• Title/Summary/Keyword: water corrosion

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A Study on the Methodology to Ensure Long-Term Durability of Low and Intermediate Level Radwaste Disposal Concrete Structure (${\cdot}$저준위 방사성폐기물 처분 콘크리트 구조물의 장기적 내구성 확보를 위한 방안 검토)

  • Kim Young-Ki;Lee Byung-Sik;Lee Yong-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.211-220
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    • 2005
  • The concrete structure is being considered for the main engineered barrier of low and intermediate level radwaste disposal facility. Concrete of low permeability can minimize infiltration of water and effectively prevent release of nuclide to ecosystem. But if concrete degrades, structural stability of disposal structure will decrease while permeability increase, resulting in increased possibility of nuclide release due to water infiltration. Therefore disposal concrete structure degradation shall be minimized to maintain capacity of nuclide isolation. The typical causes of concrete structure degradation are sulfide attack, reinforcement corrosion due to chloride attack, leaching of calcium hydroxide, alkali-aggregate reaction and repeated freezing-thawing. The common cause of these degradation processes is infiltration of water or adverse chemicals into concrete. Based on the study of these degradation characteristics and mechanisms of concrete structure, the methodology of design and service life evaluation of concrete structure as an engineered barrier are reviewed to ensure its long-term durability.

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Evaluation of Granite Melting Technique for Deep Borehole Sealing (심부시추공 밀봉을 위한 화강암 용융거동 평가)

  • Lee, Minsoo;Lee, Jongyoul;Ji, Sung-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.479-490
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    • 2018
  • The granite melting concept, which was suggested by Gibb's group for the closing of a deep borehole, was experimentally checked for KURT granite. The granite melting experiments were performed in two pressure conditions of atmospheric melting with certain inorganic additives and high pressure melting formed by water vaporization. The results of atmospheric tests showed that KURT granite started to melt at a lower temperature of $1,000^{\circ}C$ with NaOH addition and that needle shaped crystals were formed around partially melted crystals. In high pressure tests, vapor pressure was increased by adding water with maximum pressure of about 400 bars. KURT granite was partially melted at $1,000^{\circ}C$ when vapor pressure was low. However, it was not melted at vapor pressures higher than 200 bars. Therefore, it was determined that high pressure with a small amount of water vapor more effectively decreased the melting point of granite. Meanwhile, high temperature and high pressure vapor caused severe corrosion of the reactor wall.

CFD Analysis to Suppress Condensate Water Generated in Gas Sampling System of HANARO (하나로 기체시료채취계통에서 생성된 응축수 억제를 위한 CFD 해석)

  • Cho, SungHwan;Lee, JongHyeon;Kim, DaeYoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2_spc
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    • pp.327-336
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    • 2020
  • The high-flux advanced neutron application reactor (HANARO) is a research reactor with thermal power of 30 MW applied in various research and development using neutrons generated from uranium fission chain reaction. A degasifier tank is installed in the ancillary facility of HANARO. This facility generates gas pollutants produced owing to internal environmental factors. The degasifier tank is designed to maintain the gas contaminants below acceptable levels and is monitored using an analyzer in the gas sampling panel. If condensate water is generated and flows into the analyzer of the gas sampling panel, corrosion occurs inside the analyzer's measurement chamber, which causes failure. Condensate water is generated because of the temperature difference between the degasifier tank and analyzer when the gas flows into the analyzer. A heating system is installed between the degasifier tank and gas sampling panel to suppress condensate water generation and effectively remove the condensate water inside the system. In this study, we investigated the efficiency of the heating system. In addition, the variations in the pipe temperature and the amount of average condensate water were modeled using a wall condensation model based on the changes in the fluid inlet temperature, outside air temperature, and heating cable-setting temperature.

Developing a water discharge anchor & trap bolt to prevent basic salt from penetrating to harbor structures (해수 염기 침투방지를 위한 항만구조물 보수보강용 물배출 앵커 및 트랩볼트 개발에 관한 연구)

  • Ock, Jong-Ho;Moon, Sang-Deok;Lee, Hwa-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.535-541
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    • 2018
  • Most construction methods for the repair and reinforcement of old reinforced concrete harbor structures involve a process of applying a fiber complex or fiber complex panel just like wallpaper to the bottom of structures, such as slabs or beams. On the other hand, these techniques result in the sealing of repaired and reinforced portions of the structures by the fiber products, preventing moisture, such as rainwater entering the structures through the upper surfaces of the slabs or beams from being released, and causing the entire concrete covering of the structures to be peeled off in the long run. To prevent this, it is necessary to develop a technique to protect the basic salt from the sea water from penetrating into the structures while expelling the water absorbed in the structures swiftly. This study attempted to solve the problem by modifying the anchor bolts currently used to repair and reinforce the port structure. That is, by drilling holes into the body of anchor bolts and modifying the caps of the bolts to produce a structure that would let the water flow like a toilet trap, the moisture inside of the structure could be drained through the holes in the anchor bolts. The water discharge anchor bolts developed were tested and observed for 6 months; the water was discharged in 73% of the anchors (200 anchor installation, 145 anchors).

