• Title/Summary/Keyword: water absorption property

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Synthesis of Bismuth Vanadate as Visible-light Photocatalyst by Precipitation Reaction (침전 반응에 의한 가시광 광촉매 Bismuth Vanadate 합성)

  • Kim, Sang-Mun;Lee, Jae-Yong;Mun, Choo-Yeun;Lee, Hean-Soo
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.630-635
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    • 2011
  • Bismuth vanadate($BiVO_4$) with monoclinic phase as photocatalyst under visible light is synthesized by precipitation reaction in hot water. Properties such as crystal phase, particle morphology and visual light absorbance as well as the effects of thermal treatment for $BiVO_4$ powders are investigated. $BiVO_4$ powders with both single monoclinic phase and 0.2 ${\mu}m$ in particle size are synthesized when precipitate is stirred in water for 5 h at 95$^{\circ}C$. Well-developed monoclinic phase and light absorption property under 535 nm are observed as a result of thermal treatment for 1 h at 300$^{\circ}C$ after precipitation reaction in water for 5 h at 95$^{\circ}C$. Degradation of monoclinic crystal is found in firing above 350$^{\circ}C$, and particle growth is occurred in firing above 550$^{\circ}C$.

Rapid Fabrication of Micro-nano Structured Thin Film for Water Droplet Separation using 355nm UV Laser Ablation (355 nm UV 레이저 어블레이션을 이용한 마이크로-나노 구조의 액적 분리용 박막 필터 쾌속 제작)

  • Shin, Bo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.29 no.7
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    • pp.799-804
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    • 2012
  • Recently micro-nano structures has widely been reported to improve the performance of waterproof, heat isolation, sound and light absorption in various fields of electric devices such as mobiles, battery, display and solar panels. A lot of micro-sized holes on the surface of thin film provide excellent sound, or heat, or light transmission efficiency more than solid film and simultaneously nano-sized protrusions around micro hole increase the hydrophobicity of the surface of thin film because of lotus leaf effects as generally known previously. In this paper new rapid fabrication process with 355 nm UV laser ablation was proposed to get micro-nano structures on the surface of thin film, which have only been observed at higher laser fluence. Developed thin micro-nano structured film was also investigated the hydrophobic property by measuring the contact angle and demonstrated the possibility to apply to water droplet separation.

Physicochemical Properties of Potato Starches Hydroxypropylated with Propylene Oxide (Propylene Oxide로 하이드록시프로필화시킨 감자 전분의 이화학적 특성)

  • 배수경;이선자;김미라
    • Journal of the East Asian Society of Dietary Life
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    • v.7 no.4
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    • pp.519-526
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    • 1997
  • Physicochemical properties of potato starches with degree of substitution of 0-0.2645 hydroxypropylated with propylene oxide were examined. Hydorxypropyl group content of the starch was proportional to propylene oxide concentration. Water binding capacity increased but pH decreased with the increase of degree of substitution. Blue value and iodine absorption property decreased with the increase of hydroxypropylation. Differential scanning calorimeter showed that hydroxypropylation lowered the gelatinization temperature of the starch. Relative crystallinity in X-ray diffraction patterns decreased and starch granule observed by scanning electron microscopy was destroyed by hydroxypropylation. This result implied that high level hydroxypropylation affected the crystal region as well as amorphous region of starch.

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Study on Dyeing Properties of Nylon 66 Nano Fiber (1) -Levelling Type Acid Dyes- (나일론 66 나노섬유의 염색성에 관한 연구(1) -균염성 산성염료-)

  • 이권선;이범수;박영환;김성동;김용민;오명준;정성훈
    • Textile Coloration and Finishing
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    • v.16 no.4
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    • pp.1-9
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    • 2004
  • In recent, development of nano fiber has been one of the most active subjects in the world. Nano fiber is defined as a ultra fine yarn with a diameter unit of $10-100\times10^{-9}meter$, which is possible to be produced by an electro-spinning technology. In this study, physical characteristics and dyeing properties of nylon 66 nano fiber were investigated. Nylon 66 nano fiber was dyed with levelling type acid dyes. X-ray diffraction method and DSC analysis were used for the measurement of the degree of crystallization. Analysis of amino end groups was also performed in order to examine a relationship between number of amino groups and its dyeing property as well as water absorption behavior. The maximum exhaustion % of dyes and dyeing rate under various dyeing conditions, such as dyeing temperature and pH in dye bath, along with build-up properties for 2 acid dyes were evaluated. It was found that the degree of crystallization of nano fiber was smaller than that of regular fiber, and amino end groups of nano fiber were less than regular fiber. Half dyeing time of nano fiber was shorter than regular fiber because of the bigger specific surface area. Effect of pH on exhaustion % was small in case of nano fiber. Exhaustion of nano fiber increased with higher concentration of dye.

