• Title/Summary/Keyword: water corrosion

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An Experimental Study on the Fatigue Fracture Behavior of Ion-Nitrided SM45C (이온질화 처리한 SM45C의 피로파괴거동에 관한 실험적 연구)

  • Sang-Chul,Kim;Chang-Gi,Woo;Dong-Myeong,Kang
    • Bulletin of the Society of Naval Architects of Korea
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    • v.27 no.2
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    • pp.47-54
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    • 1990
  • In this study, the effects of gas ratio($N_2:H_2$) and treatment time on the fatigue fracture behavior, fatigue crack growth behavior and corrosion fatigue fracture behavior for the ion-nitrided SM45C steel were investigated. The results show that the fatigue limit and corrosion fatigue strength increased in porportion to $N_2$ gas and treatment time for all kinds of specimen, used in the experiment. Compare to the non-nitrided specimen, the fatigue limit and the corrosion fatigue strength increased about $24{\sim}29%$ at $10^7$ cycles in air and $32{\sim}48%$ at $10^6$ cycles in 3% NaCl aqueous solution, respectively. Similar results were derived with SM45C steel under Compression-Tension $24{\sim}29%$ at $10^6$ cycles in air and $32{\sim}48%$ either in 3% NaCl aqueous solution or in tap water, respectively. Ion-nitrided SM45C steel showed a slow fatigue crack growth rate at relatively low range of ${\Delta}K$ compared to the non-nitrided specimen. To the contrary, its rate increase at higher range of ${\Delta}K$.

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AN EXPERIMENTAL STUDY ON THE VASCULAR CHANGES OF RAT MOLAR PERIODONTAL LIGAMENT FOLLOWING ORTHODONTIC TOOTH MOVEMENT USING VASCULAR CORROSION CASTING METHOD (백서구치의 실험적 치아이동시 치근막 혈관변화에 관한 혈관주형법을 이용한 연구)

  • Lim, Yong-Kyu;Yang, Won-Sik
    • The korean journal of orthodontics
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    • v.24 no.1 s.44
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    • pp.37-62
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    • 1994
  • This study was undertaken to investigate the three dimensional vascular changes of periodontal ligament following orthodontic tooth movement. Experimental tooth movement was carried out in 96 Sprague-Dawley rats with the weight of 250g. They were divided into four experimental groups (each 24 rats). The left maxillary first molar was moved mesially with 25g force in group I, and with 75g force in group II. Each three animals were sacrificed after 1, 6, 12, 24 hours, and 3, 7, 14, 21 days. In group III, 25g mesial force was applied for 3 days, and in group IV, 75g mesial force was applied for 3 days. Then the appliances were removed, and each three animals were sacrificed after 1, 6, 12, 24 hours, and 3, 7, 14, 21 days from removal of appliance. The contralateral molars were used for control group. Casting media was injected via left ventricle and polymerized in warm water. After corrosion of surrounding soft tissue, three dimensional vascular changes were examined using scanning electron microscopy. The findings of this study were as follows: 1. Pressure side of group I and II showed degenerative vascular changes such as vascular compression, reduction of vasculature, leakage of casting media. But, regenerative changes were dominant after 7 days of tooth movement. Although the degenerative vascular changes were more severe in group II, which was exposed to heavy force, the timing of these changes was not different between two groups. 2. Periodontal vasculature was reestablished by the growth of new capillaries and their differentiation and union from the remaining periodontal vessels and vessels of alveolar bone marrow. Although vascular regeneration was more rapid in group I, which was exposed to light force, the vasculature was not fully normalized in both groups even after 21 days. 3. There was no remarkable changes in tension side of group I and II, but looping of capillary, new capillary growth, dilation of vessels, redirection of vessels in the direction of tensile force were occurred. 4. In pressure side of group III and IV, in which appliance was removed after 3 days of orthodontic force, bone resorption was continued even after removal of appliance. Regeneration of vasculature was initiated after 1-6 hours, and it was more rapid in group III than group IV. In both groups, the vasculature was not fully normalized even after 21 days. 5. After removal of appliance, tension side of group III and IV showed vascular compression and loss of vasculature.

