• 한국염색가공학회지
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• 제24권4호
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• pp.260-269
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• 2012

The aim of this study was to develop higher-value added dyeing materials with the fermentation-dyeing -mordanting system using only the natural ingredients by integrating traditional fermentation techniques with traditional dyeing technique. Nuruk, which is used mainly to ferment traditional foods, was used as a fermenting agent to ferment 5 different types of materials. Acidic burnt alum and alkaline calcium hydroxide were used as natural mordants. The dyeability checked after fermentation showed that both cotton and silk mordanted with Gardenia jasminoides did not show notable changes, and 10 days of fermentation was found to be appropriate. Sophora japonica L. performed better on cotton materials mordanted with slaked lime, and alkaline mordants were found to be more effective than acidic ones. With Rheum coreanum, a fermentation period of more than 24 days ($5^{th}$ fermentation) worked best on cotton material, showing a 5 fold increase in the K/S value after the $5^{th}$ slaked lime fermentation than with no fermentation. Rhus javanica L. was found to increase the color fastness to gentle washing and the fastness to light was found to possess 4 means that natural dyed fabric have the highest level of durability, the grade 1 the lowest level of fastness.

• 한국염색가공학회지
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• 제32권3호
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• pp.150-157
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• 2020

Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.

• 한국염색가공학회지
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• 제9권6호
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• pp.10-17
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• 1997

In order to improve the anti-static property of several hydrophobic fibers by sputter etching, polyester, polypropylene and poly(p-phenylene sulfide) have been etched by sputtering in the presence of argon gas and the resulting anti-static property investigated by half time decay, the time of water permeation, weight loss rate and scanning electron microscope(SEM). The temporary change and durability of anti-static property of samples treated with sputter etching were evaluated. The results were as follows; 1) Half time decay of samples treated with sputter etching were decreased about 18~38%. According to increasing sputter etching time, half time decay is decreased. 2) The wettability and weight loss rate of treated samples were increased remarkably. According to the SEM photographs, many microcraters on the substrate surface by the sputter etching were observed. 3) Although the washing treatment and the time elapsed after treatment are allowed longer, the variation of half time decay hardly can find.

• 한국염색가공학회지
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• 제31권1호
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• pp.33-41
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• 2019

In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.

• 한국염색가공학회지
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• 제33권4호
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• pp.230-237
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• 2021

The flame-retardant (FR) treatments of wool fibers using Hexafluorozirconate/titanate salts and tetrabromophthalic anhydride can cause skin irritation and gas toxicity due to Zr and Br compounds respectively. A water-soluble polyfunctional cyclophosphazene derivative, synthesized through substitution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] metacrylamide, was applied as a durable flame-retardant for wool fabrics. Also, a crosslinked structure was introduced to improve washing durability of the FR-wool, up to 10 laundering cycles, using Acrylamide(AAm) and Triacryloylhexahydrotriazine (TAHT) as a comonomer and a crosslinker respectively. The mole ratios of the TAHT and AAm concentrations compared to the Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) were optimized to 1.33 and 7.5 respectively. In addition, the pyrolysis and combustion properties of the FR wool were assessed using LOI, TGA and microcalorimetry suggesting a solid-phase FR mechanism.

• 한국염색가공학회지
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• 제35권3호
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• pp.151-158
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• 2023

In this study, we investigated the durability properties of the recycled leather using shaving scrap with antioxidant. Recycled leather sheets were manufactured by mixing shaving scrap and NB latex as a binder. HALS(Hindered Amine Light Stabilizer) and UVA(UV absorbers) were used as antioxidant. Mechanical properties such as hardness, tensile strength, elongation, tear strength and abrasion resistance were measured. Light aging resistance was evaluated using UV lamp and the degree of discoloration of the recycled leather sheets using a gray scale. In addition, to evaluate heat aging and UV aging, the degree of discoloration of the recycled leather sheets over time was measured using colorimeter. Washing fastness was evaluated on the degree of dyeing of recycled leather sheets for six type of multi-fiber woven fabrics (Acetate, Cotton, Nylon-66, Polyester, Acryl, Wool). To determine whether hazardous substances were detected in recycled leather sheets, the contents of arylamine and Cr 6⁺ were evaluated. As a result, when used in combination with antioxidant, the heat aging and light aging of recycled leather were improved and hazardous substance were not detected.

