• Title/Summary/Keyword: water absorption property

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Polarity Probing Two-Photon Fluorophores Based on [2.2]Paracyclophane

  • Woo, Han-Young;Korystov, Dmitry;Jin, Young-Eup;Suh, Hong-Suk
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2253-2260
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    • 2007
  • A series of tetra donor substituted [2.2]paracyclophane-based two-photon absorption (TPA) fluorophores were synthesized in neutral and cationic forms. The imaging activity of overall set of fluorophores was studied by the two-photon induced fluorescence (TPIF) method in a range of solvents. We also measured a clear progression toward a longer photoluminescence lifetime with increasing solvent polarity (intrinsic photoluminescence lifetime, τi: ~2 ns in toluene → 12-16 ns in water). The paracyclophane fluorophores with this unique property can be utilized as an optical polarity probe for the biomolecular substrates. The combined measurement of the two-photon fluorescence microscopy (TPM) cell image and TPIF lifetime can give us a better understanding of the biological processes and local environments in the cells.

Dyeing Properties of Polyester Ultrarmicrofiber (초극세 폴리에스테르 섬유의 염색성)

  • 정동석;김호정;이문철
    • Textile Coloration and Finishing
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    • v.11 no.3
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    • pp.1-8
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    • 1999
  • Polyester ultrarmcrofiber(UMF, fiber fineness : 0.05d) and the other three kinds of polyester fibers(0.52, 1.04 and 2.08d) were dyed with two disperse dyes, C.1. Disperse Red 60 and Blue 56. Dyeing rates and absorption isotherms of these dyes have been measured at 100, 115 and $130^\circ{C}$ in water system. The dye bath was maintained at pH 5.0 with acetic acid(0.1mo1/1) /sodium acetate(0.1mo1/1) buffers and a liquor ratio of 1000:1. The absorption isotherms from two disperse dyes are nearly linear up to the saturation values, which increase with the temperature of dyeing. Dye uptake decreased with the fiber fineness in lower temperature $100^\circ{C})$, whereas increased in higher temperature$(130^\circ{C})$. A comparatively greater quantity of dye is necessary to dye ultrarmcrofiber fabrics than conventional fabrics. Disperse Blue 56 having a good build-up property is agreed to Fothergill's equation, which is inversely varied with the fiber fineness by the quantity of dye necessary to obtain a given shade.

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Change of Mechanical Properties of Injection-Molded Glass-Fiber-Reinforced Plastic (GFRP) According to Temperature and Water Absorption for Vehicle Weight Reduction (차량 경량화를 위한 사출성형 유리섬유강화플라스틱의 온도 및 수분 흡수에 따른 기계적 물성 변화)

  • Chun, Doo-Man;Ahn, Sung-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.2
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    • pp.199-204
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    • 2013
  • Owing to the global energy crisis, studies have strongly focused on realizing energy savings through vehicle weight reduction using light metal alloys or polymer composites. Polymer composites afford many advantages including enabling the fabrication of complex shapes by injection molding, and glass and carbon fibers offer improved mechanical properties. However, the high temperature in an engine room and the high humidity during the rainy season can degrade the mechanical properties of the polymer. In this study, the mechanical properties of injection-molded glass-fiber-reinforced polymer were assessed at a temperature of $85^{\circ}C$ and the maximum moisture absorption conditions. The result showed a 23% reduction in the maximum tensile strength under high temperature, 30% reduction under maximum moisture absorption, and 70% reduction under both heat and moisture conditions. For material selection during the design process, the effects of high temperature and high humidity should be considered.

Moisturization and Transdermal Penetration Characteristics of PEGimpregnated Aloe vera Gel from DIS Processing (DIS에 의한 Polyethylene Glycol 함침 알로에 베라 겔의 보습 및 경피흡수 특성)

