• Title/Summary/Keyword: water corrosion

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Evaluation of dissolution characteristics of magnetite in an inorganic acidic solution for the PHWR system decontamination

  • Ayantika Banerjee ;Wangkyu Choi ;Byung-Seon Choi ;Sangyoon Park;Seon-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1892-1900
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    • 2023
  • A protective oxide layer forms on the material surfaces of a Nuclear Power Plant during operation due to high temperature. These oxides can host radionuclides, the activated corrosion products of fission products, resulting in decommissioning workers' exposure. These deposited oxides are iron oxides such as Fe3O4, Fe2O3 and mixed ferrites such as nickel ferrites, chromium ferrites, and cobalt ferrites. Developing a new chemical decontamination technology for domestic CANDU-type reactors is challenging due to variations in oxide compositions from different structural materials in a Pressurized Water Reactor (PWR) system. The Korea Atomic Energy Research Institute (KAERI) has already developed a chemical decontamination process for PWRs called 'HyBRID' (Hydrazine-Based Reductive metal Ion Decontamination) that does not use organic acids or organic chelating agents at all. As the first step to developing a new chemical decontamination technology for the Pressurized Heavy Water Reactor (PHWR) system, we investigated magnetite dissolution behaviors in various HyBRID inorganic acidic solutions to assess their applicability to the PHWR reactor system, which forms a thicker oxide film.

Development of Anti-Fouling Film Using Polyurea for Offshore Wind Turbine Substructure (폴리우레아를 활용한 해상풍력 지지구조물 안티파울링 필름 개발)

  • Jin Hyuk Son;Myung Bo Kang;Kyung Kuk Jung;Woo Beom Han
    • Journal of Wind Energy
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    • v.15 no.1
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    • pp.82-90
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    • 2024
  • Bio-fouling has positive aspects that are used as a fish resource, but there are also negative aspects such as corrosion of the surface of the support structure, aesthetics and work safety problems. A specimen was produced using a polyurea material with excellent anti-fouling and methodology, and contact angle, high water pressure, adhesion, and real sea area tests were performed. As a result of measuring the contact angle of the specimen with a 10 cm x 10 cm area of polyurea, There was found to be an average of 124.4 ° at nine points. No surface damage was found even above 5 Mpa when high water pressure was sprayed, and adhesive strength of 300LSE adhesives was confirmed between 22.84 and 23.04 Mpa with an adhesion test. During the 6-month real sea area test, it was confirmed that about 17.24 % of the polyurea film was less generated than the comparison group.

A Study on the Turbidity Estimation Model Using Data Mining Techniques in the Water Supply System (데이터마이닝 기법을 이용한 상수도 시스템 내의 탁도 예측모형 개발에 관한 연구)

  • Park, No-Suk;Kim, Soonho;Lee, Young Joo;Yoon, Sukmin
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.2
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    • pp.87-95
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    • 2016
  • Turbidity is a key indicator to the user that the 'Discolored Water' phenomenon known to be caused by corrosion of the pipeline in the water supply system. 'Discolored Water' is defined as a state with a turbidity of the degree to which the user visually be able to recognize water. Therefore, this study used data mining techniques in order to estimate turbidity changes in water supply system. Decision tree analysis was applied in data mining techniques to develop estimation models for turbidity changes in the water supply system. The pH and residual chlorine dataset was used as variables of the turbidity estimation model. As a result, the case of applying both variables(pH and residual chlorine) were shown more reasonable estimation results than models only using each variable. However, the estimation model developed in this study were shown to have underestimated predictions for the peak observed values. To overcome this disadvantage, a high-pass filter method was introduced as a pretreatment of estimation model. Modified model using high-pass filter method showed more exactly predictions for the peak observed values as well as improved prediction performance than the conventional model.

Development of CCPP(Calcium Carbonate Precipitation Potential) calculating program for corrosion control of drinking water distribution system (상수도관 부식방지를 위한 CCPP(Calcium Carbonate Precipitation Potential) 산정 프로그램 개발)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.170-175
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    • 2008
  • In this study, we developed the CCPP calculating program, which is a kind of index and can determine whether calcium carbonate would precipitate or not in pipe line of water distribution system. Through 9 complicated procedures, CCPP can be calculated. Assuming pH of equilibrium as a first trial, compare the right-hand-side result with left-hand-side result. If the percentage difference between the two results is less than a prescribed tolerance, the initial assumption for the assumed equilibrium pH is adequate. If the difference is too large, make a different assumption and repeat until a result within the prescribed tolerance is achieved. Plugging the intermediate results into the final equation, we could compute the CCPP. Using Fortran and Visual Basic languages, we developed the program. As a result of application of the program, the water quality of intaking water of Han River is highly corrosive by the index of CCPP.