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Effects of alloy elements on electrochemical characteristics improvement of stainless steel in sea water (해수환경하에서 스테인리스강의 전기화학적 특성 개선을 위한 합금원소의 영향)

  • Lee, Jung-Hyung;Choi, Yong-Won;Jang, Seok-Ki;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.890-899
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    • 2014
  • Austenitic stainless steel is widely used in various industries due to its excellent corrosion resistance. However, Cr carbides precipitation along the grain boundaries after heat treatment or welding may develop Cr depleted zone, which acts as a preferential site for intergranular corrosion attack. To resolve this, carbon stabilizing element such as Ti or Nb are added to suppress formation of Cr carbides. However, there are few reports on corrosion characteristics under seawater environment of the stabilized stainless steel. This study investigated the effects of alloying contents on the electrochemical characteristics in seawater of stainless steel containing stabilizing element(Ti and Nb). To achieve this, the changes on the microstructure due to alloying were observed with microscope, and the electrochemical characteristics were determined by measurement of natural potential and potentiodynamic polarization experiments. The microscopic observation revealed that all specimens had inclusions other than the austenite matrix phase due to the addition of alloying elements. Such inclusions are considered to have different electrochemical characteristics from those of the matrix, and thus a clear distinction was found according to the type of stabilizers and the contents. The results of this study suggest that it is important to consider the effects of alloying contents on the electrochemical characteristics in seawater with the addition of Ti or Nb into austenitic stainless steel.

Electrochemical Characteristics of Nanotubular Ti-25Nb-xZr Ternary Alloys for Dental Implant Materials

  • Byeon, In-Seop;Park, Seon-Young;Choe, Han-Cheol
    • Journal of Korean Dental Science
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    • v.10 no.1
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    • pp.10-21
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    • 2017
  • Purpose: The purpose of this study was to investigate the electrochemical characteristics of nanotubular Ti-25Nb-xZr ternary alloys for dental implant materials. Materials and Methods: Ti-25Nb-xZr alloys with different Zr contents (0, 3, 7, and 15 wt.%) were manufactured using commercially pure titanium (CP-Ti), niobium (Nb), and zirconium (Zr) (99.95 wt.% purity). The alloys were prepared by arc melting in argon (Ar) atmosphere. The Ti-25Nb-xZr alloys were homogenized in Ar atmosphere at $1,000^{\circ}C$ for 12 hours followed by quenching into ice water. The microstructure of the Ti-25Nb-xZr alloys was examined by a field emission scanning electron microscope. The phases in the alloys were identified by an X-ray diffractometer. The chemical composition of the nanotube-formed surfaces was determined by energy-dispersive X-ray spectroscopy. Self-organized $TiO_2$ was prepared by electrochemical oxidation of the samples in a $1.0M\;H_3PO_4+0.8wt.%$ NaF electrolyte. The anodization potential was 30 V and time was 1 hour by DC supplier. Surface wettability was evaluated for both the metallographically polished and nanotube-formed surfaces using a contact-angle goniometer. The corrosion properties of the specimens were investigated using a 0.9 wt.% aqueous solution of NaCl at $36^{\circ}C{\pm}5^{\circ}C$ using a potentiodynamic polarization test. Result: Needle-like structure of Ti-25Nb-xZr alloys was transform to equiaxed structure as Zr content increased. Nanotube formed on Ti-25Nb-xZr alloys show two sizes of nanotube structure. The diameters of the large tubes decreased and small tubes increased as Zr content increased. The lower contact angles for nanotube formed Ti-25NbxZr alloys surfaces showed compare to non-nanotube formed surface. The corrosion resistance of alloy increased as Zr content increased, and nanotube formed surface showed longer the passive regions compared to non-treatment surface. Conclusion: It is confirmed that corrosion resistance of alloy increased as Zr content increased, and nanotube formed surface has longer passive region compared to without treatment surface.

