• Journal of Environmental Science International
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• v.19 no.10
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• pp.1247-1256
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• 2010

Since biodiesel as bioenergy is defined as ester compounds formed by esterification of animal/vegetable oils, in this study three vegetable cooking oils (market, waste and refined waste ones) were esterified by reactions of alkali catalyst and immobilized enzyme. The fatty acid composition of the formed ester compounds was analyzed to investigate the feasibility of biodiesel production. By lipolysis (i.e, hydrolysis of Triglyceride (TG)), all three vegetable oils used in this study were found to produce Diglyceride (DG), Monoglyceride (MD) and Fatty acid ethylester (FAEE). However, the amount of produced FAEE (which can be used as an energy source) was in the increasing order of market cooking oil, waste one and refined waste one. With NaOH catalyst, FAEE was produced about 24.92, 17.63 and 11.31 % for the respective oils while adding Lipozyme TL produced FAEE about 43.54, 38.16 and 24.47 %, respectively. This indicates that enzyme catalyst is more effective than alkali one for transesterification. In addition, it was found that the composition of fatty acids produced by hydrolysis of TG was unchanged with alkali and immobilized enzyme reactions. Thus it can be expected that stable conditions remain in the course of mixing with gasoline whose composition is similar to that of the fatty acids.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.549-554
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• 2001

The authors have proposed that waste glass, which is crushed to pieces, can be used as a concrete aggregate. At the present time, recycled-glass concrete is used for sidewalk concrete blocks and pavement as glass is ornamental. However, in cases where recycled-glass concrete is used for structural concrete, strength and durability are required as structural concrete is exposed to the weather. Glass that is used generally is a mixture of SiO$_2$, Na$_2$O and CaO. SiO$_2$is the most likely cause of alkali-aggregate reaction when waste glass was used for concrete aggregate. In this study, an alkali-aggregate reaction test that is one of the important tests related to durability of aggregate was carried out far discussion of utilization of waste glass for concrete aggregate. From the results of the tests, it is found that glass is a reactive aggregate. The pessimum proportion of glass is about 75%. Then the cases of using fly ash, blast furnace slag and artificial zeolite for admixture materials were also examined for the purpose of prevention of alkali-aggregate reaction. from the results of the test, it was found that using them is an effective way to prevent alkali-aggregate reaction. The compressive strength in the cases of using admixture materials is larger than that without admixture materials.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.903-908
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• 2002

The production of waste glasses has been increased with the development of industry. The utilization of waste glass for concrete can cause the concrete to be cracked and to be weakened due to an expansion by alkali-silica reaction(ASR). When used the fibers with waste glass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass. In this study, we conducted basic experimental research to analyze the possibilities of recycling of amber waste glass as fine aggregates for steel fiber reinforced concrete. Test results of fresh concrete. slump is decreased because grain shape is angular and air content is increased due to involving small size particles so much in waste glasses. Also. tensile and flexural strengths increased as the content of steel fibers increased. In conclusion, the content of waste glass below 40% is reasonable and usage of pertinent admixture is necessary to obtain workability or air content.

• Resources Recycling
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• v.19 no.4
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• pp.13-18
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• 2010

Effort of reducing wastes and their recycling is increasing in worldwide. Especially, extreme care for alkali recycling is required because of its environmental pollution and its corrosive characteristics. In order to manage alkali wastes effectively, it is necessary to make quality standards for recycling products from the alkali wastes because there are no quality specifications yet. In this study, we selected several recycling candidates from the alkali wastes based on the analysis of the most recent data of the various industrial sites. As a result, the recycling candidates from the alkali wastes are sodium hydroxide, aluminum sulfate, poly aluminum chloride. It is believed that the proper management system for waste products is required in governmental point of view and it propagates positively for resolving various environmental issues.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.555-559
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• 2001

