• 펄프종이기술
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• 제48권1호
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• pp.127-133
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• 2016

This study is performed that furniture and interior materials of MDF's (Medium Density Fiberboard) biodegradation properties, and the goal of this study is investigation of possibility of waste-MDF's composting after landfilling. To investigate biodegradation, this study was performed according to KS M ISO 14855-1, and there were two different soil conditions including a compost condition and an activated vermiculite condition as artificial soil. This experiment was tested for 40 days. The measurement of carbon-dioxide generation was processed every 24 hour in 1-2 week, and every 48 hour after 3 week. In the same days, MDF showed 24.4% of biodegradation in compost condition, and 6.2% in activated vermiculite. Also, the reference material of TLC (thin-layer chromatography) grade cellulose showed 26.4%, 11.4% in compost and activated vermiculite respectively. The dilution plate method was performed for biological analysis in the study. This experiment was used for investigation of inoculum's (Bacillus licheniformis) activity. As the result of bioassay, compost has more other germs include inoculum than activated vermiculite in the first week. Especially in the 2nd week, the reference material under the compost condition showed the most germ's activity, and also the biodegradation was the highest. Consequentially, compost condition was able to reduce a performing period of biodegradation testing than activated vermiculite. However, activated vermiculite could be stabilizing errors between repetition.

• Journal of the Korean Wood Science and Technology
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• 제48권2호
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• pp.231-244
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• 2020

As a way of finding value-added materials from waste medium density fiberboard (MDF), this study characterized cellulose nanocrystals (CNCs) isolated by ammonium persulfate (APS) oxidation using recycled MDF fibers. Chemical composition of the recycled MDF fibers was done to quantify α-cellulose, hemicellulose, lignin, nitrogen, ash and extractives. The APS oxidation was performed at 60 ℃ for 16 h, followed by ultrasonication, which resulted in a CNC yield of 11%. Transmission electron microscope images showed that rod-like CNCs had an average length and diameter of 167±47 nm and 8.24±2.28 nm, respectively, which gave an aspect ratio of about 20. The conductometric titration of aqueous CNCs suspension resulted in a carboxyl content of 0.24 mmol/g and the degree of oxidation was 0.04. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy clearly showed the presence of carboxyl group on the CNCs prepared by the APS oxidation. The change of pH of the aqueous CNC suspension from 4 to 7 converted the carboxyl group to sodium carboxylate group. These results showed that the APS oxidation was facile and CNCs had a one-step preparation method, and thus suggested an optimization of the oxidation condition in future.

• Journal of the Korean Wood Science and Technology
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• 제31권3호
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• pp.1-10
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• 2003

Shredded waste newspapers, waste acrylic raw fibers, and urea-formaldehyde (UF) adhesives, at 10% by weight on raw material, were used to produce recycled waste paper-waste acrylic raw fiber composite boards in laboratory scale experiments. The physical and mechanical properties of fire retardant treated recycled waste paper-waste acrylic raw fiber composite boards were examined to investigate the possibility of using the composites as internal finishing materials with specific gravities of 0.8 and 1.0, containing 5, 10, 20, and 30(wt.%) of waste acrylic raw fiber and 10, 15, 20, and 25(wt.%) of fire retardant (inorganic chemical, FR-7^®) using the fabricating method used by commercial fiberboard manufacturers. The bending modulus of rupture increased as board density increased, decreased as waste acrylic raw fiber content increased, and also decreased as the fire retardant content increased. Mechanical properties were a little inferior to medium density fiberboard (MDF) or hardboard (HB), but significantly superior to gypsum board (GB) and insulation board (IB). The incombustibility of the fire retardant treated composite board increased on increasing the fire retardant content. The study shows that there is a possibility that composites made of recycled waste paper and waste acrylic raw fiber can be use as fire retardant internal finishing materials.

• Journal of the Korean Wood Science and Technology
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• 제47권2호
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• pp.163-177
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• 2019

폐MDF로부터 해섬하여 얻은 재생섬유를 Reactive Red H-E3B (Bis-monochlorotriazine(MCT)/MCT type)와 Reactive Red RB 133%(bis-monochlorotriazine/Vinyl sulphone type)로 염색할 때 최적의 염색조건을 구명하기 위하여 염색조건(염료 농도, 염과 알칼리 첨가량, 염색온도)과 염색특성 및 일광견뢰도와의 관계를 검토하였다. 2종의 반응성염료 모두 염료농도가 1~10(%,OWF)로 증가함에 따라 염착량(K/S)은 증가하였다. 또한, H-E3B가 RB 133%보다 염료 농도에 관계없이 K/S는 높았으며, 자외선 조사에 따른 색차는 낮아 자외선에 의한 변색 저항성이 양호하였다. 황산나트륨의 첨가량이 증가할수록 색차 및 K/S도 증가하였으며, 염의 첨가량은 50~70 g/L가 적절하였다. 2 g/L의 탄산나트륨 첨가에 의해 색차 및 K/S가 크게 증가하였으나 그 이상의 첨가량 증가에서는 거의 차이가 없었다. 탄산나트륨의 첨가량은 pH 10을 유지하는 5~10 g/L가 적절할 것으로 생각된다. H-E3B 염료는 염색 온도가 높아짐에 따라 염착량이 증가하다가 $80^{\circ}C$에서 다시 감소한 반면 RB 133%는 $60{\sim}70^{\circ}C$까지는 거의 동일한 염착량을 나타냈으나, 이후 감소하였다. 따라서 H-E3B는 $80^{\circ}C$, RB 133%는 $60^{\circ}C$가 적정한 것으로 판단된다. 이상의 최적조건에서 폐MDF 목질섬유를 염색처리하면 H-E3B염료는 1.5~2.0R, RB 133%염료는 9.6~10.0 PR의 색상을 가지는 염색 재생 목질섬유의 제조가 가능하였다.