• 한국응용과학기술학회지
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• 제31권4호
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• pp.584-594
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• 2014

고분자 필름의 표면에 친수성의 증가시키는 것은 그 자기 세정 및/또는 방담 특성을 가지게 하는데 중요한 접근 방법이다. 일반적으로 친수성 표면은 비이온 계면활성제를 코팅하거나 표면에너지를 증가시킴으로써 제조할 수 있다. 본 연구에서는 가격이 저렴하고 톨루엔 용제에 잘 용해될 뿐 만아니라 커플링제와 반응할 수 잇는 하이드록시기를 가지고 있는 Tween, Span 및 PEG-PPG 블록공중합체를 선택하여 실험을 수행하였다. 배합 조건에 따라 PET 필름 표면의 친수도에 큰 영향을 미침을 확인하였다. 그러나, PET 필름의 표면상에 단순히 이들 계면활성제의 도입은 수세 후에는 높은 내구성을 보여주지 않았다. 내구성을 높이기 위해 에폭시 및 이소시아네이트와 같은 두 종류의 커플링제를 사용하였다. 코팅액에 6 중량 %isophrone 디이소시아네이트 (IPDI)를 함유한 코팅액으로 코팅된 PET 필름 표면의 물에 대한 접촉각은 $8.7^{\circ}$까지 낮아졌으며, 이는 매우 높은 친수성에 대한 간접적인 증거이다. 또한, 코팅된 PET 필름의 광 (파장 500 nm) 투과율 값은 높은 투명 특성을 유지하면서 87%에서 85%로 약간 감소하였다. 이 PET 필름은 자기 세정 특성이 필요한 필름산업에 적합한 소제로 사용될 수 있다.

• 지식경영연구
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• 제17권2호
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• pp.27-50
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• 2016

Korean manufacturing industry have recently faced the catch-up of China in the mass commodity product, such as automotive, display, and smart phone in terms of market as well as technology. Accordingly, discussion on the importance of achieving catch-up in complex product systems (CoPS) has been increasing as a new innovation engine for the industry. In order to achieve successful catch-up of CoPS, we explored emerging technologies of CoPS, which are featured by the characteristics of radical novelty, relatively fast growth and self-sustaining, through the study of emerging technologies of gas turbine for power generation. We found that emerging technologies of the gas turbine are technologies for combustion nozzle and composition of electrical machine for increasing power efficiency, washing technology for particulate matter, cast and material processing technology for enhancing durability from fatigue, cooling technologies from extremely high temperature, interconnection operation technology between renewable energy and the gas turbine for flexibility in power generation, and big data technology for remote monitoring and diagnosis of the gas turbine. We also found that those emerging technologies resulted in technological progress of the gas turbine by converging with other conventional technologies in the gas turbine. It indicates that emerging technologies in CoPS can be appeared on various technological knowledge fields and have complementary relationship with conventional technologies for technology progress of CoPS. It also implies that latecomers need to pursue integrated learning that includes emerging technologies as well as conventional technologies rather than independent learning related to emerging technologies for successful catch-up of CoPS. Our findings provide an important initial theoretical ground for investigating the emerging technologies and their characteristics in CoPS as well as recognizing knowledge management strategy for successful catch-up of latecomers. Our findings also contribute to the policy development of the CoPS from the perspective of innovation strategy and knowledge management.

• 한국의류산업학회지
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• 제11권5호
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• pp.764-770
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• 2009

This study was conducted to analyze the wearing condition on gloves for pilots and to suggest the developments for pilot gloves design. This survey was performed with 99 pilots and the questionnaires included items about discomfort, materials and problems when wearing pilot gloves. The respondents felt uncomfortable on the finger tip, the hollow area of the hand and the end of thumb when they move their hands with the gloves. They replied that the finger length, palm length, and circumference of the fingers did not match well. Also they complained there was severe abrasion in the tip of the thumb, finger tips and the middle of the palm of the gloves. The result of these analyses supports the following suggestions. It is necessary to improve durability by applying the additional materials to the severely worn parts. Punching on the glove materials could improve sweat rate and ventilation, and careful washing should be accompanied to prevent the occurrence of linters and transformation after laundering. And it is needed to prepare an accurate and more diversified size system and to design the gloves fitted to the individual hands. With these in mind, it is required to propose solutions for pilot gloves with reference to the survey results in order to design appropriate pilot gloves in terms of movement, size and material. It was concluded that an analysis of the wearing condition and developments are useful for ergonomics pilot gloves design.

• Plant Resources
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• 제5권3호
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• pp.206-209
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• 2002

This study was performed to investigate the effect of Mentha arvensis Herba extract on the treatment of chromaticity and colorfastness. Mentha arvensis Herba has been used as a Korean medicine. It is effective in headache and stress. It is also good as a aphtha and in treating cold. In the long history of Korea, dyeing has been applied for a means representing the grace of natural and inner esthetic consciousness of man. Vegetable dyes give us such great benefits, diversified color, but no pollution. And ramie fabric has distinctive features such as beautiful brilliance, elegance, and strong durability. So, it is regarded as a special product of Korea traditionally. These studies were carried out to treat with acetate iron, dichloride copper and alum with a mordant to ramie fabric. The ramie fabric was died with Mentha arvensis Herba extract. The results of experiment showed as follows: First, the chromophoric degree was the highest in acetate iron but not distinction in another mordants. Second, the light colorfastness was the highest in non treated and dichloride copper, but alum was the lowest. Third, the discoloration was alum and dichloride copper showed first grade in washing colorfastness. Abrasion colorfastness was not significant in this test. According the previous results, Mentha arvensis Herba has an efficiency in removing aphtha and in treating cold. So it is considered that Mentha arvensis Herba can be applied effectively to headache and stress.