A by-product, waste sludge water produced from ready mixed concrete(remicon) factories may affect our environmental contamination if it is discharged without proper waste disposal. In Korea, all waste sludge water has been recycled in the way of mixing water of remicon, but the quality of the concrete then produced can be deteriorated, so it might cause slump loss or irregular compressive strength. In this study, waste sludge water is divided into two parts, remicon sludge and residual water in order to make it's property more stable. Then, the remicon sludge and high-alkaline residual water were used as admixture and alkali activator respectively. In this paper we research about quality of with remicon sludge and residual water and performed the fundamental properties of cement matrix mixed with remicon sludge and residual water.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.112-113
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• 2021

Since natural sand is being depleted, research is being conducted to use glass similar to sand as an aggregate. When non-reusable waste glass is crushed and used as fine aggregate, it is known that alkali of cement and silica of glass react to cause an alkali aggregate reaction. The purpose of this study is to provide basic data by studying the strength according to color to use waste glass as fine aggregate. When 10% was replaced, both flexural and compressive strength showed strength values similar to those of Plain. When replaced by 20% and 30%, the 7-day intensity was higher than that of Plain. In addition, colorless glass was found to have the highest strength among glass colors. More research is expected to be needed to become a fine aggregate of waste glass.

• Journal of the Korea Institute of Building Construction
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• v.13 no.4
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• pp.351-359
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• 2013

Blast furnace slag (BFS) have many advantages that are related to effective value improvement on applying to concrete while side effects of blast furnace slag also appear. Thus, research team conducted an experiment with high volume slag to see if the attribute of waste alkali accelerator for mixing rate, mixed use of NaOH and $Na_2SiO_3$, and early strength agent for mixing rate for replacement ratio and for the types of the stimulants in order to increase the use of blast furnace slag1s powder. As the result of the experiment, when it comes to compression strength, all of the alkali stimulants have been improved as the replacement rate increases except for sodium hydroxide. Among the alkali stimulants, sodium silicate was high on dynamic elastic modulus and absorption factor. In case of early strength agent, the mix of mixing 1.5% and blast furnace slag 75% have showed high strength enhancement. In event of Waste Alkali accelerator, it has showed different consequences for each experiment.

• Journal of environmental and Sanitary engineering
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• v.16 no.1
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• pp.108-116
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• 2001

It is difficult to task to achieve high biological nutrient removal from municipal wastewater because of low organic content. Volatile fatty acids(VFAs) produced from acid fermentation of food wastes can be utilized as external carbon sources for the biological nutrient process. Significant reduction and stabilization of the food wastes can also be obtained from the acid fermentation. The objective of this study is to evaluate characteristics of acid fermentation of the food wastes. Results obtained from the batch experiment of various organic wastes showed that the food wastes had high potential to be used as an external carbon source because of the largest production of the VFAs with low nitrogen and phosphorus content. The fish waste was found to be the next possible organic waste, while the others such as radish cabbage and molasses waste showed high VFAs consumption potential as a results of high nitrogen and phosphorus content. alkaline hydrolysis of the food waste was carried out using NaOH prior to the acid fermentation. As the alkali addition increased, solubilization of the organics as well as TSS reduction increased. However, fraction of soluble COD to total COD became stable after a sharp increase. Alkali addition greater than 0.5g NaOH per g TS resulted in significant increase in pH.

• Journal of Adhesion and Interface
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• v.18 no.3
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• pp.118-126
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• 2017

In a natural fiber-reinforced composite material, many studies have been devoted to improving the interfacial adhesion between natural fiber and polymer matrix and the composite properties through various fiber surface modifications. In the present study, waste wool-reinforced polypropylene matrix composites were fabricated by compression molding and their mechanical and impact properties were characterized. As a result, the tensile and flexural properties and the impact strength of waste wool/polypropylene composites strongly depended on the treatment medium, alkali treatment with sodium hydroxide (NaOH) and silane treatment with 3-glycidylpropylsilane(GPS). The composite with waste wool by silane treatment exhibited higher mechanical properties and impact resistance than that by alkali treatment. The fracture surfaces of the composites support qualitatively the increased properties, showing the improved interfacial bonding between the waste wool and the polypropylene matrix.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.268-277
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• 2004

process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.