• Title/Summary/Keyword: water/binder ratio

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Study on Characteristics of Fine Bottom Ash Based Geopolymer Mortar (미분쇄 바텀애시 기반 지오폴리머 모르타르 특성에 관한 연구)

  • Lim, Gwi-Hwan;Lee, Jeong-Bae;Jeong, Hyun-Kyu;Kim, Seong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.418-424
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    • 2016
  • This study is an experimental study on the recycling of bottom ash in coal ash discharged from a thermal power plant. Bottom ash has limited research on recycling because it has more porous and higher water absorption ratio than fly ash. In this paper, the bottom ash was pulverized to a specific surface area of $4,000cm^2/g$ in order to use as a binder, and the flow, compressive strength test and microstructure analysis of the bottom ash based geopolymer mortar were performed. The flow measurement results of the geopolymer mortar showed that the flow rate was improved by increasing mixing water as the molar concentration of activator was increased. Compressive strength increased with increasing curing temperature and molar concentration. Through the microstructure analysis, we could confirm the geopolymer gel produced by the reaction of the condensation polymerization. It is considered that it is possible to make the bottom ash based geopolymer concrete through proper molar concentration of activator and high temperature curing.

The Comparison of Apparent Chloride Diffusion Coefficients in GGBFS Concrete Considering Sea Water Exposure Conditions (해양 폭로 환경에 따른 GGBFS 콘크리트의 겉보기 염화물 확산계수 비교)

  • Yoon, Yong-Sik;Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.2
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    • pp.18-27
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    • 2022
  • In this study, the time-dependent chloride ingress behavior in GGBFS concrete was evaluated considering marine exposure conditions and the properties of concrete mixtures. The concrete mixture for this study had 3 levels of water to binder ratio and the substitution rate of GGBFS, and outdoor exposure tests were performed considering submerged area, tidal area, and splash area. According to the evaluation results of diffusion coefficient considering properties of concrete mixtures, as the substitution rate of GGBFS increased, the decreasing rate of the diffusion coefficient decreased based on exposure periods of 730 days(2 years). As the evaluation result of the diffusion behavior according to the marine exposure conditions, the diffusion coefficient was evaluated in the order of submerged area, tidal area, and splash area. In tidal area, a relatively high diffusion coefficient was evaluated due to the repetition of wet and dry seawater. In this study, the effects of GGBFS substitution rate on the decreasing behavior of apparent chloride diffusion coefficient was analyzed in consideration of exposure conditions and periods. Linear regression analysis was performed with apparent chloride diffusion coefficient as output value and GGBFS substitution rate as input value. After 730 days of exposure, the effect of GGBFS on diffusion coefficient was significantly reduced. Even for OPC concrete, after 730 days, the diffusion coefficient was as low as that of GGBFS concrete, so the gradient of the regression equation decreased significantly. It is thought that improved durability performance for chloride ingress can be secured before 730 days through the use of GGBFS.

Evaluation of Chloride Diffusion Behavior and Analysis of Probabilistic Service Life in Long Term Aged GGBFS Concrete (장기 재령 GGBFS 콘크리트의 염화물 확산 거동 평가 및 확률론적 염해 내구수명 해석)

  • Yoon, Yong-Sik;Kim, Tae-Hoon;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.47-56
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    • 2020
  • In this study, three levels of W/B(Water to Binder) ratio (0.37, 0.42, 0.47) and substitution ratio of GGBFS (Ground Granulated Blast Furnace Slag) rate (0 %, 30 %, 50 %) were considered to perform RCPT (Rapid Chloride Diffusion Test) at the 1,095 aged day. Accelerated chloride diffusion coefficient and passed charge of each concrete mixture were assessed according to Tang's method and ASTM C 1202, and improving behaviors of durability performance with increasing aged days are analyzed based on the test results of previous aged days from the preceding study. As the age of concrete increases, the passed charge and diffusion coefficient have been significantly reduced, and especially the concrete specimens containing GGBFS showed a significantly more reduction than OPC(Ordinary Portland Cement) concrete specimen by latent hydraulic activity. In the case of OPC concrete's results of passed charge, at the 1,095 days, two of them were still in the "Moderate" class. So, if only OPC is used as the binder of concrete, the resistance performance for chloride attack is weak. In this study, the time-parameters (m) were derived based on the results of the accelerated chloride diffusion coefficient, and the deterministic and probabilistic analysis for service life were performed by assuming the design variable as a probability function. For probabilistic service life analysis, durability failure probabilities were calculated using Monte Carlo Simulation (MCS) to evaluate service life. The service life of probabilistic method were lower than that of deterministic method, since the target value of PDF (Probability of Durability Failure) was set very low at 10 %. If the target value of PDF suitable for the purpose of using structure can be set and proper variability can be considered for each design variable, it is believed that more economical durability design can be made.