• 유기물자원화
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• 제20권2호
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• pp.15-19
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• 2012

폐목재를 자원화하는 방법은 물질재활용과 에너지재활용으로 분류된다. 물질재활용은 폐목재를 원료로 파티클보드 또는 MDF를 생산하는 것 등이 포함되며 분리배출 및 수집을 통해 수차례 재활용이 가능한 장점이 있다. 에너지재활용은 칩을 제조하여 열병합발전 또는 보일러의 원료로 에너지를 생산하는 것을 말한다. 화석연료를 사용하는 발전소, 보일러 등에서 기존의 연료(석유, 화석연료 등)를 폐목재로 대체하면 화석연료 구입비용과 폐목재를 폐기물로서 처리하는 비용을 절감할 수 있다. 본 연구는 폐목재를 원료로 하여 파티클보드 생산공정과 열병합 에너지 생산공정을 전과정평가의 방법으로 지구 온난화에 미치는 영향을 분석하였다. 폐목재 1톤을 사용하여 파티클보드 생산공정은 112kg의 온실가스 를 배출하며, 열병합에너지공정은 382kg의 온실가스를 배출하는 것으로 분석되었으며, 분석조건은 파티클보드의 평균수명 14년과 재활용회수 16회를 가정하였고, 이때 임시적 탄소저장능을 고려하였다.

• 한국가구학회지
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• 제21권3호
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• pp.237-247
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• 2010

This research was carried out to examine the properties of black charcoal board, in order to find the proper manufacturing condition for the black charcoal-board made of the charcoal. The charcoal in this study was distillated from domestic wood waste, and it were also the purpose of this study to see if the black charcoal-board has the advantageous properties of charcoal as a well-being building material against the sick house problem. Domestic wood waste was consisted of MDF 40%, PB 30%, plywood 15% and wood 15%, respectively. Black charcoal board was produced by hot pressing with following conditions; temperature $170^{\circ}C$, three stage pressing cycle of $40-10-40\;kgf/cm^2$(1min.-2.5min.-5min.) and non formaldehyde adhesives [P15%+M5%:MDI(M), poly vinyl acetate emulsion(P). Fine mixed particle size [#6-12(16.9%), #12-18(16.7%), #12-40(47.2%), #40-60(9.5%), #60-100(5.9%), less than #100(3.8%)] gave better results than larger particle size [over #6(33.8%), #12-18(17.7%), #12-40(37.7%), #40-60(6.4%), #60-100(2.6%), less than #100(1.8%)]. Final moisture content of the mat was best at 36%. Black charcoal-board showed less MOR and IB(internal bond), more WA(water absorption) than that of white charcoal-board. Black charcoal board showed not only the same gas adsorption and dimensional stability as white charcoal board but also good cutting, nailing and drilling for indoor environment systems.

• Journal of the Korean Wood Science and Technology
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• 제28권4호
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• pp.83-93
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• 2000

This study was carried out to improve the physico-mechanical properties of board products by applying the technique of high frequency heating, and find out the optimum conditions of high frequency heating, compared with the technique of hot platen heating. The possibility of isocyanate resin application to board production was also considered to solve the problem of free formaldehyde emission from urea resin which is generally used in wood industry. For this study, 30 mm thick MDP (medium density fiberboard) with isocyanate resin were manufactured by the techniques of hot platen heating, high frequency heating and the combination techniques of both heating methods, and compared in several point of views.

• 대한환경공학회지
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• 제30권11호
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• pp.1102-1110
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• 2008

본 연구는 폐목재 발생원별 삼성분, 발열량, 그리고 중금속 및 Cl 함량을 분석하여 폐목재 특성을 평가함으로써 향후 폐목재 등급화를 위한 품질근거 기준을 마련하는데 필요한 기초자료를 제시하고자 하였다. 임목부산물, 생활계폐목재, 건설폐목재, 그리고 사업장폐목재의 4가지로 분류한 폐목재에서 수분함량은 대부분 5$\sim$10%를 나타내었으며, 이를 수분함량을 제외한 건조기준으로 환산하였을 때 가연분함량은 95% 이상이었고, 회분함량은 5% 이하를 나타내었다. 폐목재는 수분함량이 55%로 높았던 버섯재배폐목을 제외하고는 '건설폐기물의재활용촉진에관한법률'의 고형연료제품의 품질기준 중 발열량 기준(저위발열량 $\geq$ 3,500 kcal/kg)을 만족하였다. CCA (Cr, Cu, As)로 처리된 벤치목, 폐선박, 철도침목 등 방부목에서 CCA가 매우 높게 나타나 방부목의 사용과 관리, 폐기처분에 대한 엄격한 관리가 필요한 것으로 나타났다. Cl 함량은 목재 어(魚)상자에서만 약 1.3%로 가장 높게 나타났고 나머지 폐목재 및 재활용제품에서는 0.2% 이하의 낮은 값을 보였으나 고형연료제품의 염소함량 품질기준 (건조기준 2wt.%)을 모두 만족시켰다. 발생원별 폐목재를 유해물질 함유량을 기준으로 3등급화할 경우 대부분의 폐목재가 1등급에 해당하였으며, 합판류, MDF (medium density fiber), 표면도색된 전선드럼은 2등급에 해당하였다. 3등급에 해당하는 폐목재는 벤치목, 재활용공장목재분진, 폐선박과 철도침목으로 나타났다.