Correlation of mineralogical and textural properties with mechanical qualities of granite dimension stone from the Namwon area, Korea (남원지역 화강암 석재의 품질, 암석조직과 구성광물의 비교연구)

  • 홍세선;윤현수;이병태
    • The Journal of Engineering Geology
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    • v.14 no.1
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    • pp.105-121
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    • 2004
  • The purpose of this study is to investigate the relationship between petrographical and engineering properties of granitic rocks, widely used as building and ornamental stones in Korea, at the Namwon are a. This area is one of the most famous area as a domestic dimension stone production. The granitic rocks were examined for grain sizes, modal compositions and then same samples were tested to determine specific gravity, water absorption, porosity, uniaxial compressive strength, tensile strength, abrasive hardness, P-wave velocity, modulus of elasticity and Poisson's ratio. It is suggested that the influence of the grain size on the engineering properties is more important than that of the mode of mineralogical compositions. And quartz contents also significantly influence the engineering properties of granitic rocks.

Effect of Temperature and Sodium Chloride on Seed Germination of Thuja orientalis (온도 및 염화나트륨이 측백나무 종자 발아에 미치는 영향)

  • Tak Woo-Sik;Kim Tae-Su;Choi Chung-Ho
    • Korean Journal of Plant Resources
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    • v.19 no.1
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    • pp.97-104
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    • 2006
  • This study was conducted to investigate effect of temperature and NaCl on the seed germination and water absorption of Thuja orientalis. Seeds were treated with 0, 500, 1,000, 2,000 and 4,000ppm of NaCl and placed in different chambers at 15, 20, 25 and $30^{\circ}C$, respectively. And seed properties and relative water absorptions were analyzed. Germination decreased with the increase of both temperature and NaCl concentration, and especially the difference was obvious at $30^{\circ}C$. Dormancy and mortality increased with the increase of temperature in non-NaCl treatment. Two-way analysis of variance showed significant effects of temperature, NaCl concentration and interaction between temperature and NaCl concentration (p<0.001). Mean germination time increased with the increase of NaCl concentration at 15, 20 and $25^{\circ}C$ but decreased at $30^{\circ}C$ because the seeds were mortal by NaCl high concentration, Germination speed and germination performance index decreased with the increase of NaCl concentration. Those represented decreasing tendency with NaCl concentration but high positive correlation with germination. Relative water absorption decreased with the increase of NaCl concentration and represented high values at $15^{\circ}C$, and showed high positive correlations with germination, germination speed and germination performance index. It was reported that the high temperature and salinity were inhibitive factors of seed germination of Thuja orientalis.

Experimental Study on Physical Properties and Water Absorption Resistance Evaluation of Cement Mortar Incorporating Inorganic Metal Salt-based Water Repellent Powder (무기물 금속염계 발수분체를 혼입한 시멘트 모르타르의 물리적 특성 및 수분흡수저항성에 대한 실험적 연구)

  • Lee, Won Geun;Yoon, Chang Bok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.609-616
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    • 2021
  • In this experimental, water-repellent powder, which is a metal salt-based inorganic substance, and natural zeolite powder, which is a pozzolan-based material, were mixed into cement mortar, and their physical properties and resistance to moisture were confirmed. It was confirmed that the test specimen using natural zeolite at the same time had excellent resistance in the water permeation test and the chloride penetration test as compared with the test specimen in which the inorganic metal salt-based water-repellent powder was mixed alone. When a metal salt-based water-repellent powder is used, it cannot be uniformly dispersed inside water due to its insoluble property, and is limited to the surface. When used at the same time as natural zeolite, the setting time at the initial stage of hydration is fast due to the pozzolan reaction, and the water-repellent powder adheres to the porous of the natural zeolite and is evenly distributed inside the test specimen to generate some water resistance.

