• 한국자동차공학회논문집
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• 제12권4호
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• pp.181-190
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• 2004

The interest of the fatigue life of rubber components such as engine mounts is increasing according to the extension of warranty period of the automotive components. Automotive engine mounts get damaged due to thermal and mechanical loadings. This paper discusses a fatigue life prediction of the 3-dimensional dumbbell specimens for natural rubber compound considering the effects of maximum strain and heat aging temperature. Displacement controlled fatigue life tests were performed using specimens with different levels of maximum strain and various hardness. The basic mechanical properties test and the fatigue test of aged rubber specimen under normal and elevated temperature were executed. A procedure to predicted the fatigue life of vulcanized natural rubber material based on the maximum strain method was proposed, and then this curve was in good agreement with fatigue test data less than 200% error range.

• Elastomers and Composites
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• 제18권2호
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• pp.51-59
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• 1983

고분자물질의 유전특성은 고분자의 분자구조를 연구하는데 대단히 중요하다. 황가황에 의한 천연고무의 유전흡수특성을 25[$^{\circ}C$]의 온도에서 주파수영역 10[KHz]부터 32[KHz] 사이에서 연구하였는데, 결과로서 황 4phr 이하의 가황 천연고무에서는 계면분극과 쌍극자 분극에 의한 두종류의 유전손실이 나타났고 황 7phr 이상의 가황 천연고무에서는 쌍극자분극에 의한 손실만이 존재함을 확인하였다. 더욱이 황의 증가로 저주파수쪽으로 이동되는 유전 손실스펙트럼의 최대치 $tan{\delta}$는 황에 의해 변화되며 체적고유저항은 황의 첨가와는 무관하였고 그 크기는 $10^{7}{\sim}10^{11}[{\Omega}{\cdot}cm}]$이였다.

• 대한전기학회논문지
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• 제33권3호
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• pp.112-117
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• 1984

The dielectric propertries of polymers are very important to investigate the molecular structure of polymer. The characteristrics of the dielectric absorption in vulcanized natural rubber were studied in the range of frequency from 10[KHz] to 32[MHz] at the temperature of 25[$^{\circ}C$]. As the results. it has been confirmed that in the case of natural ruber vulcanized between 2 and 4phr the specimens exhibit two kind of dielectric losses due to the dipole polarization by impurites and sulfure, and of above 7phr was only a loss due to the dipole polarization by sulfure and of natural rubber exhibit two kind of losses due to the interfacial and the dipole polarization. Furthermore, dielectric loss maximun tan spectrum, which removed to the low frequency according to increasing sulfure, depends greatly on sulfure. The volume resistivity of $10^{7}$~$10^{11}$[$\Omega\cdot$cm], regardness whether the crosslinking of rubber are tired by sulfure or, was observed.

• Elastomers and Composites
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• 제33권3호
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• pp.159-167
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• 1998

고무제품의 노화는 인간의 노화 처럼 오존, 자외선, 산소 등의 작용에 의하여 매우 복잡하게 진행된다. 노화에 대한 이해는 매우 중요하나 너무나 복잡하기 때문에 이에 대한 논문이 매우 드물다. 본문에서는 EPDM과 천연고무의 노화거동을 이해하고자 하였고 가황물과 과산화물 가교물의 노화거동을 서로 비교하여 보았다. 실험결과 파산화물에 의한 가교물이 황에 의한 가교물보다 노화면에서는 좋게 나타났다. 저자는 본 연구가 고기능성 고무 제품을 제조하는데 도움이 되리라 믿는다.

• Elastomers and Composites
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• 제21권3호
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• pp.205-212
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• 1986

The dielectric properties of natural rubber are very important to investigate the molecular structure. The charcteristics of the dielectric absorption in aging natural rubber were studied in the range of frequency from $1{\times}10^3Hz\;to\;3.2{\times}10^7Hz$ at the temperature of $23^{\circ}C$. As the results, it has been confirmed that in the case of aged NR vulcanized specimen with contained sulfur 2 phr above the specimens exhibit two kind of dielectic losses due to the the dipole polarization by impurities and sulfurs, and of raw rubber exhibit the kind of losses due the to dipole polarization. Particularly, it has been affirmed that the dielectric loss spectrum of the aging natural rubber is larger than that the natural rubber, and the dielectric strength of the aging natural rubber drop depreciate respctively.

