• Title/Summary/Keyword: water absorption property

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Analysis of biomarkers with tunable infrared gas sensors (가변 파장형 적외선 가스 센서에 의한 생체표지자 분석)

  • Yi, Seung Hwan
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.314-319
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    • 2021
  • In this study, biomarkers were analyzed and segmented using tunable infrared gas sensors after performing the principal component analysis. The free spectral range of the device under test (DUT) was around 30 nm and DUT-5580 yielded the highest output voltage property among the others. The biomarkers (isoprophyl alcohol, ethanol, methanol, and acetone solutions) were sequentially mixed with deionized water and their mists were carried into the gas chamber using high-purity nitrogen gas. A total of 17 different mixed gases were tested with three tunable infrared gas sensors, namely DUT-3144, DUT-5580, and DUT-8010. DUT-8010 resolved the infrared absorption spectra of whole mixed gases. Based on the principal component analysis with each DUT and their combinations, each mixed gas and the trends in increasing gas concentration could be well analyzed when the contributions of the eigenvalues of the first and second were higher than 70% and 10%, respectively, and their sum was greater than 90%.

Synthesis and characterization of polyimides for FPC applications

  • Yeon, J.H.;Bae, Y.U.;Yoon, T.H.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.227-227
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    • 2006
  • It was attempted to synthesize polyimides from PPMDA and 3FPPMDA with mDAPPO/pPDA in order to afford CTE of 17ppm and adhesion property of 80g/mm, besides high Tg (>$300^{\circ}C$), good thermal stability (>$500^{\circ}C$), low water absorption and good solubility. The polyimides were prepared via a conventional two-step process; preparation of poly(amic-acid), followed by solution imidization by refluxing in NMP with o-DCB and the molar ratio of mDAPPO/pPDA was varied. The polyimides were characterized by FT-IR, NMR, DSC and TGA. In addition, intrinsic viscosity, solubility and coefficient of thermal expansion (CTE) were also measured.

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Electrochemical treatment of wastewater using boron doped diamond electrode by metal inter layer

  • KIM, Seohan;YOU, Miyoung;SONG, Pungkeun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.251-251
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    • 2016
  • For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. Wastewaters are consisting of complex mixture of different inorganic and organic compounds and some of them can be toxic, hazardous and hard to degrade. These effluents are mainly treated by conventional technologies such are aerobic and anaerobic treatment and chemical coagulation. But, these processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that could be show higher purification results. Among them, boron doped diamond (BDD) attract attention as electrochemical electrode due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD on Nb, Ta, W and Si substrates, but, their application in effluents treatment is not suitable due to high cost of metal and low conductivity of Si. To solve these problems, Ti has been candidate as substrate in consideration of cost and property. But there are adhesion issues that must be overcome to apply Ti as BDD substrate. Al, Cu, Ti and Nb thin films were deposited on Ti substrate to improve adhesion between substrate and BDD thin film. In this paper, BDD films were deposited by hot filament chemical vapor deposition (HF-CVD) method. Prior to deposition, cleaning processes were conducted in acetone, ethanol, and isopropyl alcohol (IPA) using sonification machine for 7 min, respectively. And metal layer with the thickness of 200 nm were deposited by DC magnetron sputtering (DCMS). To analyze microstructure X-ray diffraction (XRD, Bruker gads) and field emission scanning electron microscopy (FE-SEM, Hitachi) were used. It is confirmed that metal layer was effective to adhesion property and improved electrode property. Electrochemical measurements were carried out in a three electrode electrochemical cell containing a 0.5 % H2SO4 in deionized water. As a result, it is confirmed that metal inter layer heavily effect on BDD property by improving adhesion property due to suppressing formation of titanium carbide.