Enhancing the Performance of Polypropylene Fiber Reinforced Cementitious Composite Produced with High Volume Fly Ash (폴리프로필렌 섬유로 보강된 하이볼륨 플라이애시 시멘트 복합재료의 성능 향상 기법)

  • Lee, Bang Yeon;Bang, Jin Wook;Kim, Yun Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.118-125
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    • 2013
  • The synthetic fibers including Polyvinyl alcohol and Polyethylene fibers have been successfully used in the manufacture of high ductile fiber reinforced cementitious composites. Polypropylene (PP) fiber has also been used in composites, not for the purpose of achieving a high level of tensile ductility but to improve the fire resistance performance of concrete exposed to high temperatures. This paper discusses the method for enhancing the performance of composites supplemented with PP fiber. Five types of mixture proportions were designed with high volume fly ash for testing the performance of composites. Type I cement and fly ash F were used as binding materials. The water-to-binder ratio was 0.23~0.25, and the amount of PP fiber used was 2 vol%. Polystyrene bead were also used to increase the tensile ductility of composites. A series of experiments including slump, density, compression and uniaxial tension tests were performed to evaluate the performance of cementitious composites supplemented with PP fiber. From the test results, it was exhibited that the performance of composites supplemented with PP fiber can be enhanced by adopting the mechanics and statistics theory.

Prediction Model for Autogenous Shrinkage of High Strength Fly Ash Concrete (고강도 플라이 애쉬 콘크리트의 자기수축 예측 모델)

  • Lee, Hoi-Keun;Lee, Kwang-Myong;Kim, Woo
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.134-142
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    • 2003
  • Autogenous shrinkage, a significant contributor of early-age cracking of high strength concrete (HSC), must be avoided or minimized from an engineering point of view. Therefore, it is necessary to study how to reduce and to predict autogenous shrinkage with respect to tile control of early-age cracking. In this study, autogenous shrinkage of HSC with various water-binder ratio (W/B) ranging from 0.50 to 0.27 and fly ash content of 0, 10, 20, and 30% were investigated. Based on the test results, thereafter, a prediction model for autogenous shrinkage was proposed. Test results show that autogenous shrinkage increased and more rapidly developed with decreasing the W/B. Also, the higher fly ash contents, the smaller autogenous shrinkage. In particular, even if much autogenous shrinkage occurs at very early-ages, stress may not be developed while the stiffness of concrete is low. In order to consider the change of concrete stiffness, the transition time referred as stiffening threshold, was obtained by monitoring of ultrasonic pulse velocity evolution and considered in the autogenous shrinkage model. From a practical point of view, the proposed model can be effectively used to predict autogenous shrinkage and to estimate stress induced by autogenous shrinkage.

Evaluation on Durability of High Performance Concrete with Expansive Additive and Shrinkage Reducing Admixture (팽창재와 수축저감제를 사용한 고성능 콘크리트의 내구성 평가)

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.205-211
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    • 2006
  • The objective of this study was to evaluate the durability of low shrinkage high performance concrete(LSHPC), which was combined with expansive additives and shrinkage reducing admixtures. We tested for not only LSHPC but also high performance concrete(HPC) and normal concrete(NC) to be compared with the durability of LSHPC. HPC was made in the same water-binder ratio of LSHPC without expansive additives and shrinkage reducing admixture. As a result, it was found that LSHPC had higher compressive and tensile strength than that of HPC. LSHPC showed more excellent performance than HPC and NC in the case of resistance to chloride ion penetration and resistance to carbonation and also showed nearly 100 durability factor in the freeze-thawing test with 500 cycles. From the examination about the watertightness and the pore distribution, it was found that the durability of LSHPC was improved because its hardened cement paste is organized closer. So we can conclude that when LSHPC is applied to structures in field, it is possible to reduce the shrinkage and crack in concrete and improve the durability.

Characteristics of Early-Age Restrained Shrinkage and Tensile Creep of Ultra-High Performance Cementitious Composites (UHPCC) (초고성능 시멘트 복합체의 초기 재령 구속 수축 및 인장 크리프 특성)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.5
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    • pp.581-590
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    • 2011
  • Since ultra-high performance cementitious composites (UHPCC) not only represents high early age shrinkage strain due to its low water-to-binder ratio (W/B) and high fineness admixture usage but also reduces the cross section of structure from the higher mechanical properties, it generally has more shrinkage cracks from the restraints of formwork and reinforcing bars. In this study, free and restrained shrinkage experiments were conducted to evaluate the suitability of incorporating both expansive admixture (EA) and shrinkage reducing agent (SRA). The test results indi-cated that approximately 40~44% of free shrinkage strain was decreased. Also, the results showed that 35% and 47% of residual tensile stresses were relieved by synergetic effect of SRA and EA, respectively. Residual tensile stresses from ringtest were relaxed by approximately 61% and 64% of elastic shrinkage stresses due to SRA and EA, respectively, because of the tensile creep effect. Therefore, the creep effect should be considered to precisely estimate the restrained shrinkage behavior of concrete structures. The degree of restraint of UHPCC was approximately in the range of 0.78~0.85. The addition of combined EA and SRA showed minute influence on the degree of restraint. However, the effect decreased when thicker concrete ring was used. Tensile creep strains were measured and compared to the predicted values from 4-parametric prediction model considering time dependent restrained forces.

