• Title/Summary/Keyword: water corrosion

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The Effect of Cold Work on Primary Water Stress Corrosion Cracking of $\textrm{INCONEL}_{TM}$ Alloy 600 Nuclear Power Steam Generator Tube Material (원전 증기발생기 전열관용 $\textrm{INCONEL}_{TM}$ Alloy 600의 1차측 응력부식균열에 미치는 냉간변형의 영향)

  • Lee, Deok-Hyeon;Han, Jeong-Ho;Kim, Gyeong-Mo;Kim, Jeong-Su;Lee, Eun-Cheol
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.726-732
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    • 1998
  • 가압 경수로형 원전에 사용되는 Alloy 600 증기발생기 전열관재료의 입계응력부식균열 거동에 미치는 냉간변형의 영향을 1차 냉각수 모사조건에서 정속인장시험방법으로 조사하였다. 인장 냉간변형은 응력부식균열을 크게 가속화 시키지는 않았으며 변형량이 25%이상인 경우에는 응력부식균열이 발생하지 않았다. 이 현상은 냉간 변형량 및 형태에 따른 미소변형 및 응력의 불균질성에 영향을 받는 것으로 사려되며 응력의 크기는 직접적인 영향을 주지 않는 것으로 보인다. 국부적인 큰 응력구배가 존재하는 경우 균열의생성 및 성장이 현저히 가속화되었는데 이는 원전 1차측 응력부식균열 기구가 응력구배에 의존하는 과정과 연관되어 있다는 증거이다. Hump 시편을 이용한 정속인장시험방법은 짧은 실험기간내에 원전 1차측 응력부식균열 특성을 평가할 수 있는 방법이었다.

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Influence of Cement Type on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 시멘트 종류의 영향)

  • Park, Jae-Im;Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Cha, Soo-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.573-576
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-binder(W/B) ratio, age, cement type and constituents, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of cement type on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. For this purpose, the diffusion characteristics in concrete with cement type such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) were estimated for the concrete with W/B ratios of 32% and 38%, respectively. It was observed from the test that the difussion characteristics of BBC containing OPC and ground granulated blast-furnace slag was found to be most excellent of the cement type used in this study.

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A Mitigation Methode of DC Stray Current for Underground Metallic Structures in KOREA (국가 기간 시설물의 전식 대책(안))

  • Bae, Jeong-Hyo;Ha, Yoon-Cheol;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1609-1611
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    • 2007
  • The owner of underground metallic structures (gas pipeline, oil pipeline, water pipeline, etc) has a burden of responsibility for the corrosion protection in order to prevent big accidents like gas explosion, soil pollution, leakage and so on. So far, Cathodic Protection(CP) technology have been implemented for protection of underground systems. The stray current from DC subway system in Korea has affected the cathodic protection (CP) system of the buried pipelines adjacent to the railroads. In this aspect, KERI has developed a various mitigation method, drainage system through steel bar under the rail, a stray current gathering mesh system, insulation method between yard and main line, distributed ICCP(Impressed Current Cathodic System), High speed response rectifier, restrictive drainage system, Boding ICCP system. In this paper, the mechanism of mitigation method of DC stray current for underground metallic structures is described.

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A Case Study(1) of Mitigation Methode of DC Stray Current for Underground Metallic Structures in KOREA (국가기간시설물의 전식대책(안) 및 그 적용 사례(1))

  • Bae, Jeong-Hyo;Ha, Yoon-Cheol;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1612-1614
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    • 2007
  • The owner of underground metallic structures (gas pipeline, oil pipeline, water pipeline, etc) has a burden of responsibility for the corrosion protection in order to prevent big accidents like gas explosion, soil pollution, leakage and so on. So far, Cathodic Protection(CP) technology have been implemented for protection of underground systems. The stray current from DC subway system in Korea has affected the cathodic protection (CP) design of the buried pipelines adjacent to the railroads. In this aspect, KERI has developed a various mitigation method, drainage system through steel bar under the rail, a stray current gathering mesh system, insulation method between yard and main line, distributed ICCP(Impressed Current Cathodic System), High speed response rectifier, restrictive drainage system. We installed the mitigation system at the real field and test of its efficiency in Busan and Seoul, Korea. In this paper, the results of field test, especially, distributed ICCP system is described.

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Fatigue Crack Propagation Characteristics of Duplex-Stainless Steel Weldment (III) (2상계 스테인리스강 용접부의 피로크랙전파 특성 (III))

  • 이택순;권종완
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.901-910
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    • 1989
  • Corrosion fatigue crack propagation behavior of duplex stainless steel weldments in substitute ocean water was investigated to evalulate effects of micro-structural change and residual stresses. Fatigue crack propagation rate was found influenced markedly .alpha./.gamma. phase ratio but little by residual stresses. Fatigue crack propagation rate is higher in the corrosive environment than in room atmosphere. The crack propagation rate estimated by the measurement of striation spacing was higher than that, obtained by crack length measurement in low .DELTK.K region. At hight .DELTK.K region, however, both crack propagation rates were found to be identical.