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Effects of Moisture and Barrel Temperature of Extrusion Process on Physicochemical and Functional Properties of Specialty Rice Cultivars

  • Choi, In-Duck;Song, Jin;Lee, Choon-Ki;Kim, Kee-Jong;Suh, Sea-Jung;Son, Jong-Rok;Ryu, Gi-Hyung;Kim, Jae-Hyun
    • Food Science and Biotechnology
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    • v.17 no.2
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    • pp.319-323
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    • 2008
  • Mutant rice cv. Goami2 (G2) and Baegjinjoo (BJJ) derived from a high-quality japonica rice cv. Ilpumbyeo (IP) were extruded under different feed moisture (20 and 30%) and barrel temperature (90, 110, and $130^{\circ}C$). Increasing feed moisture at fixed barrel temperature increased extrudate density (ED) in IP and BJJ. Whereas, G2 showed a varied ED depending on extrusion conditions; increasing barrel temperature decreased the ED of G2 extrudate with low feed moisture, but increased with high moisture. Results indicated a positive barrcl temperature effect on volume expansion in IP and G2, but a negative effect on 811, probably due to shrinkage of expanded products containing low-amylose contents. A significant increase of water absorption was found in G2 and BJJ extruded flour, while an increase of water solubility in those from IP. Non-digestible carbohydrates measured by total dietary fiber (TDF) indicated that extrusion increased slightly TDF in IP and BJJ extrudates, but decreased in G2 products, which might be variety-dependent.

Synthesis of Core@shell Structured CuFeS2@TiO2 Magnetic Nanomaterial and Its Application for Hydrogen Production by Methanol Aqueous Solution Photosplitting

  • Kang, Sora;Kwak, Byeong Sub;Park, Minkyu;Jeong, Kyung Mi;Park, Sun-Min;Kang, Misook
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2813-2817
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    • 2014
  • A new magnetic semiconductor material was synthesized to enable separation after a liquid-type photocatalysis process. Core@shell-structured $CuFeS_2@TiO_2$ magnetic nanoparticles were prepared by a combination of solvothermal and wet-impregnation methods for photocatalysis applications. The materials obtained were characterized using X-ray diffraction, transmission electron microscopy, ultraviolet-visible, photoluminescence spectroscopy, Brunauer-Emmett-Teller surface area measurements, and cyclic voltammetry. This study confirmed that the light absorption of $CuFeS_2$ was shifted significantly to the visible wavelength compared to pure $TiO_2$. Moreover, the resulting hydrogen production from the photo-splitting methanol/water solution after 10 hours was more than 4 times on the core@shell structured $CuFeS_2@TiO_2$ nanocatalyst than on either pure $TiO_2$ or $CuFeS_2$.

Mechanical Characteristics for Pulp Molds Made of ONP and OCC with Different Mixing Ratio (고지배합비율에 따른 펄프몰드 물성 변화 연구)

  • Park, In-Sik;Kim, Jae-Nung;Kim, Dae-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2007.04a
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    • pp.285-297
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    • 2007
  • As the demands of environment protection increase, the pulp mold container is developed to substitute for the plastic cushion materials like EPS(expanded poly styrene). The water-absorbing ratio, tensile strength and compressive strength of pulp mold are important factors to evaluate its shock absorbing characteristics. The study was performed to investigate the effects of the mechanical property changes on the various conditions of temperature and relative humidity for pulp mold containers made of mixed materials on ONP(old newspaper) and OCC(old corrugated container). This study also is evaluated the optimized mixing ratio of materials for making pulp mold by analyzing the changes of physical properties according to a various procured temperature and relative humidity conditions. The results show that the water absorption ratio of sample increased significantly, and tensile strength decreased $20{\sim}30%$, compressive strength decreased $10{\sim}20%$ by increasing relative humidity condition. And the results show that the ONP 50% and OCC 50% was optimized mixing ratio according to the samples.

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Varietal Variations in Physicochemical Characteristics and Amylopectin Structure of Grain in Glutinous Rice

