• Title/Summary/Keyword: waste carbon materials

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Carbon nanotubes formation on clay and fly ash from catalytic thermal decomposition of recycled polypropylene

  • Nur A. Atikah Kamaruddin;Norzilah A. Halif;Siti A. Hussin;Mohd. N. Mazlee
    • Advances in materials Research
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    • v.13 no.3
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    • pp.173-181
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    • 2024
  • Fly ash, plastic waste, and clay are mineral materials and residues commonly found in Malaysia. In this study, these materials were fully utilized as raw materials for synthesizing carbon nanotubes (CNTs). Recycled polypropylene, previously used as a food container, served as a carbon source. Fly ash and clay were explored as potential substrates for CNTs growth. The recycled polypropylene was thermally decomposed at 900 ℃ in an inert environment for 90 minutes. Carbon atoms released during this process were deposited on fly ash and clay substrates, which had been immersed in a ferrocene solution to provide a metal catalyst for CNTs growth. The deposited products were characterized using a Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). Morphological analysis revealed that both fly ash and clay were coated with fiber-like structures, confirmed to be CNTs based on a diffraction peak around 26° from the XRD pattern. In conclusion, clay and fly ash demonstrate the potential to be utilized as substrates for CNTs formation.

Performance Evaluation of Eco-friendly Permeable Block Using Basalt Waste Rock (현무암 폐석을 이용한 친환경 투수블록의 성능평가)

  • Sang-Soo Lee;Hyeong-Soon Kwon;Jae-Hwan Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.299-306
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    • 2023
  • Environmental pollution problems are occurring due to the negative treatment of basalt waste in Jeju Island. This study identifies the characteristics of permeable block with basalt with physical and chemical adsorption mechanisms and examines their applicability and functionality as building materials. This experiment is basic data for evaluating the functionality of the permeable block by analyzing flexural strength, compressive strength, permeability coefficient, carbon dioxide, and fine dust adsorption rate by producing a permeable block using a basalt waste rock. As the basalt waste stone replacement rate increased, the flexural strength and compressive strength tended to decrease, and as the replacement rate increased, the water permeability coefficient, absorption rate, carbon dioxide, and fine dust adsorption rate tended to increase. Therefore, it is judged that the permeable block using the basalt waste rock is superior to the existing permeable block.

Characterization of artificial aggregates fabricated from coal bottom ash containing much unburned carbon (미연탄소가 다량 함유된 석탄바닥재로 제조된 인공골재의 물성분석)

  • Kang, Min-A;Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.1
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    • pp.47-53
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    • 2011
  • The artificial aggregates (AAs) were manufactured from the parent batch powders consisting of bottom ash containing excess unburned carbon and dredged soil, 7 : 3 weight ratio by direct sintering method and those physical properties were evaluated. Especially, the effects of waste glass or frit (NWG) which was made by addition of 5 wt% $Na_2O$ to the waste glass upon the bloating phenomenon of AAs were analyzed. The AAs manufactured from the parent batch powders showed a lower specific gravity than that of specimens containing waste glass or NWG due to excess u$Na_2O$nburned carbon which usually obstructs a sintering process. But, the waste glass added on parent batch powders promoted the sintering and densification thus increased the specific gravity of AAs. Also the specific gravity of AAs added with 5 wt% NWG, was lowered compared to that of AAs added with as-received waste glass. This is because of bloating of shell which captures gases owing to the lowered viscosity of liquid formed at the specimen surface caused by $Na_2O$ addition. In conclusion, the AAs sintered at above $1100^{\circ}C$ in this study showed characters of lightweight aggregate of specific gravity 1.15~1.34 and water absorption 11~19 %, and the bloating phenomenon of AAs was occurred at the shell rather black core part.