Grain Boundary Character Changes and IGA/PWSCC Behavior of Alloy 600 Material by Thermomechanical Treatment (가공열처리에 의한 Alloy 600 재료의 결정립계특성 변화와 입계부식 및 1차측 응력부식균열 거동)

  • Kim, J.;Han, J.H.;Lee, D.H.;Kim, Y.S.;Roh, H.S.;Kim, G.H.;Kim, J.S.
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.919-925
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    • 1999
  • Grain boundary characteristics and corrosion behavior of Alloy 600 material were investigated using the concept of grain boundary control by thermomechanical treatment(TMT). The grain boundary character distribution (GBCD) was analyzed by electron backscattered diffraction pattern. The effects of GBeD variation on intergranular at tack(JGA) and primary water stress corrosion cracking(PWSeC) were also evaluated. Changes in the fraction of coinci dence site lattice(CSL) boundaries in each cycle of TMT process were not distinguishable, but the total eSL boundary frequencies for TMT specimens increased about 10% compared with those of the commercial Alloy 600 material. It was found from IGA tests that the resistance to IGA was improved by TMT process. However, it was found from PWSCC test that repeating of TMT cycles resulted in the gradual decrease of the time to failure and the maximum load due to change in grain boundary characteristics, while the average crack propagation rate of primary crack increased mainly due to suppression of secondary crack propagation. It is considered that these corrosion characteristics in TMT specimens is attributed to 'fine tuning of grain boundary' mechanism.

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The Effect of Stress on SCC of Heat Exchanger Tube for LNG Vessel (LNG선박용 열교환기 세관의 SCC에 미치는 응력의 영향)

  • Jeong Hae Kyoo;Lim Uh Joh
    • Journal of the Korean Institute of Gas
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    • v.7 no.2 s.19
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    • pp.22-32
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    • 2003
  • Al-brass material is generally used at the state of plastic deformation, for example; bending, extension of bell mouth at shell and tube type heat exchanger. And SCC(stress corrosion cracking) of Al-brass material will be affected by residual stress as plastic deformation. SCC results from synergism between mechanical factor and corrosion environment. Mechanical factor is stress that directly relates with stress intensity factor at the crack tip. This paper was studied on the effect of stress on SCC of Al-brass tube under in $3.5\%$ NaCl. + $0.1\%\;NH_4OH$ solution by constant displacement tester. Increasing of acidified water flow into sea and speeds up corrosion rate of Al-brass which is used as a tube material of vessel heat exchanger by polluted coast seawater. The experimental results are as follow The latent time of SCC occurrence gets longer as the initial stress intensity factor($K_{Ii}$) gets lower The main crack was propagated as the initial stress intensity factor($K_{Ii}$) gets higher, and secondary cracks occurred by electro-chemical factor a(ter stage of released stress. Dezincification phase showed around the crack, and the range of dezincification gets wider as the initial stress intensity factor($K_{Ii}$) gets higher.

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FEA Simulations on Water Absorption in Various Pre-Cracked Concretes (유한요소해석에 기반한 콘크리트 균열 조건에 따른 수분흡수 현상 분석)

  • Kim, Kun-Soo;Park, Ki-Tae;Kim, Jaehwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.68-75
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    • 2021
  • This study performed simulating water absorption in various pre-cracked concretes. 2D-Finite Element Analysis (2D-FEA) model was developed based on experimental results on the amount of absorbed water in concrete with the exposure time. Results from the 2D-FEA showed that both crack width and crack depth strongly affect the amount of absorbed water in cracked concrete. In addition, water absorption rate is introduced and a predictive equation is suggested to estimate the rate in order to quantify the amount of absorbed water in cracked concrete. It was confirmed that water absorption in concrete having less than 150 mm crack depth was dominated as a main transport factor regardless of crack width. Therefore, considering that steel corrosion caused by chlorides dissolved in water mainly occurs in reinforced concrete structures, it is necessary that crack depth as well as crack width should be investigated in reinforced concrete structures at the time of field-inspection.