  • Choi, Hae-Chune;Hong, Ha-Cheol;Kim, Yeon-Gyu;Nahm, Baek-Hie
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.3
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    • pp.207-213
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    • 1999
  • Thirty-eight glutinous rice varieties were classified into nine groups on the scatter diagram by the upper two principal components (56% contribution to the total information) based on eleven physicochemical characteristics including the viscograms and physical properties of cooked rice. The first principal component was the factor mainly associated with the viscogram characteristics of rice flour emulsion and the second was the factor chiefly related to the physical properties of cooked rice and water absorbability of rice grain. Indica glutinous rices were clearly distinguished from japonica ones by the first principal component score. Javanica glutinous rices were widely distributed on the intermediate zone between indica and japonica or on several japonica rice groups. Significant positive or negative correlations were found among water absorption rates of rice grain, physical properties of cooked rice, and viscogram characteristics of rice flour. Especially in japonica glutinous rices, the breakdown and setback viscosities of rice flour were closely associated with the alkali digestion value of milled rice and the stickiness of cooked rice. The frequency ratio of short glucose chains (A-chain) to intermediate glucose chains (B-chain), the ratio of B- chains to long glucose chains (C-chain) and the relative frequency of A- or B-chain fractions representing the amylopection structure of rice starch was closely associated with the breakdown and setback viscosities of rice flour.

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Synthesis and Characterization of Organophilic Montmorillonites Modified with Various Alkyl Substituents (다양한 구조의 알킬기를 함유한 친유성 몬모릴로나이트의 제조 및 특성 연구)

  • 심종천;김용운;원종찬;최길영;이미혜
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.129-134
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    • 2003
  • It has been known that the intercalation of long alkyl chains in montmorillonites (MMT) increased the hydrophobicity as well as gallery spacing of UT, which has influenced on the exfoliation behavior of various polymers. A series of organophilic MMTs were synthesized from the water/isopropyl alcohol solution of MMT with ammonium salts of various alkyl amines. The properties of obtained MMTs such as thermal decomposition temperature, gallery spacing as well as hydrophobic property were investigated. The X-ray diffraction experiments on organophilic montmorillonite demonstrated that the increase of length of alkyl substituent resulted in increase in the spacing between silicate layers, which was ranged from 13.1 to 29.4 $\AA$. On the other hand, introduction of (di-, tri-) alkyl substituents in ammonium salts decreased water absorption of organophiplic montmorillonite to 2.7%.

Quality Characteristics of Bread Dough added with Immature Chalssalbori Flour (미성숙 찰쌀보리가루를 첨가한 식빵반죽의 품질특성)

  • Kim, Ye-Seul;Park, Ju Yeon;Lee, Jeung Hee
    • Korean journal of food and cookery science
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    • v.30 no.4
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    • pp.385-393
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    • 2014
  • This study investigated both the chemical and antioxidative characteristics of wheat flour added with 10, 20 and 30% immature chalssalbori flour; further, the quality characteristics of bread dough during yeast fermentation were assessed. As the addition rate of chalssalbori flour into wheat flour increased, the DPPH radical scavenging capacity, water absorption index, water solubility index and viscosity were all increased. Moreover, the bread dough with an increased addition rate of chalssalbori flour demonstrated an increased pH, reduced fermentative expansion power and a darker yellowish color. The bread dough added with chalssalbori flour after mixing showed higher hardness, gumminess and adhesiveness, but lower cohesiveness and springiness compared to the control; however, these texture characteristics were changed during fermentation. In the present study, the mixed flour with 10% immature chalssalbori flour conveyed similar pasting characteristics to those of wheat flour; moreover, its bread dough showed higher springiness and fermentative expansion power. Furthermore, a delay effect of starch retrogradation can be expected compared to the control.

Chemical and Physical Characteristics of Expanded Rice Husk Medium on Growth of Rice Seedling

  • Ko Jonghan;Ham Jin Kwan;Kim Yong Bok;Kim Kyung Hee;Lee Byun Woo;Lee Youn Su
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.2
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    • pp.120-124
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    • 2005
  • Expanded rice husk (ERR) is different from commercial rice seedling media in chemical and physical properties such as pH, permeability, and water content. This study was conducted to test a possibility of improving rice seedling growth by improving the texture of ERR as a rice seedling medium. The seedling media used were a commercial seedling medium (CSM), rice husk, and ERR 1, 2, 3, and 4 with different expansion degrees. The pH of the ERHs ranged from 6.3 to 6.8. As the expansion rate increased, ERR particle sizes decreased, and water permeability and absorption rates improved. No significant differences in shoot dry weight and rate of maturity were found among the seedlings cultivated in the different ERH media. However, the mat formation of seedling roots became loose as the expansion rates were decreased. Further studies are necessary to determine the cause of poor root growth in ERH media.