CO2 Capture Performance of Dry Sorbents Manufactured by Coal Fly Ash (석탄 화력발전소의 비산재를 이용한 건식 CO2 흡수제 제조 및 특성 연구)

  • Lee, Jae Hee;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.547-553
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    • 2013
  • This paper investigates the effect of coal-fired fly ash on dry $CO_2$ sorbents as the supports and additives. For this purpose, various kinds of dry sorbent were manufactured by mixing fly-ash, the primary $CO_2$ absorption components (NaOH and CaO) and water with their different combination. Thereafter, their $CO_2$ absorption performance and the property were analyzed. As a result, variation of absorption efficiency and temperature as well as $CO_2$ desorption of the sorbents are confirmed, which may be primarily ascribed to fly-ash addition to the sorbents. Particularly, fly-ash effect is strongly measured in the sorbent manufactured by mixing all four components (named WNCF sorbents). Absorption efficiency of WNCF sorbents at $550^{\circ}C$ is 35.6% higher than that of flyash free sorbent and desorption is solely observed in WNCF sorbents. Fly-ash in WNCF sorbents leads to increase the dispersity of $CO_2$ absorption components and decrease their particle size in the sorbents. In addition, fly-ash is used as the supports and pozzolanic reaction is hindered by NaOH in WNCF sorbent. Furthermore, $CO_2$ desorption from the sorbents may be due to fly-ash. The interaction between fly-ash and $CO_2$ absorption components substantially attenuate the strength between captured $CO_2$ in CaO and NaOH.

The Effects of Sintering Temperature Influence on the Mechanical Property and Microstructure of Dental Zirconia Block (치과용 지르코니아 블록의 소결온도가 기계적 특성과 미세구조에 미치는 영향)

  • Jo, Jun-Ho;Seo, Jeong-Il;Bae, Won-Tae
    • Journal of Technologic Dentistry
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    • v.36 no.1
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    • pp.9-15
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    • 2014
  • Purpose: Generally dental technicians clinically decide the sintering temperature of zirconia artificial teeth to match the color of the teeth. However, the sintering temperature influence the microstructure and mechanical strength of ceramic body. In this study, to evaluate the free choice of sintering temperature which leads to color the problems in zirconia false teeth, the variation of microstructure, mechanical strength, and colortone of zirconia ceramics according to the change of sintering temperature was investigated. Methods: Bar type specimens were prepared from commercial zirconia blocks by cutting and polishing into $0.8cm(L){\times}1.0cm(W){\times}4.8cm(H)$. Specimens were fired from 1,400 to $1,700^{\circ}C$ at $50^{\circ}C$ intervals and held for 1hour at highest temperature. Apparent porosity, water absorption, firing shrinkage, bulk density, bend strength, whiteness were tested. Microstructures were observed by SEM. Results: When fired above $1450^{\circ}C$, all specimens showed 0% apparent porosity and water absorption, 20% firing shrinkage, and $6.1g/cm^3$ bulk density regardless of firing temperatures. SEM photomicrographs showed grain growth of zirconia occurred above $1,600^{\circ}C$. Whiteness was also largely changed above this temperature. Maximum bend strength of 1,05MPa was obtained at $1,550^{\circ}C$. Bend strength lowered slightly above this temperature and showed $950{\ss}\acute{A}$ at $1,700^{\circ}C$. Conclusion: In order to fit the colortone of zirconia artificial teeth, arbitrary choice of firing temperature higher than $1,500^{\circ}C$, up to $1,700^{\circ}C$ did not influence the mechanical strength.

Influence of Fly Ash Addition on Properties of Ceramic Wall Tiles (플라이애시 첨가에 따른 세라믹 벽타일 소지의 물성변화)

  • Kim, Jin-Ho;Cho, Woo-Seok;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Korean Journal of Materials Research
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    • v.27 no.2
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    • pp.76-81
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    • 2017
  • Recently, there have been many efforts to establish suitable processes for recycling fly ash, which is produced in thermal power plants and which poses serious environmental problems. Use of fly ash as a major ingredient of ceramic tiles can increase fly ash utilization, as well as reduce the cost of raw materials in ceramic tile production. In this study, the effects of fly ash addition on ceramic tile properties such as bending strength, water absorption and porosity were investigated. A manufacturing process of ceramic tile was developed for utilization of fly ash with high carbon content. In this approach, it is important to hold the ceramic tiles at a temperature that is sufficient for carbon oxidation, before the pores supplying oxygen to the inside of the ceramic tile are sealed. Ceramic wall tiles were manufactured with 0-40wt% of fly ash addition. The water absorption and porosity of the fired body were slightly changed with increasing fly ash content up to 30wt% and decreased with greater amounts of fly ash addition. The bending strength of ceramic tile including 10wt% fly ash increased, reaching a level comparable to that of ceramic tile without fly ash.