• Title/Summary/Keyword: water corrosion

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The Influence of Nano Synthesized Polymer Paint on Durability of Concrete (나노합성 무기질 폴리머계 표면처리제가 콘크리트의 내구성에 미치는 영향)

  • Beak, Jong-Myeong;Park, Youg-Keol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.1
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    • pp.56-63
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    • 2016
  • This experiment was compared and analyzed between the original surface paint through chloride penetration, neutralization, freeze-thaw and chemical corrosion resistance measuring internal structure and volume of voids in order to evaluate the effect of increase in durability of the newly modeled nano synthesized polymer paint painted on concrete surface which results improvement on air permeability to increase the durability of concrete structures. The test result of measuring volume of void and inner structure, concrete, spreaded with nano synthesized polymer paint, showed decreasing trend of pore volume in the range of less than $0.1{\mu}m$ and more than $0.3{\mu}m$. Also, using an electron microscope inside showed tightness of hydration texture. Chloride penetration depth of concrete, painted with nano synthesized polymer paint, was decreased more than 92% compared to non-painted concrete and 70% with water-based epoxy painted concrete. Especially, chemical corrosion resistance test set with aqueous solution of 5% sulfuric acid, non-painted concrete and water-based epoxy painted concrete showed weight loss of 4% after dipping for 12 days. On the other hand, concrete painted with nano synthesized polymer paint showed 1.7% weight loss under the same condition. Also, it showed great result of appearance under the criteria of Tsivilis et al.

Crack Growth Analysis due to PWSCC in Dissimilar Metal Butt Weld for Reactor Piping Considering Hydrostatic and Normal Operating Conditions (수압시험 및 정상운전 하중을 고려한 원자로 배관 이종금속 맞대기 용접부 응력부식균열 성장 해석)

  • Lee, Hwee-Sueng;Huh, Nam-Su;Lee, Seung-Gun;Park, Heung-Bae;Lee, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.1
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    • pp.47-54
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    • 2013
  • This study investigates the crack growth behavior due to primary water stress corrosion cracking (PWSCC) in the dissimilar metal butt weld of a reactor piping using Alloy 82/182. First, detailed finite element stress analyses were performed to predict the stress distribution of the dissimilar metal butt weld in which the hydrostatic and the normal operating loads as well as the weld residual stresses were considered to evaluate the stress redistribution due to mechanical loadings. Based on the stress distributions along the wall thickness of the dissimilar metal butt weld, the crack growth behavior of the postulated axial and circumferential cracks were predicted, from which the crack growth diagram due to PWSCC was proposed. The present results can be applied to predict the crack growth rate in the dissimilar metal butt weld of reactor piping due to PWSCC.

Strength Characteristics of Improved Dredged Clay for Urgent Recovery of Ground Subsidence (함몰지반 긴급복구를 위한 개량준설점토의 강도 특성)

  • Oh, Sewook;Baek, Seungju;Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.5
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    • pp.31-38
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    • 2019
  • Recently, there has been an increasing number of ground subsidence (sink-hole) in the downtown areas, and in such a case, it is important to minimize accidents and passages through prompt recovery. With respect to the present recovery method for ground subsidence, the methods of applying the back filling after excavating the ground subsidence or using the grouting injected materials to restore the ground are mostly used, but there has been few studies on materials used for recovering the ground subsidence. Therefore, in order to clarify the characteristics of back filling materials used in the ground subsidence, this study uses the environment-friendly hardening agent to improve the dredged clay, and then, the mixture ratio of hardening agent and mixture ratio of decomposed granite soil is changed to cure for 3, 7, 14 and 28 days to analyze the intensity characteristics of the unconfined compression, and it was compared with the unconfined compression intensity for the previously used cement, a hardening agent. In order to evaluate the characteristics of intensity on the back filling materials, the C.B.R test was carried out, and for the review on whether the back filling materials influence on corrosion of water and sewer pipes and others, the soil non-resistance test was carried out. As a result of the test, for the case of the recovery work of the ground subsidence that requires urgency, it is considered as prudent if the hardening agents of 12% are integrated to cure for 3 days or longer, and for not having the influence on the corrosion of the gas tube or water pipes, it is proposed to mix for 30% or more of the decomposed granite soil. Door model test were conducted To confirm the bearing capacity characteristics of the solidified layer.