Development of Relief Valves for the Domestic Gas-fired Hot Water Boilers (가정용 가스보일러 과압방지밸브의 개발 연구)

  • Kim Young Gyu;Kwon Jeong Rock;Kim Ji Yoon;Suh Joon Suk
    • Journal of the Korean Institute of Gas
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    • v.4 no.1 s.9
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    • pp.63-68
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    • 2000
  • We have developed a new relief valve which is a safety device for the domestic gas-fired hot water boilers. The relief valve has been designed to expand the inner diameter of the inlet, the outlet and the seat of the valve considering the relief capacity, and also to separate the spring from the room heating water. Therefore, we could minimize the adhesion and/or obstruction of the inlet and the corrosion phenomena of the spring which used to be the problem of the conventional relief valves. Test results of the developed relief valve showed that the performance of the opening pressure, reseating pressure, tightness, endurance were excellent, and the operating boiler with developed relief valve was evaluated as very good. The standardization and application of the relief valve can provide the advantage of component exchange and easy maintenance and repair.

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Ultrasonic characterization of exhumed cast iron water pipes

  • Groves, Paul;Cascante, Giovanni;Knight, Mark
    • Smart Structures and Systems
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    • v.7 no.4
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    • pp.241-262
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    • 2011
  • Cast iron pipe has been used as a water distribution technology in North America since the early nineteenth century. The first cast iron pipes were made of grey cast iron which was succeeded by ductile iron as a pipe material in the 1940s. These different iron alloys have significantly different microstructures which give rise to distinct mechanical properties. Insight into the non-destructive structural condition assessment of aging pipes can be advantageous in developing mitigation strategies for pipe failures. This paper examines the relationship between the small-strain and large-strain properties of exhumed cast iron water pipes. Nondestructive and destructive testing programs were performed on eight pipes varying in age from 40 to 130 years. The experimental program included microstructure evaluation and ultrasonic, tensile, and flexural testing. New applications of frequency domain analysis techniques including Fourier and wavelet transforms of ultrasonic pulse velocity measurements are presented. A low correlation between wave propagation and large-strain measurements was observed. However, the wave velocities were consistently different between ductile and grey cast iron pipes (14% to 18% difference); the ductile iron pipes showed the smaller variation in wave velocities. Thus, the variation of elastic properties for ductile iron was not enough to define a linear correlation because all the measurements were practically concentrated in single cluster of points. The cross-sectional areas of the specimens tested varied as a result of minor manufacturing defects and levels of corrosion. These variations affect the large strain testing results; but, surface defects have limited effect on wave velocities and may also contribute to the low correlations observed. Lamb waves are typically not considered in the evaluation of ultrasonic pulse velocity. However, Lamb waves were found to contribute significantly to the frequency content of the ultrasonic signals possibly resulting in the poor correlations observed. Therefore, correlations between wave velocities and large strain properties obtained using specimens manufactured in the laboratory must be used with caution in the condition assessment of aged water pipes especially for grey cast iron pipes.

A Study on Glass/Mo/ZnO/Glass Thin-film-heaters for Water Heating (수중 발열을 위한 Glass/Mo/ZnO/Glass 구조의 박막형 발열체 연구)

  • Kim, Jiwoo;Choi, Dooho
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.43-47
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    • 2022
  • In this study, we demonstrated an eco-friendly thin-metallic-film-based heater which can be operated in water. Based on the materials stability, Mo was selected as the heating element to secure long-term stability. Using a magnetron sputtering, 40 nm-thick Mo layers were deposited onto a glass substrate, followed by the deposition of 60-nm-thick ZnO layer to prevent oxidation during the heater fabrication process. Then, PVB (Polyvinyl Butyral) was applied on top of ZnO layer and an additional glass substrate was placed, which were heated at 150℃ for 2 hr. The PVB was cured with strong adhesion by the processing condition. We operated the Glass/Mo/ZnO/Glass heater in water, and it was shown that the water temperature reached 50℃ within 2 minutes, with a minimal resistance change of the heater. Finally, the heaters exhibit a semi-transparency, and this aesthetic advantage is expected to contribute to the added value of the heater.