Properties of Lightweight Foamed Concrete with Waste Styrofoam and Crude Steel Cement (폐스티로폼과 조강시멘트를 혼입한 경량기포콘크리트의 특성)

  • Park, Chae-Wool;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.77-78
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    • 2020
  • In Korea, more than 30,000 tons of waste Styrofoam are produced every year. Styrofoam is spent more than 500 years decomposing during the reclamation process, so it needs to be recycled. The recycling rate of waste styrofoam continues to be the third highest in the world, but it is lower than that of Germany and Japan. Therefore, measures are needed to increase the recycling rate of waste Styropol. Another problem is that cement is mainly used in existing lightweight foam concrete. However, large amounts of CO2 from cement-producing processes cause environmental pollution. Currently, Korea is increasing its greenhouse gas reduction targets to cope with energy depletion and climate change, and accelerating efforts to identify and implement reduction measures for each sector. In 2013 alone, about 600 million tons of carbon dioxide was generated in the cement industry. Therefore, this study replaces CO2 generation cement with furnace slag fine powder, uses crude steel cement for initial strength development of bubble concrete, and manufactures hardening materials to study its properties using waste styrofoam. As a result of the experiment, the hardening agent replaced by micro powder of furnace slag was less intense and more prone to absorption than cement using ordinary cement. Further experiments on the segmentation and strength replenishment of furnace slag are believed to contribute to the manufacture of environmentally friendly lightweight foam concrete.

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Applications and prospect of CDM project through recycling of inorganic waste (무기질(無機質) 폐기물(廢棄物)의 재활용(再活用)을 통한 CDM 사업(事業) 적용사례(適用事例) 및 전망(展望) - 시멘트 산업(産業)을 중심(中心)으로 -)

  • Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan;Um, Seong-Il;Yeon, Kyu-Seok
    • Resources Recycling
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    • v.20 no.2
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    • pp.3-15
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    • 2011
  • Current, Registration fields of CDM projects are being conducted in a variety of parts such as mostly energy, chemical processing and manufacturing processes. However, there are not many CDM project registrations by recycling of inorganic waste. In this paper, analysis abroad CDM project and applications in order to review possibility of CDM project registration through the recycling of domestic inorganic waste were investigated. As a results, registered case of CDM project by inorganic waste recycling was researched to registrate in raw material alternative field of cement industry that inorganic waste can be used in large quantities. Application prospects of CDM project in Korea will be possible to analysis industrial scale, industry using inorganic raw materials, green house gas emissions and inorganic waste generated in large quantities.

A Study on Treatment Efficiency of Toluene and CO2 using Vortex Cyclones (보텍스 사이클론을 이용한 Toluene과 CO2 처리효율에 관한 연구)

  • 임계규
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.493-501
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    • 2004
  • The principle of vortex tube and cyclone was introduced to enhance the treatment efficiency of waste air streams containing particulate matters, toluene, and others developed by Hangreen Tech, Ltd. and Hoseo Chemical and Industrial Technology R&D Center. Adsorption, condensation, and/or coagulation could be induced at low temperature zone formed by vortex tube and Joule-Thomson expansion. The pressurized air was introduced at the tangential direction into the cyclone system applied with the coaxial funnel tube. Easily condensible vapors such as toluene. carbon dioxide, and water vapor were adsorbed enforcedly on coagulated or condensed materials which were formed as cores for coagulation or condensation by themselves. These types of coagulation or condensation rates were rapidly promoted as the diameter being growing up. The maximum removal efficiency for carbon dioxide and toluene was achieved to about 87 and 90 percent, respectively. The Joule-Thomson coefficients were increased with the pressure of air injected in the range of the relative humidities between 10% and 30%. An optimum value was observed within the range of the tested temperatures at a fixed pressure. In conclusion. it could be identified that the treatment efficiency would be depended on the pressure of the process air introduced and physical and chemical characteristics of waste air streams containing target materials for a designed system. The final design parameters should be decided depending upon the given system and target materials.