Influence of Superplasticizers on Fluidity and Compressive Strength of Alkali Activated Slag Mortar (유동화제가 알칼리 활성 슬래그 모르타르의 유동 특성 및 압축 강도에 미치는 영향)

  • Kim, Dae-Wang;Oh, Sang-Hyuk;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.33-40
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    • 2013
  • The cement industry brought very severe environment problems with massive carbon dioxide during its production. To solve this problem, attempts on Alkali-Activated Slag (AAS) concrete that perfectly substitutes industrial by-products such as ground granulated blast furnace slag (GGBFS) for cement are being actively made. AAS concrete is possible to have high strength development at room temperature, however, it is difficult to ensure the working time due to the fast setting time and the loss of workabillity because of the alkali reaction. In this study, the early age properties of alkali activated slag mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The water-binder ratio (W/B) was fixed at 0.35 and sodium hydroxide and waterglass as alkali activator was used. The compressive strength, the flow and the ultrasonic pulse velocity were measured according to the type of superplasticisers, which were naphthalene(N), lignin(L), melamine(M) and PC(P), up to a maximum of 2 percent by the mass of GGBFS. The results showed that adding melamine type of superplasticizer improved the fluidity of AAS mortar without decreasing the compressive strength, while naphthalene and polycarbonate type of superplasticizer had little effect on the fluidity of AAS mortar.

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Properties and Prediction Model for Ultra High Performance Fiber Reinforced Concrete (UHPFRC): (I) Evaluation of Setting and Shrinkage Characteristics and Tensile Behavior (초고성능 섬유보강 콘크리트(UHPFRC)의 재료 특성 및 예측모델: (I) 응결 및 수축 특성과 인장거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5A
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    • pp.307-315
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    • 2012
  • Recently, ultra high performance fiber reinforced concrete (UHPFRC) having over 180 MPa compressive strength and 10 MPa tensile strength has been developed in Korea. However, UHPFRC represents different material properties with normal concrete (NC) and conventional high performance concrete (HPC) such as a high early age autogenous shrinkage and a rapid dry on the surface, because it has a low water-binder ratio and high fineness admixtures without coarse aggregate. In this study, therefore, to propose suitable experimental methods and regulations, and to evaluate mechanical properties at a very early age for UHPFRC, setting, shrinkage and tensile tests were performed. From the setting test results, paraffin oil was an appropriate material to prevent drying effect on the surface, because if paraffin oil is applied on the surface, it can efficiently prevent the drying effect and does not disturb or catalyze the hydration of cement. From the ring-test results, it was defined that the shrinkage stress is generated at the time when the graph tendency of temperature and strain of inner steel ring is changed. By comparing with setting test result, the shrinkage stress was firstly occurred as the penetration resistance of 1.5 MPa was obtained, and it was about 0.6 and 2.1 hour faster than those of initial and final sets. So, the starting time of autogenous shrinkage measurement (time-zero) of UHPFRC was determined when the penetration resistance of 1.5 MPa was obtained. Finally, the tensile strength and elastic modulus of UHPFRC were measured from near initial setting time by using a very early age tensile test apparatus, and the prediction models for tensile strength and elastic modulus were proposed.

Corrosion Resistance of Blended Concrete and Its Application to Crack Healing (혼합 콘크리트의 부식 저항성과 균열 치유 적용)

  • Lee, Chang-Hong;Kim, Tae-Sang;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.689-696
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    • 2009
  • In this study, electro-deposition method was applied to heal cracks in various blended concrete. The performance of the method was indirectly monitored by measuring impressed voltage, electrolyte, galvanic current monitoring, linear polarization resistance, and directly by image analysis of the cracks. The indirect and direct monitoring values are compared to develop guidelines for relating the indirect measures to actual crack healing. As a result, It was found that impressed voltage was convergence to 2.9V after 20000 minutes. From the galvanic current test results of artificial crack healing, the corrosion resistance showed that the order of 0.4 $>$ 0.6 $>$ 0.5 water to cement ratio. Furthermore, in view of binder, the corrosion resistance order was calculated OPC $>$ 60%GGBS $>$ 10%SF $>$ 30%PFA. Finally, It was found that 76.47% of healed crack surface calculated from the artificial crack healing technique using electrochemical deposition method.