As a result of technical advances and industrialization, the characteristics of domestic and industrial wastes are becoming more complex. Accordingly, improved treatment and disposal systems are being continuously sought to take account of complex characteristics and to comply with economic restrictions. In this study, an application of pyrolysis to the treatment of industrial wastes, including waste scrap rubber, waste raw material used in making the slipper bottom and waste PVC pipe, and the effectiveness of pyrolysis in resource recovery from these wastes were investigated. Batches of wastes were pyrolysed by external heating to a temperature of 400-800$\circ$C in a 32 mm diameter x 0.9 m long silica tube to produce combustible gases, oils and chars. Before the start of pyrolysis runs, the entire system was purged with nitrogen gas to exclude the air. The temperature inside the retort was controlled by the thermocouple in the gas stream, and referred to as the pyrolysis temperature. Under these conditions three products were separately collected and further analyzed. The results were summarized as follows. 1. More gases and less chars were produced with higher pyrolyzing temperature and with higher rates of heating, but the yields of oils tended downwards at temperatures above 700$\circ$C. Accordingly, operating conditions of pyrolysis should be varied with desired material. 2. Calorific values and sulfur contents of produced oils were sufficient and suitable for fuel use. Chars from waste rubber had high heating values with low sulfur contents, but calorific values of chars from waste PVC and waste slipper were as low as 3, 065-4, 273 kcal/kg and 942-2, 545 kcal/kg, respectively. Therefore, char from these wastes are inappropriate for fuel. 3. Soluble contents of Pb, Cd, Cu and Zn in chars from waste rubber and waste slipper were below the Specific Hazardous Waste Treatment Standards. However soluble contents of Pb and Cd in chars from waste PVC were one or two times and five or seven times exceedingly the Specific Hazardous Waste Treatment Standards, respectively. 4. Post high heating is desirable for treatment method of waste PVC which generates toxic hydrogen chloride. 5. The proportions of hydrogen, methane and ethane in produced gases were in the range of 3.99-35.61% V/V, 18.22-32.50% V/V and 5.17-5.87% V/V, respectively. 6. Pyrolysis is a useful disposal method in case of waste slipper, which was hardly combustible, and thus investigations of this kind of materials are required for effective management of industrial waste. 7. Based upon the possible market development for products, overall pyroly economics to take account of treatment values of noncombustible or hazardous materials should be evaluated.
Proceedings of the Korean Society of Soil and Groundwater Environment Conference
/
2005.04a
/
pp.253-259
/
2005
Mine is quickly decline, Nowadays, many of abandoned and closed mines. AMD is abandoned surface water by accumulated yellowboy and caused environmental pollution by amount of heavy metals. The aim of this study waste lime was mixed with the sediment to produce an aggregate far the purpose of neutralizing the acidity and stabilization the heavy metal in the aggregate structure .to pozzolan effect. The result of Waste lime and sediment mixed(5%, 10%, 20%)ration by curing days(3, 7, 38days), After 28 curing days as 5% mixed waste lime leaching solution concentration of all heavy metals is satisfied with regulation limit. Also, the result of fractionate heavy metals to stabilization as 28 curing days very decrease exchangeable and reducible type, and then increase carbonate type. With the above results, waste lime the most effective for the sediment treatment and useful for the recycling waste resource.