A Review of SiCf/SiC Composite to Improve Accident-Tolerance of Light Water Nuclear Reactors (원자력 사고 안전성 향상을 위한 SiCf/SiC 복합소재 개발 동향)

  • Kim, Daejong;Lee, Jisu;Chun, Young Bum;Lee, Hyeon-Geun;Park, Ji Yeon;Kim, Weon-Ju
    • Composites Research
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    • v.35 no.3
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    • pp.161-174
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    • 2022
  • SiC fiber-reinforced SiC matrix composite is a promising accident-tolerant fuel cladding material to improve the safety of light water nuclear reactors. Compared to the current zirconium alloy fuel cladding as well as metallic accident-tolerant fuel cladding, SiC composite fuel cladding has exceptional accident-tolerance such as excellent structural integrity and extremely low corrosion rate during severe accident of light water nuclear reactors, which reduces reactor core temperature and delays core degradation processes. In this paper, we introduce the concept, technical issues, and properties of SiC composite accident-tolerant fuel cladding during operation and accident scenarios of light water nuclear reactors.

Optimised neural network prediction of interface bond strength for GFRP tendon reinforced cemented soil

  • Zhang, Genbao;Chen, Changfu;Zhang, Yuhao;Zhao, Hongchao;Wang, Yufei;Wang, Xiangyu
    • Geomechanics and Engineering
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    • v.28 no.6
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    • pp.599-611
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    • 2022
  • Tendon reinforced cemented soil is applied extensively in foundation stabilisation and improvement, especially in areas with soft clay. To solve the deterioration problem led by steel corrosion, the glass fiber-reinforced polymer (GFRP) tendon is introduced to substitute the traditional steel tendon. The interface bond strength between the cemented soil matrix and GFRP tendon demonstrates the outstanding mechanical property of this composite. However, the lack of research between the influence factors and bond strength hinders the application. To evaluate these factors, back propagation neural network (BPNN) is applied to predict the relationship between them and bond strength. Since adjusting BPNN parameters is time-consuming and laborious, the particle swarm optimisation (PSO) algorithm is proposed. This study evaluated the influence of water content, cement content, curing time, and slip distance on the bond performance of GFRP tendon-reinforced cemented soils (GTRCS). The results showed that the ultimate and residual bond strengths were both in positive proportion to cement content and negative to water content. The sample cured for 28 days with 30% water content and 50% cement content had the largest ultimate strength (3879.40 kPa). The PSO-BPNN model was tuned with 3 neurons in the input layer, 10 in the hidden layer, and 1 in the output layer. It showed outstanding performance on a large database comprising 405 testing results. Its higher correlation coefficient (0.908) and lower root-mean-square error (239.11 kPa) were obtained compared to multiple linear regression (MLR) and logistic regression (LR). In addition, a sensitivity analysis was applied to acquire the ranking of the input variables. The results illustrated that the cement content performed the strongest influence on bond strength, followed by the water content and slip displacement.

Characteristics of Structural Behavior and Safety Estimation of Water Supply GFRP Pipe (상수도용 유리섬유복합관의 구조적 거동특성 및 안전성 평가)

  • Lee, Bo-Be;Lee, Seung-Sik;Joo, Hyung-Jong;Yoon, Soon-Jng
    • Composites Research
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    • v.22 no.3
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    • pp.1-8
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    • 2009
  • In this paper, we present the results of experimental and analytical investigations on the structural behavior of GFRP pipes used in the water supply pipeline system. Cross-section of the pipe is consisted with two GFRP tubes and polymer mortar between the tubes. Due to the advantages such as light-weight, corrosion resistance, smooth surface, flexibility, etc., use of GFRP pipe in the water supply pipeline system is ever increasing trend. Therefore, more optimized structural design methodology should be developed. In the investigation, we conducted theoretical and analytical studies on the load versus radial deformation characteristics of GFRP pipes. In addition, ring stiffness test is also performed. Test results are compared with theoretical and analytical results and it was found that the results are agreed well within 5% of radial deformation. Finally, it was also found that the GFRP pipes used in the water supply pipeline system are strong enough to satisfy the industrial requirements.