Consolidation to Bulk Ceramic Bodies from Oyster Shell Powder (굴 패각 분말로부터 벌크 세라믹 구조체 제조)

  • Cho, Kyeong-Sik;Lee, Hyun-Kwuon;Min, Jae Hong
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.221-227
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    • 2016
  • Waste oyster shells create several serious problems; however, only some parts of them are being utilized currently. The ideal solution would be to convert the waste shells into a product that is both environmentally beneficial and economically viable. An experimental study is carried out to investigate the recycling possibilities for oyster shell waste. Bulk ceramic bodies are produced from the oyster shell powder in three sequential processes. First, the shell powder is calcined to form calcium oxide CaO, which is then slaked by a slaking reaction with water to produce calcium hydroxide $Ca(OH)_2$. Then, calcium hydroxide powder is formed by uniaxial pressing. Finally, the calcium hydroxide compact is reconverted to calcium carbonate via a carbonation reaction with carbon dioxide released from the shell powder bed during firing at $550^{\circ}C$. The bulk body obtained from waste oyster shells could be utilized as a marine structural porous material.

Domestic Trends in Thermochemical Recycling Technology of Waste Plastics (폐플라스틱의 열화학적 재활용 기술 국내 동향)

  • Seon Ah Roh;Tai jin Min;Jin-Tae Kim;Bangwoo Han
    • Resources Recycling
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    • v.32 no.6
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    • pp.79-89
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    • 2023
  • One of the foremost environmental challenges, alongside the contemporary focus on achieving carbon neutrality, pertains to the pervasive issue of plastic waste. Thermochemical recycling technology, operating under high-temperature conditions to covert organic matter and recycle it into raw materials and energy, represents a transformative approach surpassing the conventional bounds of material recycling predominantly applied in plastic waste management. The thermochemical recycling paradigm is emerging as a pivotal technology within the circular economy, capable of transforming waste plastics into raw materials for producing original plastics. Its significance extends beyond national borders, garnering global attention due to its versatility as a chemical or energy recycling method, contingent upon the subsequent processes and final products. This study aims to scrutinize three quintessential thermochemical recycling technologies: combustion, gasification, and pyrolysis. Furthermore, the study discusses the recent major technology trends of these technologies.

Global Trend of Cement Production and Utilization of Circular Resources

  • Lim, Chaeyeon;Jung, Euntae;Lee, Seongho;Jang, Changsun;Oh, Chaewoon;Shin, Kyung Nam
    • Journal of Energy Engineering
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    • v.29 no.3
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    • pp.57-63
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    • 2020
  • In this paper, we reported that the global trend of cement production and utilization as raw materials and as a fuel. As we know, cement is one of the significant materials required for the construction industry. The recent trend of rising urbanization, both the cement and construction industry played a vital role. The cement industry is a major sustainable infrastructure for the countries. Currently, China producing cement half of the world's cement production. During the year 2018, Korea producing cements nearly 57.5 million metric tons. Waste materials are used as circular resources and also having tremendous benefits for cement production. Another important use of these circular resources is fuel for the cement industry. There is a large potential benefit of the cement industry, but it's creating a severe environmental threat. The cement industry contributes to the major emissions of CO2. This leads the global warming. As per the Paris agreement, the Korean government initiated the recycling policy of waste materials and also the utilization of circular resources for the prevention of limited natural resources and also the global warming effect.

A Study on Upcycle Fashion Design Based on the Characteristics of Materials and Techniques (재료 및 기법의 특성에 기반하는 업사이클 패션 디자인 연구)

  • Yu, Haemin;Chun, Jaehoon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.44 no.5
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    • pp.984-1003
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    • 2020
  • The global fashion industry produces significant carbon emission and micro-plastics in oceans. Studies on sustainable design methods as such environmental issues in fashion are becoming intensely problematic. This study conducted a case study on 100 upcycle fashion brands to propose strategical upcycle fashion designs to compete in a sustainable fashion market. A literature review indicated that 3 types of textile wastes are generated as upcycling materials: post-producer, pre-consumer and post-consumer. Wastes are categorized together with 3 types of techniques: redesigning, reconstruction and handcrafting. This research derived 7 types of upcycle fashion designs that have the following features: to make luxury upcycle fashion products, to make sustainable grunge looks, to re-evaluate deadstocks, to recover vintage clothes, to convert waste into craft-arts, to offer solutions for damaged products, and to make zero-waste small fabric waste. The study results show that key drivers in the upcycle fashion design are the redesignability of materials and technique-related costs. This study implies that adopting appropriate design features can be a useful strategy for designers. New technologies will solve current problems and encourage them to design products in a new circular value system.