The integrated solid waste management for Seoul Metropolitan city can be established on the basis of the following hierarchy of priorities: 1. Efforts for source reduction should be propelled by both government and citizens to achieve the effects of resource conservation. The adequate production and consumption which are environmentally amenable and sustainable can be induced by the reasonable imposition of deposit money for waste treatment to one-time use products. To accomplish source reduction effectively, the induction of legal and institutional regulation of producer and consumer participation is requisite. 2. For resource recovery, wastes generated should be recycled as far as practicable. Community residents are responsible to separate discharge, the authorities concerned have responsibility of separate collection, and recycling industry should be assissted through tax reduction and financing. Resource separation facilities can be constructed at Kimpo Metropolitan landfill site for wastes not separately collected due to some unavoidable circumstances. 3. Garbage should be composted. Garbage is uneconomical for incineration, because it has high moisture content and low calorie, thus there is no reason for the incineration of garbage even though garbage is classified into combustibles. Composting facilities can be located at sites which are not densely populated and easily accessible to transportation, for example, Kimpo Metropolitan landfill site. Compost produced can be managed by the authorities for the use of fertilizer to a green tract of suburban land and farms. 4. Nonhazardous combustible wastes not recyclable can be utilized for thermal recovery at the incinerators which are completely equipped with pollution control devices. According to the trend of local autonomy and the equity principle of local autonomous entities, incineration facilities of minimal capacity required can be constructed at each districts of Seoul Metropolitan city which have organized local assembly. In case of Yangcheon district, the economically combustible waste quantity is about 260 tons/day which exceeds 150 tons/day, the incineration capacity of existing facility. But, from now on, waste quantity can be reduced substantially by the intensive efforts of citizens for source reduction and recycling and the institutional support of administrative organizations. Especially, it is indispensable for the government to constitute institutional and technological bases that can recycle paper and plastics form 43% of waste generated. A good time for constructing of incineration facilities for municipal solid waste can be postponed to the time that pollution control technologies of domestic enterprises are fully developed to satisfy the standards of air pollution prevention, because the life expectancy of Kimpo Metropolitan landfill site is about 25 years. Within this period, institutional improvements and technological advancements can be attained, while the air qual. ity of Seoul Metropolitan city can be ameliorated to the level to afford incineration facilities. 5. For final disposal, incombustibles and ash are landfilled sanitarily at Kimpo Metropolitan landfill site.
Research on construction waste unit was in progress in the 1995 when 'Proper Disposal and Recycling Measures for Construction Waste' was made by the Seoul Development Institute. Such an effort has been made in order to cope with the lack of natural resources in Korea and to utilize the reusable resources. Furthermore, these efforts have also increased due to the improved standing of Korea in the international community. A large number of residential buildings were built in the response to the government's policy by increasing the supply of houses between the 1970's and 1980's. In 2000, more reconstruction and redevelopment was done because of the aged buildings and change of use for those buildings. And the project has been actively promoted until now, which caused a sharp increase in the generation volume of construction waste. In Korea, 8 kinds of construction waste unit, including the standard construction manpower and materials estimation, are introduced. Currently, they provide standards to different building categories and waste properties while for construction sites different standards are applied. This study aims to measure the actual amount of construction waste after sample buildings are dismantled and analyzes the estimation of the waste quantity by using various standard units. Through comparison, this study will figure out the differences among the standard units in order to find out how to apply the standard units properly. Moreover, this research will provide practical measures to apply such units to construction sites.
Rapid urbanization, resource depletion, and limited land are further increasing the need for skyscrapers in city centers; therefore, it is imperative to enhance tall building performance efficiency and energy-generative capability. Potential performance improvements can be explored using parametric multi-objective optimization, aided by evaluation tools, such as computational fluid dynamics and energy analysis software, to visualize and explore skyscrapers' multi-resource, multi-system generative potential. An optimization-centered, software-based design platform can potentially enable the simultaneous exploration of multiple strategies for the decreased consumption and large-scale production of multiple resources. Resource Generative Skyscrapers (RGS) are proposed as a possible solution to further explore and optimize the generative potentials of skyscrapers. RGS can be optimized with waste-energy-harvesting capabilities by capitalizing on passive features of integrated renewable systems. This paper describes various resource-generation technologies suitable for a synergetic integration within the RGS typology, and the software tools that can facilitate exploration of their optimal use.
Journal of the Korea Organic Resources Recycling Association
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v.20
no.2
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pp.76-88
/
2012
In this study, the treatment flow of the recyclables(paper, plastic, metal, etc.) collected and separated from MSW was investigated throughout entire phase from separation and collection to final disposal. Based on the site survey, most recyclables came into six material recovery facilities were comparatively managed well. However, some of recyclables showed irrelatively transportation flow. Because the main income source of the recyclables transportation companies is profit margin between treatment and transportation cost based on economics only therefore, it occurs an unnecessary route and long distance transportation while going to final destination. This unreasonable system should be a serious problem relating establishment of the resource recycling system. As a result of this study, in order to establish the reasonably resource recycling system, recycling center including material recovery facility has to manage the recyclables generated in close range preferentially. Also integrated its treatment system over a wide area will need to be considered as a basic step for the reasonable reasonably resource recycling system.