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

Studies on Preventive Methods Against Concrete Corrosion by Sea Water (ll) (조수에 의한 콘크리트 침식방지법에 관한 연구(ll))

  • 고재군
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.15 no.2
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    • pp.3018-3030
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    • 1973
  • This study was carried out to investigate the effects of various mix designs of concrete on the compressive strengths and corrosive rates when the concretes were immersed in sea water of the West Sea, as the part of study related to durated to durability of concrete by action of the sea water. Concrete mix designs used in this study were ordinary Concrete mix, Concrete mixes with different admixtures such as fly ash, pozzolith and vinsol resin, and pozzolan concrete mix. The concrete specimens were made and cured for 7 days and 28 days in the fresh water in accordance with the Korean Standard specification for concrete. Compressive strengths of the specimens were measured after immersing the specimens for one year in fresh water and sea water which were placed indoors. The sea water used in this test was taken from the Bay of Ahsan. Corrosive rate was also tested after immersing the specimens in the same sea water and placed indoors for one year. The results obtained from the tests are summarized as follows; 1. Compressive strength of an ordinary concrete was the lowest of the various mix desings of concrete immersed both in the fresh water and the sea water. Therefore, the uses of pozzolan cement, fly ash, pozoolith and vinsol resin in mix design of concrete had and effect on increasing compressive strength. 2. Pozzolan concrete was the most effective on compressive strength in the fresh water, but it had less effect than concrete with fly ash admixture immersed in the sea water. 3. The use of fly ash admixture in mix design of concrete showed higher strength as the immersing age is longer both in fresh water and sea water than the other concretes besides pozzolan concrete, but the concretewith fly ash admixture had lower strength than pozzolan concrete in the sea water. Therefore, concrete with fly ash admixture might be better than the pozzolan concrete as far as durability of concrete to sea water was concerned. 4. The use of pozzolith admixture in mix design of concrete had less compressive strength than the use of pozzolan cement for fly ash admixture both in fresh water and sea water. However, the concrete with pozzolith admixture was much stronger than one with vinsol resin admixture in fresh water, but somewhat stronger in the sea water. 5. Though the use of vinsol resin admixture was more effective than ordinary concrete on compressive strength both in fresh water and sea water, it was the least compressive strength among the other concretes. 6. Relation between compressive strengths and absorption rates of every kind of concrete besides concrete with fly ash admixture showed a linear regression line and the compressive strength is highee as the absorption rate is lower. Concrete with fly ash admixture had extremely high strength in comparison with corresponding adsorption rates of the other concretes. 7. Corrosive appearance on the surface of concretes was not occured significantly when exposed to the sea water for one year, However, the specimens of concretes besides ordinary concrete were a little heavier than those cured in fresh water for 28 days.

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An Experimental Study on Evaluation of Bond Strength of Arc Thermal Metal Spaying According to Treatment Method of Water Facilities Concrete Surface (수처리 시설물 콘크리트 표면처리 방법에 따른 금속용사 피막의 부착성능 평가에 관한 실험적 연구)

  • Park, Jin-Ho;Lee, Han-Seung;Shin, Jun-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.2
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    • pp.107-115
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    • 2016
  • In this study, the bond strength of metal spraying system by surface treatment of concrete (waterproof/corrosion method) in water treatment facilities was evaluated. The results showed that the system with Sa-P-R-(S) (sanding-perviousness surface hardener-surface roughness agent-metal spraying-sealing) led to the desirable performance. The bond strength, the coefficient of water permeability and air permeability were 3.7MPa, $0.68{\ast}10^{-8}cm/sec$, and $0.45{\ast}10^{-16}m^2$, respectively. In scanning electron microscope analysis, the microstructure of specimen coated with perviousness surface hardener was much denser than that without it. Therefore, the specimen coated with sanding-perviousness surface hardener-surface roughness agent-metal spraying-sealing had the best bond performance and was the most suitable system to concrete surface in water treatment facilities.