• 한국안전학회지
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• 제6권4호
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• pp.5-12
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• 1991

The dielectric properties of natural rubbers for electric safety are very important to investigate the molecular structure. The electric safety characteristics of the dielectric absorption in aging vulcanized natural rubber were studied in the range of frequency from 1$\times$10$^3$［Hz］to 3.2$\times$10$^3$［Hz］l at the temperature of 23［$^{\circ}C$］. As the results, it has been confirmed that in the case of aging natural rubber of above 2 phr the specimens exhibit two kinds of dielectric losses due to the dipole polarization by impurities and sulfurs, and of raw rubber exhibit the kind of losses due to the dipole polarization. Rurthermore, dielectric loss maximum tansspectrum in high freguency region for electric safety, which removed to the low freguency according to increasing sulfur, depends greatly on sulfur.

• Elastomers and Composites
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• 제42권4호
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• pp.209-216
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• 2007

가변진폭 하중에서 고무부품의 피로수명 예측방법에 대하여 연구하였다. 서로 다른 변위에서 변위제어 피로시험을 수행하였으며 피로손상변수로 최대 Green-Lagrange 변형률을 선정하였다. Green-Lagrange 변형률에 의한 고무의 피로수명 곡선은 3차원 덤벨시편의 비선형 유한요소법을 이용하여 결정하였다. 피로수명 예측을 위하여 가변진폭 하중이력으로 SAE의 하중이력을 이용하였다. 레이스트랙법과 단순화된 레인플로집계법을 이용하여 하중이력신호를 축약하였다. 누적손상피로를 계산하는 방법으로 수정Miner 법칙을 이용하였으며, 최종적으로 하중이력신호에서 최대 진폭의 30% 이하를 노이즈로 간주하여 예측하였을 경우의 피로수명은 실제 가변진폭 하중 하에서의 피로시험결과와 비교적 잘 일치하였다.

• Advances in materials Research
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• 제3권3호
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• pp.175-183
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• 2014

Natural rubber bound phenolic antioxidant, 2,6-di-tert-butyl-4-vinylphenol (2,6-DBVP), was prepared from natural rubber and 2,6-DBVP in both solution and melt state. The 2,6-DBVP had been synthesized from 3,5-di-tert-butyl-4-hydroxybenzaldehyde and methyltriphenylphosphonium iodide ($MePPh_3I$) by Wittig reaction ($0^{\circ}C$ for 2 hrs, $N_2$ atmosphere). The conditions for preparation of natural rubber bound 2,6-DBVP (NR-DBVP) were optimized for both solution state (1 phr BPO and 8 phr 2,6-DBVP at $70^{\circ}C$ for 2 hrs) and for melt state (1 phr BPO and 8 phr 2,6-DBVP at $70^{\circ}C$ for 10 mins, with rotor speed of 60 rpm). A thermoplastic vulcanizate was obtained using a compatibilizer, polypropylene modified with phenolic resin (PhHRJ-PP), in a closed mixer ($180^{\circ}C$ for 3 mins, rotor speed 60 rpm). The antioxidant properties of vulcanized NR-DBVP, using phenolic as the vulcanization system, were similar to NR with the conventional antioxidant BHT. In addition, the antioxidant, water leaching property of the thermoplastic vulcanizate of NR-DBVP/PP were good in comparison to a NR blend with BHT; the morphologies of these thermoplastic vulcanizates were similar.

• Elastomers and Composites
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• 제36권2호
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• pp.121-129
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• 2001

다양한 조건 하에서 고무판의 마찰계수를 폭정하기 위하여 수직하중, 미끄럼속도, 경도, 윤활 조건 및 고무판 두께 등을 변화시켜가면서 시험을 실시하였다. 시험에 사용된 고무판의 재질은 천연고무이며, 상대 부품은 강구를 사용하였다. 수직하중과 미끄럼속도는 마찰계수에 현저한 영향을 미치지 않았으며, 고무판의 경도가 높아지고 고무판의 두께가 얇아질수록 마찰계수는 감소하였다. 무윤활 시 마찰계수는 큰 편차를 보였으나, 오일 윤활인 경우 다른 조건에 관계없이 안정된 값을 나타내었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.309-314
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• 2000

Rubber is used as a primary suspension component in a vehicle or a mechanical structure. The aim of this study is to establish a procedure for measuring the material properties of rubber and to analyze the differences of material properties of virgin rubber and heat aged rubber. The effect of mechanical conditioning was shown and included in the procedures of tensile. compression. simple shear. and pure shear tests. In addition. using engine oil was recommended for compression test in order not to have barrelling. Moreover, based on the material properties of vil·gin rubber and heat aged rubber. equations of C10 and IRHD were proposed as a function of heat aging temperature and time.