Selection of appropriate liner type would be the most important factor to prevent groundwater contamination by leachate from waste management site. This report introduces the IWEM (Industrial Waste Management Evaluation Model) developed by US EPA to evaluate the potential pollution of groundwater under the waste management unit and to suggest an appropriate type of liner, and provides with the results of IWEM application to a coal-ash landfill site in Korea as a case study. IWEM uses a standard method using a database, a decision-making process based on site characteristics, and the user-friendly input-and-output system. Authors evaluate this model to be applicable in Korea provided that the database is replaced into local data.
Since 2005, food waste has been separately collected and recycled to animal feed or aerobic compost in South Korea. However, the conventional recycling methods discharge process wastewater, which contain pollutant equivalent to more than 50% of food waste. Therefore, anaerobic digestion is considered as an alternative recycling method of food waste to reduce pollutant and recover renewable energy. Recent studies showed that hydrogen can be produced at acidogenic stage in two-stage anaerobic digestion. In this study, the authors investigated the effects of pretreatment time and pH low set value on continuous mesophilic hydrogen fermentation of food waste. Food waste was successfully converted to $H_2$ when heat-treated at $70^{\circ}C$ for 60 min, which was milder than previous studies using pH 12 for 1 day or $90^{\circ}C$. Organic acid production dropped operational pH below 5.0 and caused a metabolic shift from $H_2/butyrate$ fermentation to lactate fermentation. Therefore, alkaline addition for operational pH at or over 5.0 was necessary. At pH 5.3, the result showed that the maximum hydrogen productivity and yield of 1.32 $m^3/m^3$.d and 0.71 mol/mol $carbohydrate_{added}$. Hydrogen production from food waste would be an effective technology for resource recovery as well as waste treatment.
Biodiesel is a clean energy resource that can replace diesel as fuel, which can be used without any structural changes to the engine. Vegetable oil accounts for 95 percent of the raw materials used to produce biodiesel. Thus, many problems can arise, such as rising prices of food resources and an imbalance between supply and demand. Most of the previous studies using waste cooking oil used waste cooking oil from a single material. However, the waste cooking oil that is actually collected is a mixture of various types of waste cooking oil. Therefore, in this study, biodiesel produced with mixed waste cooking oil was supplied to an agricultural single-cylinder diesel engine to assess its potential as an alternative fuel. Based on the results, the brake specific fuel consumption (BSFC) increased compared to diesel, and the axis power decreased to between 70 and 99% compared to the diesel. For emissions, NOx and CO2 were increased, but CO and HC were decreased by up to 1 to 7% and 16 to 48%, respectively, compared to diesel. The emission characteristics of the mixed waste cooking oil biodiesel used in this study were shown to be similar to those of conventional vegetable biodiesel, confirming its potential as a fuel for mixed waste cooking oil biodiesel.
The present study verifies compressive strength, ultrasonic pulse velocity, electrical resistance,permeable ratio, and shrinkage from waste glass controlled low strength materials (WGCLSM) and early-high-strength WGCSLM specimens, by replacing the sand with waste glass percentages of 0%, 10%,20%, and 30%. This study reveals that increasing amounts of waste LCD glass incorporated into concrete increases WGCLSM fluidity and reduces the setting time, resulting in good working properties. By increasing the glass to sand replacement ratio, the compressive strength decreases to achieve low-strength effects. Furthermore, the electrical resistance also rises as a result of increasing the glass to sand replacement ratio. Early-high-strength WGCSLM aged 28 days has twice the electrical resistance compared to general WGCSLM. Early-high-strength WGCSLM aged 7 days has a higher ultrasonic pulse velocity similar to WGCSLM aged 28 days. The variation of length with age of different compositions is all within the tolerance range of 0.025%. This study demonstrates that the proper composition ratio of waste LCD glass to sand in early-high-strength WGCSLM can be determined by using different amounts of glass-sand. A mechanism for LCD optical waste glass usage can be established to achieve industrial waste minimization, resource recycling, and economic security.
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