Evaluation of the Pull-out Resistance of the SMA Wire Connector (SMA 와이어를 이용한 연결재의 인발저항성능 평가)

  • Jung, Chi-Young;Woo, Tae-Ryeon;Lee, Jong-Han;Cheung, Jin-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.130-137
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    • 2019
  • Precast concrete (PC) structure is one of the type of the structures which is made in a facility prior to installing it to a construction field. The contact surfaces between two PC structures should be treated for obtaining enough binding force by inducing prestressing force. However, in the many cases, the contact surface causes the crack and leakage of water. These cracks and water leakage can cause the corrosion of the rebar, and the corrosion of the rebar can severely reduce the long-term durability. In this study, the SMA wire connector is suggested to solve the problem with the contact surfaces between two PC structures. The pull-out resistance of the suggested SMA wire connector is evaluated by conducting the tests to find the effect of the number of wires, shape of connector part, and shape memory effect. As a result of this study, the empirical formula is suggested to estimate the pull-out resistance related with the effects of the shape of the connector, shape memory effect, and the adhesive force. The validity between the estimated pull-out resistance and the measured value is confirmed.

A Study on Conservation and Desalination for Iron Weapons During the Korean War from DMZ (비무장지대 한국전쟁 전사자 유해발굴 수습 철제 총기류의 보존처리와 탈염처리 방법 고찰)

  • Jo, Ha Nui;Nam, Do Hyeon;Kim, Mi Hyun;Lee, Jae Sung
    • Journal of Conservation Science
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    • v.37 no.6
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    • pp.821-830
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    • 2021
  • The weapons excavated from the de-militarized zones (DMZ) of Korea are vulnerable to corrosion due to the immediate and drastic environmental change. Especially, the chloride ions (Cl-) in iron weapons cause active corrosion and require removal. In this study, conservation treatment and de-salination was performed for the discovered weapons from excavation sites of soldiers killed in action during the Korean War. Furthermore, an attempt was made to prepare the most stable plan for conservation treatment through the comparative study of soaking weapons in distilled water without chemicals and in a solution of sodium (SSC) at different temperatures. In the preliminarily experiments, the comparison of the eluted Cl- ions according to different conditions of de-salination showed that the highest number of ions were detected from the de-salination with SSC at a temperature of 100℃, and its duration was much smaller, i.e., 1~2 weeks. Accordingly, for the parts from the guns and rifles amongst other objects, a six-time de-salination was conducted in the SSC solution for 8 hours at 100℃ and subsequently, for 16 hours at room temperature during which the distilled water and SSC were exchanged every week. However, in the case of a loaded rifle, the de-salination was not conducted, considering the risk that the high temperature and pressure by impregnation in vacuum could cause an explosion

Characteristics of the Cyclic Hardening in Low Cycle Environmental Fatigue Test of CF8M Stainless Steel (CF8M 스테인리스 강 저주기 환경피로 실험의 주기적 변형률 경화 특성)

  • Jeong, Ill-Seok;Ha, Gak-Hyun;Kim, Tae-Ryong;Jeon, Hyun-Ik;Kim, Yeong-Sin
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.17-22
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    • 2007
  • Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor. The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside the small autoclave. So the magnet type LVDT's were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. FEM calculated the displacement and the strain of the gauge length from the data measured at the shoulders. Tensile test properties in elastic and plastic behavior of CF8M material were used in the FEM analysis. A series of low cycle fatigue tests simulating the cyclic strain hardening effect verified that the FEM calculation was well agreed with the simulated tests. The process and method developed in this study would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

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Removal of COD and T-N caused by ETA from Nuclear Power Plant Wastewater using 3D Packed Bed Bipolar Electrode System (3D 복극충진전기분해를 이용한 원전 ETA에 의해 유발된 폐수 내 COD 및 T-N 제거)