  • Kwon, Hye Mi;Hur, Won;Lee, Shin Young
    • KSBB Journal
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    • v.28 no.5
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    • pp.319-326
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    • 2013
  • This study was carried out to investigate the in vitro and in vivo moisturizing properties and percutaneous absorption of PEG-impregnated Aloe vera gel. The PEG-i-Aloe gel was obtained from dewatering and impregnation by soaking (DIS) of Aloe vera leaf slice. The moisturizing property of the obtained sample was evaluated by moisture determination using gravimetric method in desiccator under different RH% and by water sorption-desorption test on human skin. The transdermal penetration characteristics of PEG-i-Aloe gel was investigated by Franz diffusion cell in vitro transdermal absorption method. PEG-i-Aloe gel had high moisture retention ability and could significantly lead the enhancing skin hydration status as well as reducing the skin water loss due to the film formation as a skin barrier. The skin penetration rate of PEGi- Aloe gel at steady state was 9.76 ${\mu}g/(h{\cdot}cm^2)$ and the quantity of the transdermal absorption was 144 ${\mu}g/cm^2$ in 9 hr. The penetration mechanism was well fitted with Higuchi model ($R^2$ = 0.974-0.994). The results show that PEG-i-Aloe gel has the significant moisturizing effect and strong penetration of the animal skin. It could be used as the moisturizing additive in cosmetic skin products.

Comparison of Mechanical Properties on Helical/Hoop Hybrid Wound HNT Reinforced CFRP Pipe with Water Absorption Behavior (CFRP 파이프의 와인딩 적층 패턴 설계 및 HNT 나노입자 보강에 따른 수 환경에서의 기계적 물성 평가)

  • Choi, Ji-Su;Park, Soo-Jeong;Kim, Yun-Hae
    • Composites Research
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    • v.34 no.3
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    • pp.174-179
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    • 2021
  • Currently, fluid transfer steel pipes take a lot of time and expense to maintain all facilities due to new construction and painting or corrosion and aging. Therefore, this study was conducted for designing a CFRP pipe structure with high corrosion resistance and chemical resistance as a substitute for steel pipes. The helical/hoop pattern was cross-laminated to improve durability, and HNT was added to suppress the moisture absorption phenomenon of the epoxy. The HNT/CFRP pipe was manufactured by a filament winding process, and performed a mechanical property test, and a moisture absorption test in distilled water at 70℃. As a result, the highest bending strength was obtained when the hoop pattern was laminated with a thickness equivalent to 0.6% of the pipe. The 0.5 wt% HNT specimen had the highest moisture absorption resistance. Also, the delamination phenomenon at the interlayer interface was delayed, resulting in the lowest strength reduction rate.

Effects of Relative Humidity and Fiber Properties on the Moisture Permeability of Multilayer Fabric Systems (환경 및 섬유 특성이 멀티레이어 직물시스템의 투습성에 미치는 영향)

  • Suhyun Lee;Sohyun Park
    • Fashion & Textile Research Journal
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    • v.25 no.1
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    • pp.119-126
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    • 2023
  • This study aimed to determine the effects of relative humidity and fiber properties on the moisture permeability of multilayer systems by measuring water vapor transmission in the overlapping condition of various fabrics. The results confirmed that the property of the fabric in contact with the humid environment affects the moisture permeability. If the layer facing the humid environment is hydrophobic and the layer facing the dry environment is superhydrophobic, water vapor transmission increases by up to 17.8% compared to the opposite conditions. Comparing the correction values of the water vapor transmission reflecting the thickness of the specimen under the multilayer condition showed that permeability was higher when the hydrophilic or hydrophobic layer was facing the humid environment. The opposite was true from the "push-pull" effect of absorption mechanism. In the case of moisture permeability, the more hydrophilic the surface facing the humid environment, the more permeable that water vapor diffuses and passes through. It was concluded that the "pull-push" effect, in which water vapor diffuses widely through the hydrophilic facing a humid environment and then passes through the hydrophobic layer, contributes to the improvement of permeability. Permeability differed according to the multilayer overlapping condition. When the relative humidity was high, the "pull-push" effect was insignificant. This is caused by water droplets absorption after the partial migration of water due to condensation. These results suggest that the overlapping conditions and properties of fabrics should vary depending on heavy sweating or not.

