• 제목/요약/키워드: waste rates

검색결과 457건 처리시간 0.03초

Determination of reaction kinetics during vitrification of radioactive liquid waste for different types of base glass

  • Suneel, G.;Rajasekaran, S.;Selvakumar, J.;Kaushik, Chetan P.;Gayen, J.K.;Ravi, K.V.
    • Nuclear Engineering and Technology
    • /
    • 제51권3호
    • /
    • pp.746-754
    • /
    • 2019
  • Vitrification of radioactive liquid waste (RLW) provides a feasible solution for isolating radionuclides from the biosphere for an extended period. In vitrification, base glass and radioactive waste are added simultaneously into the melter. Determination of heat and mass transfer rates is necessary for rational design and sizing of melter. For obtaining an assured product quality, knowledge of reaction kinetics associated with the thermal decomposition of waste constituents is essential. In this study Thermogravimetry (TG) - Differential Thermogravimetry (DTG) of eight kinds of nitrates and two oxides, which are major components of RLW, is investigated in the temperature range of 298-1273 K in the presence of base glasses of five component (5C) and seven component (7C). Studies on thermal behavior of constituents in RLW were carried out at heating rates ranging from 10 to $40\;K\;min^{-1}$ using TG - DTG. Thermal behavior and related kinetic parameters of waste constituents, in the presence of 5C and 7C base glass compositions were also investigated. The activation energy, pre-exponential factor and order of the reaction for the thermal decomposition of 24% waste oxide loaded glasses were estimated using Kissinger method.

신축아파트 현장의 건설폐기물 발생원단위 개발을 위한 자재별 폐기물 수량 예측 방법: 건축공사 내역서의 투입 물량을 중심으로 (Estimation Method of Waste Amount from Materials to Develop Generation Rates of Construction Waste in New Apartment Construction Sites: Focused on Bill of Quantities for Architectural Works)

  • 정종석;송상훈;박성식;이석제
    • 토지주택연구
    • /
    • 제5권1호
    • /
    • pp.41-51
    • /
    • 2014
  • 국내 신축 공동주택 건설은 2002년 11% 이상의 증가를 기록한 후 매년 3~4% 대의 꾸준한 증가추세를 보이고 있다. 최근 공공부문의 아파트 신축공사 현장에서 폐기물 분리발주제도에 의한 최초 발주물량과 실제 발생물량의 과다한 차이가 발주자와 수급인 사이에서 빈번하게 논란을 일으키고 있다. 이에 대해서는 현장 환경관리 미흡, 초기 계약물량의 과소 등 다양한 원인이 제기되고 있으며, 특히 건설폐기물 수량 예측에 적용되는 발생원단위 기준에 대한 개정 요구가 갈수록 증가하고 있다. 대부분의 현행 원단위는 2000년대 초에 수립되어 기술 발전에 따라 새롭게 적용되는 자재와 공법으로 인한 폐기물 발생 유형과 수량의 변화를 반영하지 못한다는 문제점을 지니고 있다. 따라서 본 연구는 보다 정밀한 신축아파트 폐기물 발생 원단위를 개발하기 위한 기초작업으로서 현장의 공종별 폐기물 발생 유형과 수량 예측방법을 명확히 하고자 하였다. 이를 위해 2010년에서 2013년 사이에 착공한 신축 아파트 10개 현장의 건축공사 내역서를 확보하고, 건설폐기물 전문가와 현장 폐기물관리 담당자의 의견을 반영하여 각 내역항목에서 발생가능한 폐기물 유형과 실질 할증률을 검토하였다. 본 연구에서 가설공사부터 지급자재부문까지의 건축공사 내역항목별로 정리한 폐기물 발생여부와 유형, 수량예측 시 반영여부, 손실률 등의 자료는 향후 보다 현실적인 데이터에 근거한 간접추계방식의 원단위 개발에 기여할 것이다.

