• Nuclear Engineering and Technology
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• v.49 no.4
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• pp.744-751
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• 2017

The fatigue crack propagation behaviors of Z3CN20.09M duplex stainless steel (DSS) were investigated by studying oxide films of specimens tested in $290^{\circ}C$ water and air. The results indicate that a full oxide film that consisted of oxides and hydroxides was formed in $290^{\circ}C$ water. By contrast, only a half-baked oxide film consisting of oxides was formed in $290^{\circ}C$ air. Both environments are able to deteriorate the elastic modulus and hardness of the oxide films, especially the $290^{\circ}C$ water. The fatigue lives of the specimens tested in $290^{\circ}C$ air were about twice of those tested in $290^{\circ}C$ water at all strain amplitudes. Moreover, the crack propagation rates of the specimen tested in $290^{\circ}C$ water were confirmed to be faster than those tested in $290^{\circ}C$ air, which was thought to be due to the deteriorative strength of the oxide films induced by the mutual promotion of oxidation and crack propagation at the crack tip. It is noteworthy that the crack propagation can be postponed by the ferrite phase in the DSS, especially when the specimens were tested in $290^{\circ}C$ water.

• Journal of the Korea Concrete Institute
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• v.21 no.3
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• pp.245-253
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• 2009

The importance of chloride ions in the corrosion of steel in concrete has led to the concept for chloride threshold level (CTL). The CTL can be defined as the content of chlorides at the steel depth that is necessary to sustain local passive film breakdown and hence initiate the corrosion process. Despite the importance of the CTL, due to the uncertainty determining the actual limits in various environments for chloride-induced corrosion, conservative values such as 0.4% by weight of cement or 1.2 kg in 1 $m^3$ concrete have been used in predicting the corrosion-free service life of reinforced concrete structures. The paper studies the CTL for blended cement concrete by comparing the resistance of cementitious binder to the onset of chloride-induced corrosion of steel. Mortar specimens were cast with centrally located steel rebar of 10 mm in diameter using cementitious mortars with ordinary Portland cement (OPC) and mixed mortars replaced with 30% pulverized fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF), respectively, at 0.4 of a free W/B ratio. Chlorides were admixed in mixing water ranging 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder(Based on $C1^-$). Specimens were curd 28 days at the room temperature, wrapped in polyethylene film to avoid leaching out of chloride and hydroxyl ions. Then the corrosion rate was measured using the polarization resistance method and the order of CTL for binder was determined. Thus, CTL of OPC, 60%GGBS, 30%PFA and 10%SF were determined by 1.6%, 0.45%, 0.8% and 2.15%, respectively.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.6
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• pp.1351-1360
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• 1993

The fatigue behavior of GFRP composites is affected by environmental parameters. Therefore, we have to study on effect of sea water on fatigue behavior of GFRP composites as to maintain the safety and confidence in design of ocean structure of GFRP. In this paper, we investigated the fatigue properties of chopped strand glass mat/polyester composite in synthetic sea water. (pH 8.2) In case of the glass fiber (CSM type) reinforced polyester composite materials, the fatigue crack in the both dry and wet specimens tested in air or synthetic sea water occurred at the initial of cycle. Thereafter, it was divided with two regions that one decreased with the crack extension and the other increased with the crack extension. The transition point occurred during the crack propagation shifted to high ${\Delta}K$ value as load increase but its point is not changed regardless of immersion or test environment under a constant load. The synthetic sea water degrades the bond strength between fiber and matrix, thereby the tendency of rapid deceleration and acceleration of the crack growth was appeared.

• Journal of the Korean Geotechnical Society
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• v.36 no.8
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• pp.27-34
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• 2020

Strong alkaline waste water is generated in large quantities due to using Concrete, shotcrete and various compounds in tunnel construction sites. As the release of this alkaline waste water will contaminate the stream water, it has to be neutralized. Currently, this waste water is mainly neutralized by using sulfuric acid or hydrochloric acid, but the risks of corrosion and handling of facilities are inherent and the chemical control act requires strict management measures. Therefore, using CO₂ (carbon dioxide) as an alternative has been highlighted and various indoor experiment studies have been conducted to prove its potential. However, it is difficult to apply CO₂ to the site because it is still completely lacking in field application research and shows different characteristics from indoor experiments. In this study, the actual site applicability is verified through field testing.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.15 no.2
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• pp.71-79
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• 2003

The estimation functions were proposed for calculating diffusion coefficient, chloride binding, and evaporable water. The program estimating chloride ion penetration was developed on the basis of these functions and the effects of humidity, curing temperature, water-cement ratio, and $C_3$A on chloride penetration were analyzed. The relative humidity increases the depth of chloride ion penetration and the trend becomes greater with aging. On the contrary, the influence of curing temperature on chloride ion penetration decreases with aging. By the way, the rise of $C_3$A in cement increases total chloride concentration on the surface as the bound chloride concentration increases but it decreases total chloride concentration on the inner part as the diffusion velocity of free chloride decreases. The fall of water-cement ratio decreases the chloride penetration depth rapidly. Therefore, the reduction of water-cement ratio may be the most effective method for reducing of the steel corrosion by chloride penetration.