LARGE SCALE FINITE ELEMENT THERMAL ANALYSIS OF THE BOLTS OF A FRENCH PWR CORE INTERNAL BAFFLE STRUCTURE

  • Rupp, Isabelle;Peniguel, Christophe;Tommy-Martin, Michel
    • Nuclear Engineering and Technology
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    • v.41 no.9
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    • pp.1171-1180
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    • 2009
  • The internal core baffle structure of a French Pressurized Water Reactor (PWR) consists of a collection of baffles and formers that are attached to the barrel. The connections are done thanks to a large number of bolts (about 1500). After inspection, some of the bolts have been found cracked. This has been attributed to the Irradiation Assisted Stress Corrosion Cracking (IASCC). The $Electricit\acute{e}$ De France (EDF) has set up a research program to gain better knowledge of the temperature distribution, which may affect the bolts and the whole structure. The temperature distribution in the structure was calculated thanks to the thermal code SYRTHES that used a finite element approach. The heat transfer between the by-pass flow inside the cavities of the core baffle and the structure was accounted for thanks to a strong thermal coupling between the thermal code SYRTHES and the CFD code named Code_Saturne. The results for the CP0 plant design show that both the high temperature and strong temperature gradients could potentially induce mechanical stresses. The CPY design, where each bolt is individually cooled, had led to a reduction of temperatures inside the structures. A new parallel version of SYRTHES, for calculations on very large meshes and based on MPI, has been developed. A demonstration test on the complete structure that has led to about 1.1 billion linear tetraedra has been calculated on 2048 processors of the EDF Blue Gene computer.

A SOFT-SENSING MODEL FOR FEEDWATER FLOW RATE USING FUZZY SUPPORT VECTOR REGRESSION

  • Na, Man-Gyun;Yang, Heon-Young;Lim, Dong-Hyuk
    • Nuclear Engineering and Technology
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    • v.40 no.1
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    • pp.69-76
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    • 2008
  • Most pressurized water reactors use Venturi flow meters to measure the feedwater flow rate. However, fouling phenomena, which allow corrosion products to accumulate and increase the differential pressure across the Venturi flow meter, can result in an overestimation of the flow rate. In this study, a soft-sensing model based on fuzzy support vector regression was developed to enable accurate on-line prediction of the feedwater flow rate. The available data was divided into two groups by fuzzy c means clustering in order to reduce the training time. The data for training the soft-sensing model was selected from each data group with the aid of a subtractive clustering scheme because informative data increases the learning effect. The proposed soft-sensing model was confirmed with the real plant data of Yonggwang Nuclear Power Plant Unit 3. The root mean square error and relative maximum error of the model were quite small. Hence, this model can be used to validate and monitor existing hardware feedwater flow meters.

Validation of the fuel rod performance analysis code FRIPAC

  • Deng, Yong-Jun;Wei, Jun;Wang, Yang;Zhang, Bin
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1596-1609
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    • 2019
  • The fuel rod performance has great importance for the safety and economy of an operating reactor. The fuel rod performance analysis code, which considers the thermal-mechanical response and irradiation effects of fuel rod, is usually developed in order to predict fuel rod performance accurately. The FRIPAC (${\underline{F}}uel$ ${\underline{R}}od$ ${\underline{I}}ntegral$ ${\underline{P}}erformance$ ${\underline{A}}nalysis$ ${\underline{C}}ode$) is such a fuel rod performance analysis code that has been developed recently by China Nuclear Power Technology Research Institute Co. Ltd. The code aims at the computational simulation of the Pressurized Water Reactor fuel rod behavior for both steady-state and power ramp condition. A brief overview of FRIPAC is presented including the computational framework and the main behavioral models. Validation of the code is also presented and it focuses on the fuel rod behavior including fuel center temperature, fission gas release, rod internal pressure/internal void volume, cladding outer diameter and cladding corrosion thickness. The validation is based on experimental data from several international projects. The validation results indicate that FRIPAC is an accurate and reliable fuel rod performance analysis code because of the satisfactory comparison results between the experimental measurements and the code predictions.

Phase formation and microstructural characteristics of ytterbium silicates coatings fabricated by plasma spraying with Ar/He gas compositions for environmental barrier coating applications (플라즈마용사로 증착된 환경차폐코팅 이터븀 실리케이트의 Ar/He 가스 조성에 따른 상형성 및 미세구조 특성)

  • Choi, Jae-Hyeong;Kim, Seongwon;Kim, Ji-Yoo;Moon, Hung Soo
    • Journal of Surface Science and Engineering
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    • v.55 no.6
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    • pp.376-382
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    • 2022
  • Yb2Si2O7 has a coefficient of thermal expansion similar to that of the base material of SiC and has excellent corrosion resistance in a high-temperature oxidizing atmosphere including water vapor, so it is being studied as one of the materials for environmental barrier coatings (EBCs). In this study, Yb2Si2O7 powder granule is deposited using atmospheric plasma spraying (APS) with different Ar/He ratios. Phase formation and microstructural characteristics are investigated with the coated specimens. In the coating layer, the crystallinity decreased, and the amorphous content increased from an increase in the ratio of Ar. In addition, the various types of particles involved by local volatilization of Si according to the Ar/He ratios were identified.

Dependence of Na+ leakage on intrinsic properties of cation exchange resin in simulated secondary environment for nuclear power plants

  • Hyun Kyoung Ahn;Chi Hyun An;Byung Gi Park;In Hyoung Rhee
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.640-647
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    • 2023
  • Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na+. This study was conducted to understand the Na+ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na+ was inappreciably escaped throughout the channel created in resin layer. Na+ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na+ capture and with increasing the fraction of ETAH-form resin. Na+ did not reach the breakthrough earlier than ETAH+ and NH4+ due to the increased selectivity of Na+ to the cation-exchange resin (H+ < ETAH+ < NH4+ ≪ Na+) at the feed composition. Na+ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na+ leakage from the condensate polishing plant (CPP) in NPPs.