돈사폐수의 세정산발효시 온도와 전처리의 영향 (Effect of Temperature and Pre-treatment for Elutriated Acidogenic Fermentation of Piggery Waste)

  • 배진연;민경석
    • 한국물환경학회지
    • /
    • 제21권1호
    • /
    • pp.34-39
    • /
    • 2005
  • The performance of elutriated acid fermentation with slurry-type piggery waste was investigated, especially to evaluate the effects of temperature and pre-treatment. In the first phase, the acid elutriation reactor with piggery waste after centrifugation operated at both mesophilic and thermophilic conditions to evaluate the effect of temperature. Solubilization yield($gVFAs/gSCOD_{prod.}$) and acidification rate($gVFAs/gSCOD_{prod.}$) in the thermophilic digestion were 0.45 and 0.55, which were higher than those of the mesophilic digestion, 0.25 and 0.45. In addition, the acid elutriation reactor at thermophilic temperature is more effective in removing e-coli. In the second phase, the acid elutriation reactor was fed with piggery waste before centrifugation. With piggery wastes before centrifugation, the solubilization yield and the acidificaton rate were 0.40 and 0.80, respectively, which were higher than the rates using piggery waste after centrifugation at both mesophilic and thermophilic conditions. The higher sludge volume reduction of 80% benefits sludge management. Furthermore, economical advantages can be achieved by removing the pre-treatment process, such as centrifugation. Consequently, the treatment with piggery waste before centrifugation proved to be effective. Also, the optimum temperature condition was estimated at mesophilic or thermophilic conditions, considering solubilization yields and acidification rates, though the system should be heated.

석유화학폐수슬러지와 유기성 폐기물 혼합에 의한 연소특성 및 고형연료 폐기물화 재활용에 관한 연구 (A Study on Combustion Characteristics and Evaluating of RDFs(Refused Derived Fuels) from Mixture of Petrochemical Wastewater Sludge and Organic Matters)

  • 한영립;최영익
    • 한국환경과학회지
    • /
    • 제24권2호
    • /
    • pp.237-244
    • /
    • 2015
  • This objectives of research are to figure out combustion characteristics with increasing temperature with petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and sawdust, and to exam heating value and ignition temperature for using refused derived fuels(RDFs). After analyzing TGA/DTG, petrochemical sludge shows a rapid weight reduction by vaporing of inner moisture after $170^{\circ}C$. Gross weight reduction rate, ignition temperature and combustion rates represent 68.6%, $221.9^{\circ}C$ and 54.1%, respectively. In order to assess the validity of the RDFs, the petrochemical sludge by adding wasted organic matters which are waste electric wire, anthracite coal and waste sawdust. The materials are mixed with 7:3(petrochemical sludge : organic matters)(wt%), and it analyzes after below 10% of moisture content. The ignition temperatures and combustion rates of the waste electric wire, anthracite coal and waste sawdust are $410.6^{\circ}C$, $596.1^{\circ}C$ and $284.1^{\circ}C$, and 85.6%, 30.7% and 88.8% respectively. In heating values, petrochemical sludge is 3,600 kcal/kg. And the heating values of mixed sludge (adding 30% of the waste electric wire, anthracite coal and waste sawdust) each increase up to 4,600 kcal/kg, 4,100 kcal/kg and 4,300 kcal/kg. It improves the ignition temperatures and combustion rates by mixing petrochemical sludge and organic matters. It is considered that the production of RDFs is sufficiently possible by using of petrochemical sludge by mixing wasted organic matters.

처분환경조건에서 모의 방사성폐기물 붕규산유리고화체의 장기침출률 (Long-term leach rates of simulated borosilicate waste glasses under a repository condition)

  • 전관식;김승수;최종원
    • 방사성폐기물학회지
    • /
    • 제1권1호
    • /
    • pp.41-46
    • /
    • 2003
  • 심부 처분환경조건에서 붕규산유리고화체의 장기침출거동을 규명하기 위하여 3종의 모의붕규산유리고화체에 대한 장기침출실험이 1997년에 착수되었다. 5년간의 침출결과는 붕소가 본 붕규산유리고화체의 장기침출지표물질로 사용될 수 있음을 확인시켜 주었고, 비록 고화체들의 조성은 약간씩 다르지만, 초기 1년여 기간동안의 침출률을 제외한 장기침출률은 S/V에도 무관하게 0.03g/$m^2$-day 에 근접하는 경향을 보여주고 있다.