• Nuclear Engineering and Technology
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• v.50 no.3
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• pp.416-424
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• 2018

Microstructure of oxide formed on Zr-Nb-Sn tube sample was intensively examined by scanning transmission electron microscopy after exposure to simulated primary water chemistry conditions of various concentrations of Zn (0 or 30 ppb) and dissolved hydrogen ($H_2$) (30 or 50 cc/kg) for various durations without applying desirable heat flux. Microstructural analysis indicated that there was no noticeable change in the microstructure of the oxide corresponding to water chemistry changes within the test duration of 100 days (pretransition stage) and no significant difference in the overall thickness of the oxide layer. Equiaxed grains with nano-size pores along the grain boundaries and microcracks were dominant near the water/oxide interface, regardless of water chemistry conditions. As the metal/oxide interface was approached, the number of pores tended to decrease. However, there was no significant effect of $H_2$ concentration between 30 cc/kg and 50 cc/kg on the corrosion of the oxide after free immersion in water at $360^{\circ}C$. The adsorption of Zn on the cladding surface was observed by X-ray photoelectron spectroscopy and detected as ZnO on the outer oxide surface. From the perspective of $OH^-$ ion diffusion and porosity formation, the absence of noticeable effects was discussed further.

• Journal of the Korean Electrochemical Society
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• v.24 no.2
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• pp.13-27
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• 2021

Stainless steel, which includes Ni and Cr with Fe balance, is most often applied for a wide range of applications such as structure and equipment material. It is not only suitable for use in these applications due to its good corrosion resistance, but also can be applied to catalyst, supporting material, and current collector due to intrinsic properties of Ni and Fe contained in stainless steel. Therefore, in recent years, a lots of surface treatment methods have been studied to activate stainless steel, developing application of water splitting system. In this review paper, the research on the surface treatment technology of stainless steel for water splitting is summarized. It is expected to be able to propose the diverse surface treatment approaches of stainless steel for application to low-cost and highly efficient water splitting electrode.

• Composites Research
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• v.21 no.6
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• pp.1-7
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• 2008

The main objective of this study is to investigate the effect of salt water on the mechanical properties of a high modulus carbon-epoxy composite. Specimens were made of a carbon-epoxy composite UPN139B of SK Chemical and tested under inplane tension and shear after 0, 1, 3, 6, 9, and 12 months immersion in 3.5% salt water. Acceleration technique such as temperature elevation was not used. The tensile strengths and modulli in fiber and matrix direction did not show any remarkable degradation until 12 months immersion. In contrast to the tensile properties, shear strength and modulus started to gradually decrease up to about 10% of values of dry specimens after 12 months immersion. It was confirmed through the test that the material UPN139B can be an effective material for the shell structures in salt water to resist against the external pressure buckling because of the high fiber directional modulus and corrosion resistance.

• Land and Housing Review
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• v.13 no.1
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• pp.141-150
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• 2022

Responding to the increasing demand for research on seismic resistance of structures triggered by a large-scale earthquake in Korea, the Ministry of the Interior and Safety revised the typical application of the existing seismic design standards with the national seismic performance target enhanced. Therefore, in this paper, the dam body of the aged Test-Bed and the penstock with fluid were modeled by the three-dimensional finite element method by introducing several variables. The current seismic design standard law confirmed the safety of the dam structure and penstock against seismic waves. As a result of the 3D finite element analysis, the stress change due to the water impact of the penstock was minimal, and it was confirmed that the effect of the hydraulic pressure was more significant than the water impact in the earthquake situation. When the hydrostatic pressure is in the form of SPH, it was analyzed that the motion of the fluid and the location of stress caused by the earthquake can be effectively represented, and it will be easier to analyze the weak part. As a result of the analysis, which considers penstock's corrosion, the degree of stress dispersion gets smaller because the penstock is embedded in the body. The stress result is minimal, less than 1% of the yield stress of the steel. In addition, although there is a possibility of micro-tensile cracks occurring in the inlet of the dam, it has not been shown to have a significant effect on the stress increa.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.5
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• pp.133-142
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• 2008

This paper studies the early-aged chloride binding capacity of various blended concretes including OPC(ordinary Portland cement), PFA(pulversied fly ash), GGBFS(ground granulated blast furnace slag) and SF(silica fume) cement paste. Cement pastes with 0.4 of a free water/binder ratio were cast with chloride admixed in mixing water, which ranged from 0.1 to 3.0% by weight of cement and different replacement ratios for the PFA, GGBFS and SF were used. The content of chloride in each paste was measured using water extraction method after 7 days curing. It was found that the chloride binding capacity strongly depends on binder type, replacement ratio and total chloride content. An increase in total chloride results in a decrease in the chloride binding, because of the restriction of the binding capacity of cement matrix. For the pastes containing maximum level of PFA(30%) and GGBFS(60%) replacement in this study, the chloride binding capacity was lower than those of OPC paste, and an increase in SF resulted in decreased chloride binding, which are ascribed to a latent hydration of pozzolanic materials and a fall in the pH of the pore solution, respectively. The chloride binding capacity at 7 days shows that the order of the resistance to chloride-induced corrosion is 30%PFA > 10%SF > 60%GGBFS > OPC, when chlorides are internally intruded in concrete. In addition, it is found that the binding behaviour of all binders are well described by both the Langmuir and Freundlich isotherms.