A Fundamental Study on the Effect to Build up a Vegetation Strip at Stream Confluence by Using Reed Mat (하천합류부에서 갈대매트를 이용한 하천식생대 조성에 대한 기초적 연구)

  • Chung, Kyung-Jin;Kim, Mi-Kyeong;An, Won-Yong
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.6 no.4
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    • pp.62-73
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    • 2003
  • The study was to apply a mat style reed planting method at confluence to improve plants growth conditions by relaxing disturbed topographical base due to water flow and was intended to review the effect to build up a vegetation strip by monitoring process after the construction. First off, We've attempted to construct reed mats on selected sites as confluences of Tan and Gaehwa stream and then examined and analyzed characteristics of soil and vegetation community. As the results of the examination, the soil texture was proven to be a mix of sand and loamy sand and be 6.3 ~ 7.0 soil pH. In addition, it contained 1.0 ~ 4.6% of organic matter, 0.04 ~ 0.22% of T-N and 27.8 ~ 41.2% of water content. For its vegetation structure, the Tan stream confluence was first actually a point bar without plants prior to the construction but 8 kinds of hygrophytes including Persicaria hydropiper and 9 kinds of terrestrial plants such as Potentilla supina, Artemisia annua, and Alopecurus aequalis var. amurensis. On the other hand, the Gaehwa stream confluence contained 6 kinds of hygrophytes such as Bidens frondosa and other 11 kinds of terrestrial plants prior to the construction while it produced 7 kinds of hygrophytes including Ranunculus ternatus as well as Phragmites australis and 9 kinds of terrestrial plants such as Potentilla supina after the construction. For the Phragmites australis, almost of them was weathered away in early days just after planting because of development period passed, but on May, six months later from planting, it was investigated that its length was approximated as 65 ~ 85cm with 75% coverage and that the number of it was 437 ~ 633/$m^2$. The study was shown that reed mats can improve environmental conditions of disturbed topographical base, enabling natural growth of various riparian vegetation including the introduced plant, reed. In the meantime, it was supposedly judged that to recover or build up a vegetarian strip, supplementary materials should be prepared to help produce and grow plants because it is not probable to expect river drift by water flow at confluence and that corrosion, burying or inundation owing to changes of water lever should be considered.

A Study on Characteristics of Durability for Plunger of High Speed and Ultra-High Pressure Reciprocating Pump Using High Velocity Oxygen Fuel Spraying (초고속 용사 적용 고속 초고압 왕복동 펌프 플런저의 내구성 특성에 관한 연구)

  • Bae, Myung-Whan;Park, Byoung-Ho;Jung, Hwa;Park, Hui-Seong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.5
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    • pp.20-28
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    • 2014
  • The high velocity oxygen fuel spraying (HVOF) is a kind of surface modification process technology to form the sprayed coating layer after spraying the powder to molten or semi-molten state by the ultra-high speed at the high-temperature heat source and conflicting with a substrate. It is desirable to melt completely the thermal spray powder in order to produce the coating layer with an optimal adhesion, however, because a semi-molten powder in a spray process has the low efficiency and become a factor that degrades the mechanical property by the inducement of pore-forming within the coating layer. To improve the wear resistance, corrosion resistance and heat resistance, in this study, the plungers of high-speed and ultra-high pressure reciprocating hydraulic pumps for oil and water used in ironwork are produced with $420J_2$ and the coating layers of plungers are formed by the powders of WC-Co-Cr and WC-Cr-Ni including the high hardness WC. The surface of these plungers is modified by the super-mirror face grinding machine using variable air pressure developed in this laboratory, and then the characteristics of cross-sectional microstructure, and surface roughness and hardness values between no operation and 100 days-operation are examined and made a comparison. The fine tops and bottoms on surface roughness curve of oil-hydraulic pump plunger sprayed by WC-Cr-Ni are molded more and higher than those of water-hydraulic pump sprayed by WC-Co-Cr because the plunger diameter of oil-hydraulic pump is 0.4 times smaller than that of water-hydraulic pump and the pressure of oil-hydraulic pump exerted on the plunger is operated with the 70 bars higher than that of water-hydraulic pump. As a result, it is found that the values of centerline average surface roughness and maximum height for oil-hydraulic pump plunger are bigger than those of water-hydraulic pump plunger.

Study on Influencing Factors of Adhesive Strength for Polymer Coating on Metal Adherend by Dolly Test (돌리테스트로 고분자 코팅층과 금속 피착재의 접착강도 측정시 영향인자에 대한 연구)

  • Baeg, Ju-Hwan;Park, Hyun;Lee, Sung In;Ha, Yungeun;Cho, Young-Rae
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.2
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    • pp.1-8
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    • 2019
  • The demand and importance of adhesives and paint coatings applied to solid surfaces such as metals, ceramics, and plastics are increasing. In this study, the influencing factors on the adhesive strength between the polymer coating and the metal adherend were investigated by Dolly test when the adhesive or the paint coating was applied on the metal adherend. Two-component epoxy adhesive was used as the adhesive, and EH2350, a two-component epoxy paint for anti-corrosion, was used as the paint. Especially, the effect of adherend metals(Al, Fe, STS, Cu, Zn), surface roughness and surface contamination(tap water, salt water) on adhesive strength was studied as influencing factors. The adhesive strength between adhesive and adherend was different when the type of metal adherend was different even when the same adhesive was used. It was found that spray water cleaning was necessary before the paint coating process on the surface of the oxide contaminated adherend with tap water or salt water. As a result of this study, it was confirmed that Dolly test can be widely used in the future to measure adhesive strength between paint coating and adherend.