct contact heat exchanger as an evaporator to solve the difficulties such as scaling, corrosion and law thermal efficiencies, associated with the conventional evaporator. Liquified nitrozen was utilized as a working fluid to investigate basic natures of bubble dynamics in the evaporator, and spray nozzles were adopted to inject liquified nitrozen into the spray column with varying flow rates of dispersed phase fluids. Experimentations were carried out in the range of $6.54{\times}10^{-4}kg/s$ - 0.030 kg/s for dispersed phase flow rates with one, three and five nozzle holes. Observing the bubble dynamics for the evaporator the feasibility of utilizing a direct contact heat exchanger as a LNG evaporator has been evaluated. The results show that no eruption phenomena was observed in the present investigation with $LN_2$ and the interface between $N_2$ bubbles and water was fully turbulent. It is believed that the high injection velocity of $LN_2$ through the spray nozzles provide good mixing effects for both heat and mass transfers between water and $N_2$ bubbles. Ice was formed on the surface of the spray nozzle for higher $LN_2$ flow rates. However, even in this case, it is observed that the ice was detached as soon as it was formed. Under the present experimental conditions, the shapes of $LN_2$ bubbles were in the spherical-cap region according to the Clift, Grace and Weber Graphs. The height of foam region caused by the breakup of larger bubbles keeps increasing with high injection velocities until it reaches it's maximum height.

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The Study on Salt Injury and Carbonation of Reinforced-Concrete (철근콘크리트의 염해와 중성화 피해 사례 연구)

  • Kim, Dong-Hun;Lim, Nam-Gi;Lee, Sang-Beam
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.2
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    • pp.165-172
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    • 2002
  • A reinforced concrete building neighboring in Pusan or Ulsan where is directly exposed to salt water contrasting with other in land areas contains much salt content percolated from the outside that the high salt content percolates and diffuses through the inside of reinforced concrete; therefore, an immovable tunic surrounding it begins to be destroyed and eroded with high speed. At the time, the cross-sectional area and volume expansion of re-bar reinforcing result in being cracks make a rapid progress gradually until they appear in the surface of the one, the phenomenon such as being a thin layer or falling off the part of it causes a lowering of its durability and might collapse the concrete construction. So far, we've investigated into salt content of reinforced concrete constructions neighboring in a seaside district and damage by carbonation, and we came to a conclusion as follows: $\circled1$ Under the oceanic circumstance a concrete construction is influenced by sea water directly that contains much amount of salt content contrasting with other constructions on inland areas. $\circled2$ Because of chloride penetration the carbonation of reinforced concrete made a rapid progress until more than the covering thickness of re-bar. $\circled3$ An old reinforced concrete building which has been piled up salt injury and proceeding the carbonation of its cross-sectional area. $\circled4$ According to rapidly cracking from the inside to surface of reiforced concrete, the phenomenon of being a thin layer or falling off the part of reinforced concrete results in a lowering of durability and shortening the life-time of concrete construction itself.

A Study on the Properties of Epoxy Based Powder Coating with Various Curing Agents (에폭시 분체도료의 경화제 종류에 따른 물성에 관한 연구)

  • Park, Jae-Hong;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.58-65
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    • 1998
  • Substituted dicyandiamide(Sub-DICY), Accelerated dicyandiamide(Acc-DICY), Trimellitic anhydride(TMA), Pyromellitic dianhydride(PMDA) and Phenolic curing agent(Ph.C.A.) are mainly used for epoxy powder coating curing agent. Various characteristics of epoxy films fully cured by optimum condition such as mechanical properties like $T_g$, tensile strength, elongation at break hardness, abrasion resistance and chemical properties like water absorption, acid resistance, alkali resistance and electrical properties, corrosion resistance are determined by various measuring devices and analyses devices. In conclusion, phenolic curing agent was shown excellent thoughness but severe color change as temperature increased. Acid anhydride has excellent insulation properties and color stability at elevated temperature but lower thoughness and adhesion to substrate. DICY curing agent was shown high water absorption and severe color chance as temperature increased.

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Fretting Wear Characteristics of the Corroded Fuel Cladding Tubes for Nuclear Fuel Rod against Supporting Girds (부식된 핵연료 피복관과 지지격자 사이의 프레팅 마멸 특성)

  • Kim, Jin-Seon;Park, Se-Min;Kim, Yong-Hwan;Lee, Seung-Jae;Lee, Young-Ze
    • Tribology and Lubricants
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    • v.23 no.3
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    • pp.130-133
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    • 2007
  • Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.

Fretting Wear Characteristics of the Corroded Fuel Cladding Tubes for Nuclear Fuel Rod against Supporting Girds (부식된 핵연료 피복관과 지지격자 사이의 프레팅 마멸 특성)

  • Lee, Young-Ze;Kim, Jin-Seon;Park, Se-Min;Kim, Yong-Hwan;Lee, Seung-Jae
    • Tribology and Lubricants
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    • v.24 no.3
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    • pp.129-132
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    • 2008
  • Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.