  • PDF

생활폐기물 특성 분석 및 소각시설의 CO2 배출량 평가 (Property Analysis of Municipal Solid Waste and Estimation of CO2 Emissions from Waste Incinerators)

  • 김병순;김신도;김창환;이태정
    • 한국대기환경학회지
    • /
    • 제26권6호
    • /
    • pp.657-665
    • /
    • 2010
  • Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

D시 생활폐기물 관리 방법과 온실가스 배출량과 감축량 산정 연구 (A Study of Estimation of Greenhouse Gas Emission and Reduction by Municipal Solid Waste (MSW) Management)

  • 윤현명;장윤;장용철
    • 한국폐기물자원순환학회지
    • /
    • 제35권7호
    • /
    • pp.606-615
    • /
    • 2018
  • Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately $63,323tCO_2\;eq/yr$ in 2005, while the lowest value of $35,962tCO_2\;eq/yr$ was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was $59,199tCO_2\;eq/yr$. The reduction rate by material recycling was the highest ($-164,487tCO_2\;eq/yr$) in 2016, followed by the rates by heat recovery with incineration ($-59,242tCO_2\;eq/yr$) and landfill gas recovery ($-23,922tCO_2\;eq/yr$). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was $-3.46MtCO_2\;eq$, implying a very positive impact on future $CO_2$ reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

물질흐름분석을 통한 사업장폐기물의 실제적인 재활용률과 최종처분율의 산정 및 분석 (Calculation and Analysis of Actual Recycling Rate and Final Disposal Rate of Industrial Waste by Material Flow Analysis)

  • 오길종;조윤아;김지연;김기헌
    • 한국폐기물자원순환학회지
    • /
    • 제35권8호
    • /
    • pp.785-798
    • /
    • 2018
  • Since the Framework Act on Resource Circulation was enacted in 2018, the government should establish a National Resource Circulation Master Plan every 10 years, which defines mid- to long-term policy goals and directions on the efficient use of resources, prevention of waste generation and recycling of waste. In addition, we must set mid- to long-term and stepwise targets for the final disposal rate, recycling rate (based on sorted recyclable materials and recycled products), and energy recovery rate of wastes, and relevant measures should be taken to achieve these targets. However, the current industrial waste (IW) statistics have limitations in setting these targets because the final disposal rate and recycling rate are calculated as the ratio of the recycling facility input to the IW generation. In this study, the material flow from the collection stage to the final disposal of industrial waste was analyzed based on the generation of 2016, and the actual recycling amount, actual incineration amount, final disposal amount and their rates were calculated. The effect on the recycling, incineration and final disposal rates was examined by changing the treatment method of nonhazardous wastes from the factory and construction and demolition wastes, which were put in landfills in 2016. In addition, the variation of the waste treatment charge was investigated according to the change of treatment methods. The results of this study are expected to be effectively used to establish the National Resource Circulation Master Plan and industrial waste management policy in the future in South Korea.

석탄폐석의 흡착능 및 흡착제로의 활용방안에 관한 기초 연구 (Fundamental Study on Adsorption Capacity and Utilization of Coal Waste as Adsorbents)

  • 한동준;임재명;이찬기;이해승
    • 한국토양환경학회지
    • /
    • 제2권2호
    • /
    • pp.61-72
    • /
    • 1997
  • 본 연구에서는 산과 계곡에 폐기물로 방치되어 있는 석탄폐석의 재활용 및 자원화의 측면에서 수처리에 이용될 수 있는 흡착제의 개발을 위한 기초실험이 수행되었다. 석탄폐석으로는 굴진폐석과 선탄폐석이 이용되었으며, 석탄폐석 자체가 지니고 있는 흡착능 실험과 열처리로 인한 흡착능 개선 여부를 검토하였다. 처리 대상물질은 중금속, 색도, 그리고 COD등을 선정하였다. 실험조건은 회분식과 컬럼식으로 구분하여 각각 이루어졌으며, 실험결과 다음과 같은 결론을 얻을 수 있었다. 1) 천연상태의 석탄폐석은 약 20~30%의 중금속 흡착능을 지니고 있는 것으로 나타났으며, 탄화 공정인 간단한 열처리만으로도 약 2~5배의 흡착능 향상이 이루어졌다. 2)석탄폐석의 열처리 조건 변화에 따른 중금속 흡착능을 비교한 결과, 50$0^{\circ}C$에서 6시간 반응시킨 것이 가장 우수하였다. 3)칼럼실험에 있어 기존의 입상활성탄 보다 처리효율이 저조하나 석탄폐석은 무가공 상태로도 약 20~60%의 COD 및 색도를 제거할 수 있었다. 4) $500^{\circ}C$, 에서 6시간 열처리된 폐석의 컬럼실험에서 생물학적 유출수의 색도 제거에 우수함을 알 수 있었으며, 중금속 및 COD제거에 있어서는 여과 속도에 따라 많은 차이를 보였다. 따라서 석탄폐석을 흡착제로의 활용이 가능할 것으로 판단되며, 본 연구 이외에 활성화 공정을 적용할 경우 흡착정도는 더 향상 될 것으로 판단된다.

  • PDF