Current Status and Investigation of International Co-operative Research Program-PINC(Program for the Inspection of Nickel Alloy Components) (국제공동연구 PINC(Program for the Inspection of Nickel Alloy Components) 현황 및 고찰)

  • Kim, Kyung-Cho;Kang, Sung-Sik;Song, Kyung-Ho;Chung, Koo-Kap;Chung, Hae-Dong
    • Journal of the Korean Society for Nondestructive Testing
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    • v.29 no.2
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    • pp.153-161
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    • 2009
  • After several PWSCCs were found in Bugey(France), Ringhals(Sweden), Tihange(Belgium), Oconee, Arkansas, Crystal Fever, Davis-Basse, VC Summer(U.S.A.), Thuruga(Japan), USNRC and PNNL started the research on PWSCC, that is, PINC project. The aim of this project is to fabricate and obtain representative NDE mock-ups with flaws to simulate tight PWSCC cracks, to identify and quantitatively assess NDE methods for accurately detecting, sizing and characterizing tight cracks such as PWSCC, to document the range of locations and crack morphologies associated with PWSCC and observed responses and to incorporate findings from other ongoing PWSCC research programs, as appropriate. By participating in PINC project, Korean morphology technique about PWSCC and NDE technique have improved and become similar lever with other advanced country. Therefore, the evaluation technique of integrity for nickel alloy component has been improved by cooperation with university, research institute and industries.

Sensitivity Analysis of Finite Element Parameters for Estimating Residual Stress of J-Groove Weld in RPV CRDM Penetration Nozzle (원자로 CRDM 관통노즐 J-Groove 용접부 잔류응력 예측을 위한 유한요소 변수 민감도 해석)

  • Bae, Hong-Yeol;Kim, Ju-Hee;Kim, Yun-Jae;Oh, Chang-Young;Kim, Ji-Soo;Lee, Sung-Ho;Lee, Kyoung-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.10
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    • pp.1115-1130
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    • 2012
  • In nuclear power plants, the reactor pressure vessel (RPV) upper head control rod drive mechanism (CRDM) penetration nozzles are fabricated using J-groove weld geometry. Recently, the incidences of cracking in Alloy 600 CRDM nozzles and their associated welds have increased significantly. The cracking mechanism has been attributed to primary water stress corrosion cracking (PWSCC), and it has been shown to be driven by welding residual stresses and operational stresses in the weld region. The weld-induced residual stress is the main factor contributing to crack growth. Therefore, an exact estimation of the residual stress is important for ensuring reliable operation. This study presents the residual stress computation performed for an RPV CRDM penetration nozzle in Korea. Based on two and three dimensional finite element analyses, the effect of welding variables on the residual stress variation is estimated for sensitivity analysis.

An Experimental Study on Piping Feasibility of PE Compound Pipe for Fire Protection Service (PE 이종강관의 소방용 배관 적용성에 관한 실험적 연구)

  • Park, Jeong-Hwa;Oh, Cheon-Young;Kwark, Ji-Heon;Son, Bong-Sei
    • Fire Science and Engineering
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    • v.30 no.3
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    • pp.55-61
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    • 2016
  • In this study, to determine whether it is possible to apply Polyethylene (PE) compound pipe, which was developed to solve the problem caused by the corrosion of the fire protection piping currently in usein water based fire extinguishing systems, we performed an actual mockup fire test. Since no test standard was available related to the developed compound pipe, we compared and analyzed domestic and international technical materials and test standards and selected suitable fire test standards to evaluate the performance of the PE compound pipe. we applied two fire test standards to the PE compound pipe, viz. those for CPVC and metallic pipes, and conducted a total of 6 experiments to evaluate its performance. According to the results of the first and second fire tests based on the test standard for the CPVC pipe, neither the fitting nor the piping was damaged or deformed and no leakage was observed in the pressure test, which was performed for 5 minutes. For the fire test based on the metallic pipe test standard, a total of 4 experiments were conducted. The first two experiments were conducted to simulate the wet piping system. In the results of this fire test, neither leakage nor rupture was observed from the PE compound pipe and no damage was caused, such as the secession of the PE material. However, in the next two experiments, which simulated the dry system, the PE compound pipe suffered damage and rupture, including deformation before the fire fighting water was discharged. Therefore, we found that the piping performance of the PE compound pipe did not undergo any deterioration, including fusion, deformation, or damage, in the wet piping system simulated fire test.