  • Kim, Han-Ki;Jeong, Joo-Young;Shin, Ja-Won;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.409-421
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    • 2012
  • Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

Characteristics of the Cyclic Hardening in Low Cycle Environmental Fatigue Test of CF8M Stainless Steel (CF8M 스테인리스 강 저주기 환경피로 실험의 주기적 변형률 경화 특성)

  • Jeong, Il-Seok;Ha, Gak-Hyun;Kim, Tae-Ryong;Jeon, Hyun-Ik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.2
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    • pp.177-185
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    • 2008
  • Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor (PWR). The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside a small autoclave. So the magnet type LVDT#s were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. Displacement of the fatigue specimen gauge length calculated by FEM (finite element method) used to modify the measured displacement and fatigue life at the shoulders. A series of low cycle fatigue life tests in air and PWR conditions simulating the cyclic strain hardening effect verified that the FEM modified fatigue life was well agreed with the simulating test results. The process and method developed in this study for the environmental fatigue test inside the small sized autoclave would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

Structural health monitoring of a newly built high-piled wharf in a harbor with fiber Bragg grating sensor technology: design and deployment

  • Liu, Hong-biao;Zhang, Qiang;Zhang, Bao-hua
    • Smart Structures and Systems
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    • v.20 no.2
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    • pp.163-173
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    • 2017
  • Structural health monitoring (SHM) of civil infrastructure using fiber Bragg grating sensor networks (FBGSNs) has received significant public attention in recent years. However, there is currently little research on the health-monitoring technology of high-piled wharfs in coastal ports using the fiber Bragg grating (FBG) sensor technique. The benefits of FBG sensors are their small size, light weight, lack of conductivity, resistance corrosion, multiplexing ability and immunity to electromagnetic interference. Based on the properties of high-piled wharfs in coastal ports and servicing seawater environment and the benefits of FBG sensors, the SHM system for a high-piled wharf in the Tianjin Port of China is devised and deployed partly using the FBG sensor technique. In addition, the health-monitoring parameters are proposed. The system can monitor the structural mechanical properties and durability, which provides a state-of-the-art mean to monitor the health conditions of the wharf and display the monitored data with the BIM technique. In total, 289 FBG stain sensors, 87 FBG temperature sensors, 20 FBG obliquity sensors, 16 FBG pressure sensors, 8 FBG acceleration sensors and 4 anode ladders are installed in the components of the back platform and front platform. After the installation of some components in the wharf construction site, the good signal that each sensor measures demonstrates the suitability of the sensor setup methods, and it is proper for the full-scale, continuous, autonomous SHM deployment for the high-piled wharf in the costal port. The South 27# Wharf SHM system constitutes the largest deployment of FBG sensors for wharf structures in costal ports to date. This deployment demonstrates the strong potential of FBGSNs to monitor the health of large-scale coastal wharf structures. This study can provide a reference to the long-term health-monitoring system deployment for high-piled wharf structures in coastal ports.

Study on the Electrode Characteristics for the Alkaline Water Electrolysis (알칼리 수전해용 전극에 관한 연구)

  • Choi, Ho-Sang;Yim, Doo-Soon;Rhyu, Cheol-Hwe;Kim, Jae-Chul;Hwang, Gab-Jin
    • Journal of Hydrogen and New Energy
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    • v.23 no.2
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    • pp.117-124
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    • 2012
  • Alkaline electrolysis needs the electrode having a low overvoltage and good corrosion resistance in alkaline solution such as KOH and NaOH, for the oxygen and hydrogen production. The commercial materials such as SUS(stainless steel)-316, Ni and NiFe were evaluated for the electrode in alkaline electrolysis. The test solution for the alkaline electrolysis used 1~9M NaOH and 1~9M KOH. The voltage increased with an increase of current density in each solution. As for the 15wt.% (about 5M) NaOH, the voltage of the tested electrode under the current density of 1.8A/$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: Ni${\fallingdotseq}$NiFe$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: NiFe${\fallingdotseq}$SUS-316. From the results, it was estimated that NiFe and Ni was suitable as the electrode for the alkaline water electrolysis using NaOH and KOH electrolyte.