Development of Perfluoroalkyl Derivative for $Cr^{3+}$ Adsorbent Promotion Process (3가 크롬 흡착 증진용 과불소 알킬유도체 제조 및 적용공정 개발)

  • Shin, Jong-Sub;Kum, Chang-Hun;Yun, Jong-Kuk;Park, Il-Kyu
    • Clean Technology
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    • v.14 no.3
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    • pp.193-203
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    • 2008
  • A surfactant is used to assist the effect of cleaning, dispersibility and adhesion during leather manufacturing process. Existing surfactant for that process includes many hydrophilic groups that may cause problem such as stain, bad water resistance and poor durability, etc. It is potential problem to make high-performance property for future leather market. In this study, we have synthesized the fluorinated surfactant of which property decreases surface tension, increases dispersion, cleaning effect and the better chrome absorption by the high bond energy of C-F to complement weakness that the present alkyl derivative surfactants have. Using fluorinated surfactant, we can confirm that dispersion is increased, chrome absorption ratio is augmented with high osmosis and coherence, chrome content in the tanning waste water is reduced, BOD and COD contents are diminished and physical characteristics are improved.

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Solvothermal Synthesis and Photocatalytic Property of SnNb2O6

  • Seo, Se-Won;Lee, Chan-U;Seong, Won-Mo;Heo, Se-Yun;Kim, Sang-Hyeon;Lee, Myeong-Hwan;Hong, Guk-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.441-442
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    • 2012
  • SnNb2O6 nanoplates were prepared by a solvothermal synthesis with water and ethanol mixed solvent. For improvement of their properties, as-prepared SnNb2O6 nanoplates also were calcined. The prepared powder was characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), Transmission electron microscope (TEM), UV-vis spectroscopy, Raman spectrometer, Brunauer-Emmett-Teller (BET). The calcined nanoplates have a smaller surface area than the as-prepared nanoplates have. Nevertheless, in the case of the optical absorption properties, the calcined nanoplates could absorb more photon energy, due to their smaller band gaps. The Raman analysis revealed that the Nb-O bond length in the calcined nanoplates was longer than that in the as-prepared nanoplate. The higher optical absorption capability of the calcined nanoplates was attributed to the local structure variation within them. Furthermore the high crystallinity of the calcined nanoplates is effective in improving the generation of charge carriers. So, It was found that the calcined nanoplates exhibited superior photocatalytic activity for the evolution of H2 from an aqueous methanol solution than the as-prepared nanoplates under UV and visible irradiation. Therefore, the enhanced photocatalytic activity of the calcined nanoplate powder for H2 evolution was mainly attributed to its high crystallinity and improved optical absorption property resulting from the variation of the crystal structure.

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Analysis on optical property in the South Sea of Korea by using Satellite Image : Study of Case on red tide occurrence in August 2013 (위성영상을 활용한 한국 남해의 광학적 특성 연구 : 2013년 8월 발생한 적조 사례를 중심으로)

  • Bak, Su-Ho;Yoon, Hong-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.11 no.7
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    • pp.723-728
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    • 2016
  • This study is analyzed the optical property of red tide pixel by using Landsat-7 ETM+, Landsat-8 OLI and COMS/GOCI image. In order to sample red tide pixel, Landsat-7, 8 true color image were used and obtained coordinate of red tide pixel in the true color image. Normalized water leaving radiance(nLw) and absorption coefficient were obtained from GOCI image in the same coordinate of the true color image. When red tide was not occurred the main absorption range was 412nm and 660nm but when red tide occurred it was 660nm and absorption coefficient in 412nm are drastically reduced. It made no difference of nLw spectrum between red tide pixel and non red tide pixel in nLw, but the absolute value of nLw was low than non red tide pixel, especially 660nm and 680nm wavelength sharply decrease.

Effects of Extrusion Conditions on Pasting Properties of Potato

  • Cha, Jae-Yoon;Ng, Perry K.W.;Shin, Han-Seung;Cash, Jerry
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.783-788
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    • 2007
  • An advantage to the extrusion of raw potatoes is a reduction in the energy input required to process potato products; however, the effects of extrusion on the properties of raw potato have not been studied. The purposes of this study were to develop a workable extrusion process for raw potato and to study the effects of extrusion conditions on the pasting properties of extruded potato products. The peak viscosity, final viscosity, pasting temperature, water solubility index, and water absorption index of pressed and pressed-dried potato extrudates decreased as die exit temperature increased, whereas they did not change as screw speed increased. The peak viscosity, final viscosity, and water solubility of steam-cooked potato products decreased with extrusion processing; however, they did not change with increasing die exit temperature and screw speed. Potato products with different degrees of depolymerization of extruded potato starch, depending on die exit temperature, were produced from raw potatoes.